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2. Efficient proton conductivity of a novel 3D open-framework vanadoborate with [V6B20] architectures.

3. Layer-by-layer assembly into bulk-like g-C3N4via artificial manipulation of electrostatic forces.

4. Efficient proton conductivity of a novel 3D open-framework vanadoborate with [V 6 B 20 ] architectures.

5. Layer-by-layer assembly into bulk-like g-C 3 N 4 via artificial manipulation of electrostatic forces.

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