Search

A green magnetic composite mCS/GO was synthesized using water hyacinth extract, as a reducing agent, and proanthocyanidin, as a crosslinking agent, for the adsorption of naphthalene from effluents. The green composite was evaluated using different characterization techniques to determine its thermal (TG/DTG), structural (BET, XPS and FTIR), crystallographic (XRD), and textural (SEM) properties in natura and post-adsorption. The results obtained through a central composite design (CCD) experiment indicated that the initial concentration of NAP and the adsorbent dosage are significant for the adsorption capacity. The adsorption assays indicated that physisorption, through π-π and hydrophobic interactions, were the main mechanism involved in the NAP adsorption. However, the adjustment to the PSO and Freundlich models, obtained through kinetic and equilibrium studies, indicated that chemisorption also influences the adsorptive process. The thermodynamic study indicated physisorption as the mechanism responsible for the NAP adsorption. Also, the adsorbent has high affinity for the adsorbate and the process is spontaneous and endothermic. The maximum adsorption capacity (q max ) of the green mCS/GO was 334.37 mg g -1 at 20 °C. Furthermore, the green mCS/GO was effectively regenerated with methanol and reused for five consecutive cycles, the percentage of NAP recovery went from approximately 91 to 75% after the fifth cycle. The green composite was also applied in the adsorption of NAP from river water samples, aiming to evaluate the feasibility of the method in real applications. The adsorption efficiency was approximately 70%. From what we know, this it is the first time that a green adsorbent was recycled after the polycyclic aromatic hydrocarbon (PAHs) adsorption process., (© 2022. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

Photocatalysts supported in magnetic nanocomposites for application in environmental remediation processes have been evaluated for removing contaminants due to easy recovery and low toxicity to the ecosystem. In this work, copper oxide (CuO) nanoparticles with photocatalytic properties were decorated on magnetic support constituted by hydroxyapatite (HAP) and ferrite to achieve efficiency in contaminated water remediation under visible light irradiation. First, nanomaterials were obtained by precipitation route, allowing fast and straightforward synthesis. Then, CuO nanoparticles with 6 nm diameter were efficiently decorated on magnetic support (25 nm), showing a high ability to absorb visible light irradiation (bandgap) to promote electronic transition and charge separation. Under visible irradiation, CuO promotes the H 2 O 2 reduction in the conduction band (BC) to form hydroxyl radicals ( • OH), which are responsible for rhodamine B (RhB) dye degradation (> 90% in 60 min). Magnetic hysteresis assays confirmed the magnetic properties of HAP/ferrite support, which enabled the recovery and reuse of the magnetic photocatalyst efficiently up to 3 cycles. Due to low Cu 2+ leaching after the photocatalytic application stage, cytotoxicity assay for the Allium cepa seeds did not exhibit abnormal cells other than those commonly found. Furthermore, the CuO-decorated nanoparticles showed bactericidal activity against S. aureus (Gram-positive) and E. coli (Gram-negative) microorganisms, being more significant for the first one. Thus, the developed nanocomposite of CuO nanoparticles decorated on the magnetic support surface showed to be a complete system for water remediation, acting in contaminant degradation under visible light irradiation and bactericidal control with environmentally friendly characteristics.Graphical abstract CuO nanoparticles decorated on hydroxyapatite/ferrite magnetic support acting as a photocatalytic and bactericidal system., (© 2021. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

The application of one-dimensional (1D) V2O5·nH2O nanostructures as pH sensing material was evaluated. 1D V2O5·nH2O nanostructures were obtained by a hydrothermal method with systematic control of morphology forming different nanostructures: nanoribbons, nanowires and nanorods. Deposited onto Au-covered substrates, 1D V2O5·nH2O nanostructures were employed as gate material in pH sensors based on separative extended gate FET as an alternative to provide FET isolation from the chemical environment. 1D V2O5·nH2O nanostructures showed pH sensitivity around the expected theoretical value. Due to high pH sensing properties, flexibility and low cost, further applications of 1D V2O5·nH2O nanostructures comprise enzyme FET-based biosensors using immobilized enzymes.