Search

Your search keyword '"Mingde Ye"' showing total 1 results
Start Over Author "Mingde Ye" Publisher royal society of chemistry
1 results on '"Mingde Ye"'

1. Efficient and selective nitrile hydration reactions in water catalyzed by an unexpected dimethylsulfinyl anion generated in situ from CsOH and DMSO.

Author

Haonan Chen, Wujie Dai, Yi Chen, Qing Xu, Jianhui Chen, Lei Yu, Yajuan Zhao, Mingde Ye, and Yuanjiang Pan

Subjects
NITRILES, CYCLOTRIPHOSPHAZENES, CATALYSIS, HYDRATION, HYDRATASES, HEAT of hydration
Abstract

Unexpected dimethylsulfinyl anions (I), generated in situ from the superbase system CsOH-DMSO, was found to be a highly active catalyst for controllable nitrile hydration reactions in water, which selectively afforded the versatile amides via interesting Cs-activated I-catalyzed direct and indirect hydration mechanisms involving an O-transfer process from DMSO onto the nitriles. [ABSTRACT FROM AUTHOR]

Published
2014
Full Text
View/download PDF

Catalog

Books, media, physical & digital resources
See catalog results