Search

The Jinding deposit in the Lanping basin, southwest China, is the largest sandstone-hosted Zn deposit in the world and the second largest Zn-Pb deposit in China. However, questions related to the metal compositions and origin of the ore fluids remain. In this study, microthermometry and laser ablation-inductively coupled plasmamass spectrometry (LA-ICP-MS) were employed to determine the properties and compositions of individual fluid inclusions trapped in sphalerite and calcite. The results show that the fluid inclusions trapped in sphalerite and calcite have similar homogenization temperatures (79°–173°C with the majority 100°–130°C), salinities (10.3–29.1 wt % NaCl + CaCl2 equiv with the majority 24.5–27.4 wt % NaCl + CaCl2 equiv), and concentrations of alkali and alkali earth elements (e.g., Na, Ca, Mg, K, Sr, Ba, Li, Rb, and Cs). However, the concentrations of ore and associated metals (e.g., Pb, Sb, Ag, and Tl) in the fluid inclusions hosted by sphalerite are significantly higher than those hosted by calcite. Based on these observations, we propose that the sulfides including sphalerite were precipitated from a low-temperature, high-salinity, Ca-rich, metal-rich fluid, while the gangue minerals such as calcite crystallized subsequently from fluids depleted in metals due to prior precipitation of sulfides, and that the high salinities of the fluid inclusions are likely due to a combination of seawater evaporation and subsequent dissolution of evaporitic sequences during fluid percolation. The LA-ICP-MS analyses reveal that the fluid inclusions have K/Na, Rb/Na, and Cs/Na ratios within the range of modern basinal brines, and Li/Na, Ba/Na, and Ca/Na ratios share similar compositions with the ore fluids of basement interacted deposits in the world. The Jinding ore fluids contain ~200 to 650 ppm Pb, based on the data of fluid inclusions trapped in sphalerite. The estimated concentrations of Zn in the ore fluids are also very high at ~200 to 6,500 ppm. Our results reveal that anomalously metal rich fluids played a critical role in the formation of the giant Jinding sediment-hosted Pb-Zn deposit. We concur with the previous suggestion that sulfide precipitation at Jinding occurred when ascending metal-rich brines encountered an H2S-rich, Ca-rich fluid, which was produced by interaction of hydrocarbons with evaporites, in the cap of the Jinding dome.

South China is rich in vein-type hydrothermal uranium deposits hosted in granitic, volcanic, and carbonaceous and siliceous pelitic sedimentary rocks. The uranium deposits are spatially associated with extensional structures and/or mantle-derived mafic dikes. Both the uranium deposits and mafic dikes are Cretaceous to Tertiary in age, temporally coincident with the crustal extension. Carbon isotope analyses of calcite deposited in the main-stage mineralization in the veins from 12 representative uranium deposits yield δ13C values of ore-forming fluids mainly from −4 to −8 per mil, which are permissive of a mantle origin for the CO2 in the ore-forming fluids. A mantle origin is consistent with the association of the deposits with mafic dikes and the 3He/4He ratios of ore-forming fluids (e.g., 0.10–2.02 Ra for the volcanic-hosted Xiangshan uranium deposit). Isotopic compositions of H and O demonstrate that water in the ore-forming fluids is predominantly meteoric in origin. Ore-forming temperatures ranged approximately from 150° to 250°C. Uranium-rich crustal rocks in South China may have been the sources for the uranium. Crustal extension and associated mafic magmatism are considered to have heated the rocks and allowed CO2 (possibly from mantle sources) to migrate upward and to mix with CO2-poor meteoric water. The CO2-rich hydrothermal fluids mobilized uranium from the source rocks and then the uranium was deposited in various host rocks to form the uranium deposits.