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We conducted an experimental investigation to examine the immiscible radial displacement flows of air invading three-dimensional foam in a Hele-Shaw cell. Our study successfully identified three distinct flow regimes. In the initial regime, characterized by relatively low fingertip velocities, the foam underwent a slow displacement through plug flow. During this process, the three-phase contact lines slipped at the cell walls. Notably, we discovered that the air injection pressure exhibited a proportional relationship with the power of the fingertip velocity. This relationship demonstrated excellent agreement with a power law, where the exponent was determined to be 2/3. Transitioning to the second regime, we observed relatively high velocities, resulting in the displacement of the foam as a plug within single layers of foam bubbles. The movement of these bubbles near the cell walls was notably slower. Similar to the first regime, the behavior in this regime also adhered to a power law. In the third regime, which manifested at higher air injection pressures, the development of air fingers occurred through narrow channels. These channels had the potential to isolate the air fingers as they underwent a process of "healing." Furthermore, our results unveiled a significant finding that the width of the air fingers exhibited a continuous scaling with the air injection pressure, irrespective of the flow regimes being observed. [ABSTRACT FROM AUTHOR]

Closed-loop deep borehole heat exchanger (DBHE) systems for producing heat from geothermal sources have the advantage that the heat transfer fluid is contained within the loop. In this study, for the first time, a U-configuration closed-loop DBHE was examined to evaluate the energy produced per unit energy invested from a 2330-m-deep geothermal reservoir in central Alberta, Canada. A detailed earth model where the system is modeled from the surface to the geothermal source is used in a numerical simulation model to understand the efficiency of the process. The results reveal that the fluid flow reaches its highest temperature in the ascending section of the U-loop rather than the bottom section which implies that the insulation on the working fluid should start in the ascending section of the U-loop. The results demonstrate that the closed-loop system can achieve ratios of the energy produced and energy invested of 7 GJ/GJ. Although this efficiency is promising, the absolute amount of heat energy harvested is limited by the loop's heat transfer area in the geothermal reservoir. [ABSTRACT FROM AUTHOR]

The poor stability of organic–inorganic hybrid perovskites hinders its commercial application, which motivates a need for greater theoretical insight into its binding mechanism. To date, the binding mode of organic cation and anion inside organic–inorganic hybrid perovskites is still unclear and even contradictory. Therefore, in this work based on density functional theory (DFT), the binding mechanism between organic cation and anion was systematically investigated through electronic structure analysis including an examination of the electronic localization function (ELF), electron density difference (EDD), reduced density gradient (RDG), and energy decomposition analysis (EDA). The binding strength is mainly determined by Coulomb effect and orbital polarization. Based on the above analysis, a novel 2D linear regression descriptor that Eb = − 9.75Q2/R0 + 0.00053 V∙EHL − 6.11 with coefficient of determination R2 = 0.88 was proposed to evaluate the binding strength (the units for Q, R0, V, and EHL are |e|, Å, bohr3, and eV, respectively), revealing that larger Coulomb effect (Q2/R0), smaller volume of perovskite (V), and narrower energy difference (EHL) between the lowest unoccupied molecular orbital (LUMO) of organic cation and the highest occupied molecular orbital (HOMO) of anion correspond to the stronger binding strength, which guides the design of highly stable organic–inorganic hybrid perovskites. [ABSTRACT FROM AUTHOR]

Hydraulic fracturing is widely used in the exploitation of unconventional reservoirs, such as shale gas and tight gas. However, a full understanding of the activation of natural fractures, prediction of fracture growth, distribution of proppant, and network fracture system effectiveness remain unresolved. The onset of fracturing in the media requires energy and this is due to the buildup of pressure within the rock due to continuous injection of fluid. In other words, when the energy associated with the injection fluid reaches the fracture strength of the rock, the fracture initiates and propagates into the formation. Here, we use gelatin in hydraulic fracturing laboratory tests and compare the results to a modified radial hydraulic fracturing theory. The mechanics of the gelatin, procedures to make a testing gelatin block, and procedures to conduct the test are described. The results show that the fracture evolving behaviours from experiments are well matched by the theory. The results are then scaled up to understand fracture growth behaviour in a tight rock reservoir. [ABSTRACT FROM AUTHOR]

The use of cellulose microcrystal suspensions has two advantages for displacement of viscous oil from porous media—first, it viscosifies the aqueous phase thus improving the mobility ratio and second, it reduces the interfacial tension between the phases leading to improved capillary number. Here we examine oil displacement both macroscopically and microscopically to understand the interface between oil and cellulose microcrystal and in particular, the formation of stable microemulsions at the interface. The results show that microcrystal suspensions improve the displacement of oil from porous media over that of water alone and the reason for this is the formation of a viscous microcrystal microemulsion phase that forms at the interface. This high viscosity phase improves the mobility ratio of the system locally at the interface raising the efficiency of oil displacement. [ABSTRACT FROM AUTHOR]

There are two basic requirements for heavy-oil recovery processes: first, mobilize the bitumen, and second, have a drive mechanism deliver the mobilized bitumen to a production wellbore. In situ combustion has the potential to be an important heavy-oil recovery method. Before design of in situ combustion recovery processes can start, it is necessary as a first step to understand the kinetics of various complex chemical reactions and determine kinetic constants associated with the reactions. Even with modern reservoir simulation capabilities, this is a significant challenge. In this research, an Athabasca bitumen combustion tube experiment, conducted by the ISC Research Group at the University of Calgary, was history matched by using a reservoir thermal simulator to determine a set of kinetic parameters as well as the transport parameters for the system. The main results of the history match was a match of air injection rate, bitumen and gas production volumes, average product gas compositions, temperature profiles along the tube through time, and pressure. Gridding sensitivities were examined to determine if the derived kinetic and transport parameters were dependent on gridblock size. The results revealed that the grid was refined enough to sufficiently capture thermal, mass transfer, and reaction length scales. After this single match was achieved, the same constants were used to successfully predict several other combustion tube experiments. The results suggest that the fuel (coke) for high-temperature oxidation (HTO) originates mainly from low-temperature oxidation (LTO) and not from thermal cracking. This implies that the major control on HTO is upstream oxygen transfer into the LTO region. If LTO does not occur, then a relatively small amount of coke is deposited in the matrix due to thermal cracking and this may be insufficient to start or sustain HTO. [ABSTRACT FROM AUTHOR]

In response to recent advances in understanding relating to the remarkable persistence of soil organic matter during burial and diagenesis, we examine the extent to which bitumen compositionally reflects the soil organic matter from which it was derived. Through a simple set of experiments, exposure of bitumen to lipase and cellulase, two enzymes effective in the biodegradation of soil organic matter, resulted in the release of glycerin, palmitic and oleic fatty acids from lipase digestion in addition to the release of glucose, alkylphenols and acyclic polyols from fermentation with cellulase, consistent with the products expected these enzymes. These results are significant in that they suggest that heavy oils are more similar to their soil precursor than previously thought, that biodegradation of bitumen can be accelerated using common over the counter enzymes in aerobic conditions and that heavy oils, which are 1000 times more abundant than coal, can release similar biomolecules as those generated in bioreactor culture or biomass harvest, using two of the most abundantly produced enzymes presently available. [ABSTRACT FROM AUTHOR]