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This study focuses on the role of low-quality calcined Fanja (FNJ) clay in enhancing the behavior of cured cement mortar (CM) and its resistivity to chloride and sulfuric acid attack. Ordinary Portland cement was replaced with different quantities (10%, 25%, 35%, and 50% by weight) of FNJ, which was calcined at different temperatures (620 °C, 760 °C, and 900 °C). After 28 days of curing, all the hardened mortars were immersed in 5% sulfuric acid for up to 12 weeks. Additionally, a rapid chloride permeability test was conducted on the 91-day cured CM and CM-FNJ samples to evaluate the affinity of calcined FNJs to retard the chloride diffusion into CM. The results showed that all samples containing FNJ900 showed better physical and mechanical properties than the control sample, while CM with NFJ760 recorded nearly similar performance as CM-NFJ900. In contrast, the CM-FNJ620 mixtures showed lower properties than those of other mixtures. In addition to the pozzolanic reactivity of the calcined clay, the presence of hematite in the calcined clay strongly contributed to increasing the mechanical properties of the hardened mortar through forming calcium ferrosilicate hydrate binding phase, as confirmed by X-ray diffraction. Moreover, the existence of hematite increased the resistivity of CM against sulfuric acid attack as it acts as a buffer for an acidic medium. Compared with CM-FNJ900, the CM-FNJ760 is recommended for use as it exhibited a higher strength activity index and comparable resistance to accelerated chloride diffusion and sulfuric acid accompanied by lower energy demand and lower CO2 emission, achieving the concept of 'sustainability'. [ABSTRACT FROM AUTHOR]

This study examined low-binder ultrahigh-performance concrete (UHPC) when nanosilica (NS) and/or microsilica (MS) were incorporated in Portland cement (PC) in either binary or ternary blends. Two groups were created for this purpose, and they were divided based on the presence or absence of silica flume (SF). NS was used as a restricted substitute for cement by weight at five different percentages (0%, 0.5%, 1%, 2% and 3%). The total binder was 800 kg/m3, and the ratio of water to binder was 1:5. Results demonstrated that optimum resistance to chloride permeability, gas permeability, sorptivity, water absorption and water penetration came from the 3% UHPC sample. The ternary blends of NS, PC and SF yielded better results than binary PC and NS blends. A 1% NS replacement gave similar effects to the UHPC properties investigated as a 10% MS replacement. [ABSTRACT FROM AUTHOR]

The chloride permeability and microstructure of persulphated phosphogypsum-slag cement concrete (PPSCC), the Portland slag cement concrete (PSCC) and ordinary Portland cement concrete (OPCC) were investigated comparatively. Some test methods were used to evaluate the chloride permeability and explain the relationship between the permeability and microstructure of concrete. The results show that the resistance to chloride penetration in PPSCC is significantly better than that in OPCC, the reasons are as follows: 1) the slag in PPSCC is activated by clinker (alkali activation) and phosphogypsum (sulfate activation), forming more low Ca/Si C-S-H gel and gel pores below 10 nm than OPCC, improving the resistance to chloride penetration; 2) the hydration products of PPSCC have a much stronger binding capacity for chloride ions; and 3) in the same mix proportion, PPSCC has a better workability without large crystals calcium hydroxide in the hydration products, the interfacial transition zone (ITZ) is smoother and denser, which can cut off the communicating pores between the pastes and aggregates. [ABSTRACT FROM AUTHOR]

Presently, ternary-blended concrete is widely accepted as a building material, which is obtained from two well-known materials. It can be used for enhancing the structural properties (mechanical and durability properties) of the concrete as well as increasing the total quantity of the replacement level of cement. It is also useful to eliminate the drawbacks of the particular supplementary cementitious materials through combining with other superior quality material and reducing the overall cost of the concrete production. In this paper, the mechanical and permeability properties of self-compacting concrete (SCC) containing metakaolin (MK), rice husk ash (RHA), and a combination of MK and RHA (1:1 ratio) were evaluated and their interrelationships discussed. For this purpose, different mixtures were prepared with different amounts of MK and RHA and ordinary Portland cement (OPC) was replaced by 5 to 40 % of MK and RHA. As a result of increasing the percentage of MK, RHA, and MK + RHA, the mechanical and permeability properties of SCC improved considerably. One interesting point is observed that the sample incorporating the ternary blend of cement with 15 % MK and 15 % RHA showed better workability and mechanical and permeability properties than that of the normal SCC sample without MK or RHA. This blend was proven to be the optimum combination for achieving maximum synergistic effect. In addition, the linear relationship between chloride penetration in terms of total charge passed and the (SiO + AlO + FeO)/CaO ratio was studied. [ABSTRACT FROM AUTHOR]

