1. Influence of fibre stretching on the microstructure of self-reinforced poly(ethylene terephthalate) composite
- Author
-
Daniel Ståhlberg, Malin Åkermo, and Lars Jerpdal
- Subjects
010407 polymers ,Materials science ,Ethylene ,Polymers and Plastics ,Mechanical Engineering ,Composite number ,02 engineering and technology ,021001 nanoscience & nanotechnology ,Microstructure ,01 natural sciences ,Self reinforced ,0104 chemical sciences ,chemistry.chemical_compound ,chemistry ,Mechanics of Materials ,Woven fabric ,Materials Chemistry ,Ceramics and Composites ,Composite material ,0210 nano-technology ,Poly ethylene - Abstract
Self-reinforced poly(ethylene terephthalate) laminates were prepared from woven fabric by compression moulding. The fabric was stretched to different degrees during heating before hot consolidation to simulate a manufacturing process where the material is stretched through forming. High tenacity poly(ethylene terephthalate) fibres with different degrees of stretching were prepared for a comparison to laminates. Tensile tests were made to characterize mechanical properties, while dynamical mechanical analysis, differential scanning calorimetry, FTIR spectroscopy and X-ray diffraction analysis were employed to study microstructural changes caused by the stretching. Tensile tests show that 13% stretching of the fabric increases the laminate tensile stiffness by 34%. However, same degree of stretching for pure fibres increases the fibre tensile stiffness by 111%. Crystallinity and molecular conformations are not influenced by stretching while shrinkage upon heating increases with degree of stretching. Shrinkage is known to be related to disorientation of non-crystalline regions whereof the conclusion from this study is that the increased tensile properties are due to orientation of the non-crystalline regions of the fibre.
- Published
- 2016