1. n-Type AlCuFeMn Medium-Entropy Alloy with Reduced Thermal Conductivity: A Prospective Thermoelectric Material.
- Author
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Swarnakar, Palash, Ojha, Abhigyan, De, Partha Sarathi, Bathula, Sivaiah, and Roy, Amritendu
- Subjects
TRANSPORT theory ,THERMAL conductivity ,HEAT recovery ,THERMOELECTRIC materials ,AB-initio calculations - Abstract
Developing affordable thermoelectric (TE) materials is critical for efficient waste heat recovery in industries. With the goal of developing novel, affordable TE materials, the present experimental–theoretical investigation, for the first time, presents a rigorous analysis of the electrical and thermal transport properties of a multi-principal-component AlCuFeMn alloy (MPCA). TE properties related to electronic transport, including the Seebeck coefficient, electrical conductivity, and thermal conductivity, were measured on a vacuum-cast sample and were computed using semi-classical Boltzmann transport theory. Additionally, ab initio calculations were performed to calculate the lattice thermal conductivity. The alloy demonstrated overall thermal conductivity of < 4 W/mK, comparable to conventional thermoelectric materials, while the computed lattice thermal conductivity was < 1 W/mK. Such low thermal conductivity may be attributed to the complex microstructure as well as the uniform distribution of aluminium in the matrix. The power factor of the alloy, however, was small (< 0.1 mW/mK
2 ), translating to a low figure of merit (ZT ~ 0.01). Our study indicates that composition engineering can potentially improve the power factor and thus the overall TE response in an AlCuFeMn alloy. [ABSTRACT FROM AUTHOR]- Published
- 2025
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