A new luminescent copolymer containing three functional moieties was prepared. It possesses high thermal stability (decomposition temperature = 456 °C), good electrochemical reversibility, and good thin film-forming ability. Electrical characterization of a two-layer diode device based on the structure of ITO/CuPc/TPDPQ-FPQ/AI showed excellent electroluminescence performance (bright yellow emission, a rectification ratio greater than iO and a low turn-on voltage of3.0 V).Keywords: polyquinolines, tetraphenyldiaminobiphenyl, electroluminescence, light emitting diodes. 1. INTRODUCTION Since the first report on electroluminescence (EL) in polymeric light emitting diode (LED) by Cambridge group in 1990', asintensive research has been directed to the development of new polymers, and much progress was achieved.26 A highperformance polymer should possess the combination of desirable properties, such as high EL efficiency, good thermal,chemical, electrochemical and optical stability. This is often not the case for most of the polymers studied so far, therefore,the search for such a new polymer remains to be a frontier subject in this field. In addition, high quantum efficiency ELdevices can only be obtained by both efficient charge injection and balanced mobility of both charge carriers inside the ELmaterials. In most of the EL polymers, it is rather more difficult to inject electrons than holes and therefore the majoritycharge carriers are holes. In such cases, hole charge injection and transport are favored and the recombination of holes andelectrons takes place near the interface between EL material and cathode, which leads to the quenching of the excitons. On theother hand, a part of holes goes through the EL material to the cathode without recombination, and the Joule heat produceddamages the devices. Recently, a few research groups79 and our previous reported the results of light-emittingpolymers containing both electron and hole transporting moieties to achieve efficient device performance. Thus, it isdesirable to design and synthesize a high performance polymer that possesses high EL efficiency, high stability, excellentprocessibility, as well as a bipolar ability in order to meet the requirements for efficient LEDs. Polyquinolines (PQ) haveoutstanding thermal stability, low dielectric constants, low moisture absorption, and good film-forming properties.'214Recently, blue EL device using a fluorinated polyquinoline (PQ-lOO) as the emitting layer has been However, thisdevice possessed a very high turn-on voltage (50