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Soft robotic systems are increasingly emerging as robust alternatives to conventional robotics. Here, we demonstrate the development of programmable soft actuators based on volume expansion/retraction accompanying liquid-vapor phase transition of a phase-change material confined within an elastomer matrix. The combination of a soft matrix (a silicone-based elastomer) and an embedded ethanol-impregnated polyacrylonitrile nanofiber (PAN NF) mat makes it possible to form a sealed compound device that can be operated by changing the actuator temperature above/below the boiling point of ethanol. The thermo-responsive actuators based on this principle demonstrate excellent bending ability at a sufficiently high temperature (>90 °C) - comparable with compressed air-based soft actuators. The actuator using the mechanism presented here is easy to manufacture and automate and is recyclable. Finally, the actuation mechanism can be incorporated into a wide variety of shapes and configurations, making it possible to obtain tunable and programmable soft robots that could have a wide variety of industrial applications.

Electrospun metal-plated nanofibers and supersonically sprayed nanowires were used to fabricate hybrid films exhibiting a superior low sheet resistance of 0.18 Ω sq-1, a transparency of 91.1%, and a figure-of-merit of 2.315 Ω-1. The films are suitable to serve as thermal sensors and heaters. Such hybrid transparent conducting films are highly flexible and thus wearable. They can be used as body-temperature monitors and heaters. The employed hybrid approach improved the sheet resistance diminishing it to a minimum, while maintaining transparency. In addition, the low sheet resistance of the films facilitates their powering with a low-voltage battery and thus, portability. The thermal sensing and heating capabilities were demonstrated for such films with various sheet resistances and degrees of transparency. The temperature sensing was achieved by the resistance change of the film; the resistance value was converted back to temperature. The sensing performance increased with the improvement in the sheet resistance. The temperature coefficient of resistivity was TCR = 0.0783 K-1. The uniform distribution of the metal-plated nanofibers and nanowires resulted in a uniform Joule heating contributing to an efficient convection heat transfer from the heaters to the surrounding, demonstrated by an improved convective heat transfer coefficient.

Here, model blister-like soft thermo-pneumatic artificial muscles with the embedded nanofibers impregnated with ethanol are developed. The muscles are essentially blister-like thermo-pneumatic soft actuators (BTSAs), which deflect in response to heat supplied to their bottom. The resulting deflections are on the scale of 1 cm, and the BTSAs are operational for several cycles. They are able to raise the artificial rigid scales, spines or fur/thin fibers attached to them emulating animals such as pangolin, hedgehog and porcupine. They are also capable of removing the stickiest adhesive tapes attached to them, and thus hold great promise for biomedical applications where artificially grown skin patches should be removed from an underlying substrate without being damaged. The theory of the BTSA proposed in this work is in reasonable agreement with the acquired experimental data.

Aneurysmal subarachnoid hemorrhage (SAH) is the extravasation of blood into the subarachnoid space and is fatal in most cases. Platinum coils have been used to fill the hemorrhage site and prevent the extravasation of blood. Here we explored the use of Pt-coated polymer nanofibers (NF) to prevent blood extravasation and were able to achieve improved results in vitro. The polymer nanofibers were produced via electrospinning and were subsequently electroplated with Pt, resulting in metalized nanofibers. These nanofibers were installed within a microfluidic channel, and the resulting reduction in the permeability was evaluated using a fluid similar to blood. Based on the obtained results, these newly developed nanofibers are expected to decrease the operation cost for SAH, owing to their reduced size and low material cost. Furthermore, it is expected that these nanofibers will be used in a smaller amount during SAH operation while having the same preventive effect. This should reduce the operational risk associated with the multiple steps required to place the Pt coils at the SAH site. Finally, the underlying hydrodynamic mechanism responsible for the reduced permeability of the synthesized nanofibers is described.

Bioluminescent jellyfish has a unique structure derived from fiber/polymer interfaces that is advantageous for effective light scattering in the dark, deep sea water. Herein, we demonstrate the fabrication of bio-inspired hybrid films by mimicry of the jellyfish's structure, leading to excellent light-scattering performance and defrosting capability. A haze value reaching 59.3% and a heating temperature of up to 292 °C were achieved with the films. Accordingly, the developed surface constitutes an attractive optical device for lighting applications, especially for street or vehicle luminaries for freezing Arctic-climate countries. The morphological details of the hybrid films were revealed by scanning electron microscopy. The light-scattering properties of these films were examined by ultraviolet-visible-infrared spectrophotometry and anti-glare effect analyses. The defrosting performance of the hybrid films was evaluated via heating tests and infra-red observations.

Mechanically robust freestanding platinum (Pt) nanofiber (NF) meshes are of great interest in applications where the corrosion resistance, malleability, and stability of a pure platinum structure must be combined with high surface area for catalysis. For photoelectrochemical applications, transparent electrodes are desirable. Several 1-dimensional (1D) Pt-based materials have been developed, but energy-intensive fabrication techniques and unsatisfactory performance have limited their practical implementation in next-generation photoelectrochemical applications. Here, we introduce relatively simple yet commercially-viable methods for creating robust, free-standing PtNF mats through combined electrospinning/solution blowing and electroplating steps. The PtNFs obtained by these processes exhibited outstanding low sheet resistance (R s ) values with reasonable transparency. In addition, the PtNFs were highly bendable and stretchable. Thus, the new methods and materials presented here hold great promise for creating mechanically robust and catalytically active transparent conducting films for diverse photoelectrochemical applications.

Coaxial electrospinning was used to fabricate two types of core-shell fibers: the first type with liquid resin monomer in the core and polyacrylonitrile in the shell, and the second type with liquid curing agent in the core and polyacrylonitrile in the shell. These two types of core-shell fibers were mutually entangled and embedded into two flexible transparent matrices thus forming transparent flexible self-healing composite materials. Such materials could be formed before only using emulsion electrospinning, rather than coaxial electrospinning. The self-healing properties of such materials are associated with release of healing agents (resin monomer and cure) from nanofiber cores in damaged locations with the subsequent polymerization reaction filing the micro-crack with polydimethylsiloxane. Transparency of these materials is measured and the anti-corrosive protection provided by them is demonstrated in electrochemical experiments.