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Start Over Author "Sharma, Rajpal" Publisher royal society of chemistry
1 results on '"Sharma, Rajpal"'

1. Bis(mandelato)borate: an effective, inexpensive spiroborate anion for chiral resolution.

Author

Wong, Lawrence W-Y., Kan, Jack W-H., Nguyen, Thanh-ha, Sung, Herman H-Y., Li, Dang, Au-Yeung, Alex S-F., Sharma, Rajpal, Lin, Zhenyang, and Williams, Ian D.

Subjects
RESOLUTION (Chemistry), BORATES, ALKALOIDS, DIAMINOPROPANE, ANIONS
Abstract

Bis(mandelato)borate [B(Man)2]− (R- or S-) anions are simply prepared and appear widely effective for resolution of racemic cations. Three examples demonstrate their scope; the alkaloid tetrahydropalmatine (THP), 1,2-diaminopropane (1,2-dap) and the metal–organic complex [Co(phen)3]3+ are readily resolved, either by a facile one-pot procedure, or via counter-ion metathesis. [ABSTRACT FROM AUTHOR]

Published
2015
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