This study reports the findings of an experimental study carried out on transport properties of the concretes modified with different calcined non purified kaolins (CK) and commercially available high reactivity metakaolin (MK). CK used in this study were obtained by calcining impure ground kaolins from four different quarries located on kaolin beds of different morphological and geological formations in Turkey. However, commercially available MK produced by thermal treatment of high purity kaolin from Czech Republic was used as reference material. In concrete mix design, the cement was replaced with 5, 10, 15, and 20 % by weight of CK or MK. The gas permeability, water permeability, water sorptivity, and chloride permeability tests were performed at the end of 28 and 90 days of curing periods. The results indicated that the concretes incorporated with different types of calcined kaolins had comparable performance in permeability with MK modified concrete, depending mainly on the type and amount of the mineral admixture used. Moreover, all of the concretes incorporation MK or CK had considerably better permeability than plain concrete regardless of the replacement level. [ABSTRACT FROM AUTHOR]

Sustainability of concrete can be improved by using large volume of fly ash as a replacement of cement and by ensuring enhanced durability of concrete. Durability of concrete containing large volume of class F fly ash is dependent on the design of mixture proportions. This paper presents an experimental study on the effect of mixture proportions on the drying shrinkage and permeation properties of high strength concrete containing large volume of local class F fly ash. Concrete mixtures were designed with and without adjustments in the water to binder ratio (w/b) and the total binder content to take into account the incorporation of fly ash up to 40% of total binder. Concretes, in which the mixture proportions were adjusted for fly ash inclusion achieved equivalent strength of the control concrete and showed enhanced properties of drying shrinkage, sorptivity, water permeability and chloride penetration as compared to the control concrete. The improvement of durability properties was less significant when no adjustments were made to the w/b ratio and total binder content. The results show the necessity of the adjustments in mixture proportions of concrete to achieve improved durability properties when using class F fly ash as a cement replacement. [ABSTRACT FROM AUTHOR]

The interfacial bond characteristics between normal concrete substrate as old concrete and ultra high performance fiber concrete as repair material have been investigated. Normal concrete substrates were first subjected to different surface preparation methods prior to bonding the ultra high performance fiber concrete to form repair composites. The interfacial mechanical bond of the composites was assessed using slant shear and tensile splitting strength tests. In addition, rapid chloride permeability test was performed to ascertain the potential chloride resistance of the composites. The microstructure of the transition zone between the normal concrete and ultra high performance fiber concrete was also studied using scanning electron microscope. The results generally indicate that surface preparation of the substrate is very much required to obtain superior mechanical bond of the composites; whereby the composites with the sand-blasted substrate providing the most superior mechanical bond. The excellent bond of the composite is also evident through the rapid chloride permeability test, as well as confirms by the scanning electron microscope image of the interface. Hence, the ultra high performance fiber concrete exhibits significant potential as an excellent material for repair and rehabilitation of concrete structures. [ABSTRACT FROM AUTHOR]

In the present research work, investigations were carried out to improve the performance of concrete in terms of strength and resistance to chloride-ion-penetration by incorporating metakaolin (MK) as mineral admixture in concrete. Parametric study was carried out by considering w/cm ratio, various percentage of MK and age of concrete as parameters to understand the effect of each parameter. The study was conducted for different water-to-cement metakaolin ratio (w/cm) ratios of 0.32, 0.35, 0.4 and 0.5. The MK proportion was varied from 0 to 15% with an increment of 5% and ages of concrete from 3 to 90 days were considered and experiments performed accordingly. The effects of above said parameters on the various properties of concrete such as workability, compressive strength, chloride penetrability (Rapid chloride permeability test as per ASTM C 1202), pH of concrete and depth of penetration of chloride ions were investigated, and the results of MK concrete were compared with the conventional concrete. From the results, it was observed that MK concrete showed greater strength for higher w/cm ratios (0.4 and 0.5) and its resistance to chloride ion penetration was more or less consistent for all w/cm ratios and the optimal amount of MK resulted significant reduction in chloride ion penetration. A Multiple non-linear regression analysis was used to develop a statistical model to predict the strength and found to have good correlation between the observed and predicted values. It was concluded that the concrete developed in this study have significant potential for use on real time projects. [ABSTRACT FROM AUTHOR]

