1. Advanced Kinetic and Titration Strategies for Assessing the Intrinsic Kinetics on Oxide and Sulfide Catalysts.
- Author
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Cai, Guangming, Broomhead, William T., Chin, Ya-Huei Cathy, and Cai, Haiting
- Subjects
VOLUMETRIC analysis ,METAL sulfides ,CHEMICAL amplification ,SULFIDES ,BRONSTED acids ,TRANSITION metal oxides - Abstract
Found on the surfaces of transition metal oxides or sulfides are metal cations and oxygen or sulfur anions (M
n+ -O2− or Mn+ -S2− ) with diverse catalytic functions as redox sites (Mn+ -O2− → M-□), Brønsted acid sites (M-OH), and Lewis acid–base sites (Mδ+ -O2− ). These active site pairs often work together in catalyzing the chemical transformation in cascade reactions. This article describes several experimental strategies, combining kinetic and titration methods, to decouple the effects of surface site occupation on turnover rates, identify the kinetic bottlenecks, remove the effects arising from deactivation, as well as elucidate the potential participation of multiple types of active sites. Using a correlative approach in connecting the rate dependencies and titration studies, one could pinpoint the key factors that contribute to the rates and interpret the measured rates in terms of molecular events on the surfaces. [ABSTRACT FROM AUTHOR]- Published
- 2023
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