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Start Over Author "Keisei Sowa" Publisher royal society of chemistry (rsc)
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1. Multiple electron transfer pathways of tungsten-containing formate dehydrogenase in direct electron transfer-type bioelectrocatalysis

Author

Tatsushi Yoshikawa, Fumiaki Makino, Tomoko Miyata, Yohei Suzuki, Hideaki Tanaka, Keiichi Namba, Kenji Kano, Keisei Sowa, Yuki Kitazumi, and Osamu Shirai

Subjects
Electron Transport, Materials Chemistry, Metals and Alloys, Ceramics and Composites, Electrons, General Chemistry, Electrodes, Formate Dehydrogenases, Tungsten, Catalysis, Surfaces, Coatings and Films, Electronic, Optical and Magnetic Materials
Abstract

Tungsten-containing formate dehydrogenase from Methylorubrum extroquens AM1 (FoDH1) was investigated from structural biology and bioelectrochemistry. The electron transfer (ET) pathways were investigated by structural information, electrostatic interactions between the electrode and the enzyme, and the differences in the substrates. Two electrode-active sites and multiple ET pathways in FoDH1 were discovered.

Published
2022
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