The effects of glass powder on the strength development, chloride permeability and potential alkali-aggregate reaction expansion of lightweight aggregate concrete were investigated. Ground blast furnace slag, coal fly ash and silica fume were used as reference materials. The replacement of cement with 25% glass powder slightly decreases the strengthes at 7 and 28 d, but shows no effect on 90 d’s. Silica fume is very effective in improving both the strength and chloride penetration resistance, while ground glass powder is much more effective than blast furnace slag and fly ash in improving chloride penetration resistance of the concrete. When expanded shale or clay is used as coarse aggregate, the concrete containing glass powder does not exhibit deleterious expansion even if alkali-reactive sand is used as fine aggregate of the concrete. [ABSTRACT FROM AUTHOR]

Structure characteristics of three kinds of ceramsite with different water absorption and the influence on microstructure of interfacial zone as well as performance of chloride permeability and frost resistance of combined aggregate concrete were investigated. The results show that, dense shell and closed internal pore have sharp effects on lowering water absorption of ceramsite. However, the ceramsite with high water absorption has obvious effect on the densification of interfacial paste which would develop a structure with lower porosity, finer aperture and higher microhardness. Furthermore, the impermeability and frost-resistance of concrete can be improved due to the effect of water absorption and releasing by ceramsite with higher water absorption. [ABSTRACT FROM AUTHOR]

The study presented herein has been carried out in order to investigate the strength development and chloride permeability characteristics of plain and rubberized concretes with and without silica fume. For this purpose, two types of tire rubber, namely crumb rubber and tire chips, were used as fine and coarse aggregate, respectively, in the production of rubberized concrete mixtures which were obtained by partially replacing the aggregate with rubber. Two water-cementitious material (w/cm) ratios (0.60 and 0.40), three moist curing periods (3, 7, and 28 days), four designated rubber contents (0, 5, 15, and 25 by total aggregate volume), two silica fume content (0 and 10% by weight of cement), and five different testing ages (3, 7, 28, 56, and 90 days) were considered as experimental parameters. The results indicated that for a given w/cm ratio and moist curing period, the use of rubber significantly aggravated the chloride ion penetration through concrete but the degree of the rate of the increment of the chloride permeability depended on the amount of the rubber used. When the curing period was extended from 3 to 28 days, the reduction in the magnitude of chloride penetration depth was notably higher for the rubberized concretes, even at a rubber content of as high as 25%. It was also observed that silica fume may be considered as a remedy to enhance the chloride penetration resistance of the rubberized concretes. [ABSTRACT FROM AUTHOR]

The availability of accelerated chloride permeability test and the effect of w/c ratio, incorporation of silica fune, maximum aggregate size and aggregate type on the chloride permeability were studied. The mathematic analysis certifies that there is a linear relationship between accelerated test and natural diffusion. Test results show that the chloride permeability of concrete increases as w/c ratio increases whilst a limited amount of replacement of cement with silica fune, the chloride permeability decreases dramatically. The maximum aggregate size in the range of 8 to 25 mm seems also affect chloride permeability but with a much less significant level. The chloride permeability of silica fume lightweight aggregate concrete is very low, especially the concrete made with dry lightweight concrete. The chloride permeability can be evaluated by this accelerated test method. [ABSTRACT FROM AUTHOR]

It has been reported that cAMP controls the transepithelial Cl conductance in fish intestine (Bakker, R., Groot, J.A., 1984, Am. J. Physiol. 246:G213-G217; Krasny, E.J., Madara, J.L., DiBona, D.L., Frizzell, R.A., 1983, Fed. Proc. 42:1100). In both studies, the cAMP effect was interpreted as an increase in tight junction Cl conductance, because cAMP did not change the membrane potential or membrane resistance ratio. However, the activation of a Cl conductance in the membranes of a subset of the epithelial cells might be difficult to discern from an increase in tight junction Cl conductance. Here we report experiments that were designed to distinguish a tight junction Cl conductance from a membrane Cl conductance in a subpopulation of the epithelial cells. The effect of hypotonicity on the cAMP-induced increase in transepithelial conductance showed that cAMP-induced conductance is located in series with the lateral intercellular spaces. Transepithelial serosa to mucosa direct current caused an increase in resistance due to so-called transport number effects. Forskolin abolished the transport number effects, indicating that cAMP increases the Cl conductance of the tight junctions. Increasing cAMP did not change mannitol fluxes, whereas Cl fluxes more than doubled. Changes in dilution potential and transepithelial resistance demonstrated that the cAMP-induced conductance is specific for Cl and Br as opposed to I, NO, SO and gluconate. In contranst, cytochalasin D also decreased the transepithelial resistance and dilution potential in Nagluconate Ringer's. This demonstrates that cAMP acts on the tight junctions in a more specific manner than cytochalasin D. [ABSTRACT FROM AUTHOR]

