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1. Efficient tandem synthesis of 3-alkylaminoprop-2-enamides from 3-trimethylsilylprop-2-ynamides.

Author

Andreev, M., Medvedeva, A., and Safronova, L.

Subjects
*CHEMICAL reactions, *CHEMICAL synthesis, *YNAMIDES, *ORGANIC chemistry, *INTERMEDIATES (Chemistry), *AMINES
Abstract

A tandem synthetic approach to previously unknown 3-aminoprop-2-enamides has been developed. It is based on Si-C desilylation of 3-trimethylsilylprop-2-ynamides and subsequent addition of an amine to the triple bond of intermediate terminal propynamides. The effects of the reaction conditions and amine nature on the efficiency of the process have been studied. [ABSTRACT FROM AUTHOR]

Published
2013
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