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Start Over Author "Tong-De Tan" Publisher royal society of chemistry (rsc)
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1. Stereoselective synthesis of 2,5-disubstituted pyrrolidines via gold-catalysed anti-Markovnikov hydroamination-initiated tandem reactions

Author

Hao-Ze Su, Jia-Le Wang, Long-Wu Ye, Tong-De Tan, Yang-Bo Chen, Feng-Lin Hong, Ming-Yang Yang, and Jin-Mei Zhou

Subjects
Tandem, 010405 organic chemistry, Chemistry, Markovnikov's rule, Metals and Alloys, General Chemistry, 010402 general chemistry, 01 natural sciences, Combinatorial chemistry, Catalysis, 0104 chemical sciences, Surfaces, Coatings and Films, Electronic, Optical and Magnetic Materials, Intramolecular force, Materials Chemistry, Ceramics and Composites, Stereoselectivity, Hydroamination
Abstract

A series of gold-catalysed intramolecular anti-Markovnikov hydroamination-initiated azidation, allylation and heteroarylation reactions of chiral homopropargyl sulfonamides have been developed. Various enantioenriched 2,5-disubstituted pyrrolidines are obtained in moderate to excellent yields with excellent enantioselectivities and generally high diastereoselectivities.

Published
2019
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