K+ and Cl--selective double-barreled microelectrodes were used to study the effect of changes in external K+ concentration on intracellular Cl- activity (aiCl) in epithelial cells of Necturus gallbladder. Decreasing the K+ concentration simultaneously in both bathing solutions produced a decrease in aiCl. Steady-state values of aiCl were related to the values of the chemical potential gradient for K+ (delta microK) across either the apical or the basolateral cell membrane. A similar dependence between aiCl and delta microK appeared when the K+ concentration was changed in the serosal solution only. This indicates that aiCl depends on delta microK across the basolateral membrane. aiCl was virtually independent of the membrane potential. This supports the idea that both the mucosal and the basolateral membranes of Necturus gallbladder cells have very low passive permeabilities to Cl-. These results indicate that the exit of Cl- from Necturus gallbladder cells is driven by delta microK across the basolateral membrane, and suggest that KCl electroneutral coupled mechanism in this membrane plays an important role in transcellular Cl- transport. [ABSTRACT FROM AUTHOR]

A 15% of band 3 protein, the assumed chloride channel, is associated with spectrin, the major peripheral protein of a lattice located at the red cell membrane-cytosol interface, the present study was undertaken to evaluate whether a rearrangement of the lattice modifies the functional property of band 3 protein. Such a rearrangement was modulated by depletion of cell ATP and/or by accumulation of Ca2+ ions within the cell. ATP depletion induces an inhibition of the electroneutral one-for-one chloride exchanges. Neither the modification of red cell morphology due to ATP depletion (discocyte-echinocyte transformation) nor a direct effect of the decrease in internal ATP level can account for this inhibition. On the other hand, it seems reasonable to consider that inhibition is related to the changes in membrane protein organization (formation of heteropolymers) induced by the decrease in ATP level. But it does not appear that the degree of inhibition is modified when this altered assembly of membrane protein is stabilized by disulfide linkages. Accumulation of Ca2+ ions in the cell at a relatively low concentration (10 micro M range) inhibits chloride exchange without apparent modification of the assembly of membrane proteins. This effect of calcium on chloride exchanges is speculatively denoted as a "direct" effect of calcium. Calcium loading of fresh red cells at higher concentrations (500 to 1000 micro M) obtained by use of the ionophore A23187 induces a very strong inhibition of chloride exchanges. In this case, inhibition can be reasonably accounted for by two simultaneous effects of calcium: a "direct" effect which explains half of the inhibition and an "indirect effect due to the formation of membrane protein complexes stabilized by covalent crosslinkages (activation by Ca2+ ions of a transglutaminase). It is interesting to note that intracellular calcium, whatever the level, inhibits electroneutral exchanges of chloride but increases net chloride movements. [ABSTRACT FROM AUTHOR]

From previous studies, it is known that in the diluting segment, Cl-ions are transported from the tubule lumen into the cell together with Na and K via a furosemide-sensitive cotransport system. This carrier-mediated process, located in the luminal cell membrane, is driven by the steep 'downhill' Na gradient (directed from lumen to cell) which is maintained by the ouabain-sensitive Na/K-pump at the peritubular cell membrane. Cl-ions are accumulated within the cell cytosol and are supposed to leave the cell by a Cl-conductive pathway. The present experiments, performed in diluting segments of the isolated perfused frog kidney, demonstrate the existence of a significant Cl-permeability of the peritubular cell membrane and its complete inhibition by anthracene-9-COOH. The data indicate that Cl-reabsorption can be reduced not only by the inhibition of luminal Cl-entry (i.e. by furosemide) but also by the blockade of the passive Cl-exit step across the peritubular cell membrane. Since complete inhibition of Cl-permeability reduces transepithelial uphill Cl-transport only to half, the data disclose the existance of an additional Cl-pathway at the peritubular cell membrane. [ABSTRACT FROM AUTHOR]