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Start Over Author "Hai-Tao Qin" Publisher royal society of chemistry (rsc)
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1. Photoredox-catalysed redox-neutral trifluoromethylation of vinyl azides for the synthesis of α-trifluoromethylated ketones

Author

Hai-Tao Qin, Shu-Wei Wu, Feng Liu, and Jia-Li Liu

Subjects
010405 organic chemistry, Trifluoromethylation, Metals and Alloys, Sodium trifluoromethanesulfinate, General Chemistry, 010402 general chemistry, 01 natural sciences, Redox, Catalysis, 0104 chemical sciences, Surfaces, Coatings and Films, Electronic, Optical and Magnetic Materials, chemistry.chemical_compound, chemistry, Materials Chemistry, Ceramics and Composites, Organic chemistry
Abstract

A redox-neutral, mild, and simple protocol is developed for the synthesis of α-trifluoromethylated ketones from vinyl azides under transition-metal-free conditions. In the presence of organic photoredox catalyst N-methyl-9-mesityl acridinium and sodium trifluoromethanesulfinate, a broad range of substituted vinyl azides were found to react smoothly upon visible-light irradiation, readily furnishing the corresponding products in satisfied yields.

Published
2017
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