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1. Demethylation of 2,4-dimethoxyquinolines: the synthesis of atanine.

Author

Jones K, Roset X, Rossiter S, and Whitfield P

Subjects
Methylation, Models, Chemical, Molecular Structure, Quinolines chemistry, Quinolones chemistry, Quinolines chemical synthesis, Quinolones chemical synthesis
Abstract

The synthesis of the quinoline alkaloid atanine 6, by selective demethylation of the 2,4-dimethoxyquinoline 11 is presented. An alternative demethylation utilising a thiolate anion leads to the regioisomeric 4-hydroxyquinoline 13.

Published
2003
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