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A proof-of-concept for magneto-optical barcodes is demonstrated for the first time. The dual-signalled spectrum observed via magnetic circular dichroism spectroscopy can be used to develop anti-counterfeiting materials with extra layers of security when compared with the widely studied luminescent barcodes.

Luminescence thermometry with trivalent lanthanide ions is a promising avenue for contactless temperature probing. The area has been growing exponentially for the last two decades, and its viability has been successfully demonstrated in various research domains. However, moving from laboratory equipment to real-life applications remains a challenging task. One of the reasons is the possibility of a background luminescence from the probing device or probed environment. To tackle this issue, we elegantly incorporate a rarely explored thermometric approach called time-gated luminescence thermometry (TGLT). Furthermore, we demonstrate an enhanced relative sensitivity through this innovative approach and a path to move toward practical application.

Upconversion (UC) is a fascinating process in which higher energy photons can be emitted from excitation by lower energy photons. The current challenge remains in downscaling and effectively achieving upconversion with lanthanide ions at the molecular scale. Here, using a rationally designed molecular cluster-aggregate (MCA), we demonstrate for the first time Ho III ion molecular upconversion. The synthesized MCA exhibits identifiable Ho III green and red UC emissions with a uniquely enhanced red to green ratio as well as a conventional near-infrared (NIR) emission. A combined rigid spherical cluster core with reduced molecular vibrations, ideally matched donor and acceptor excited levels via a phonon-assisted mechanism, led to an upconversion quantum yield of 5.24 × 10 -6 %.

The engineering of core@multi-shell nanoparticles containing heterogeneous crystalline phases in different layers constitutes an important strategy for obtaining optical probes. The possibility of obtaining an opto-magnetic core@multi-shell nanoparticle capable of emitting in the visible and near-infrared ranges by upconversion and downshifting processes is highly desirable, especially when its optical responses are dependent on temperature and magnetic field variations. This work proposes the synthesis of hierarchically structured core@multi-shell nanoparticles of heterogeneous crystalline phases: a cubic core containing Dy III ions responsible for magnetic properties and optically active hexagonal shells, where Er III , Yb III , and Nd III ions were distributed. This system shows at least three excitation energies located at different biological windows, and its emission intensities are sensitive to temperature and external magnetic field variations. The selected crystalline phases of the core@multi-shell nanoparticles obtained in this work is fundamental to the development of multifunctional materials with potential applications as temperature and magnetic field optical probes.

Near-Infrared emissions are highly important in biological and telecommunications technology. For the first time, NIR-to-NIR emission was achieved in a water-soluble molecular cluster-aggregate. The erbium analogue of the highly tunable [Ln6(teaH)6(NO3)6] complex emits at 1530 nm with direct excitation at 980 nm, and can be boosted by replacing three erbium ions with three ytterbium(iii), in the molecular structure. The presented methodology is a unique approach to probe the effect of composition control and harness the luminescence properties of nanoscale molecular material.