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Biofouling has been referred to as "the Achilles heel" of reverse osmosis (RO) membrane technology; the main cause being polyamide RO membranes lack of chlorine tolerance. Biofouling increases the operating cost of water treatment by increasing RO system feed pressure (i.e., energy demand) and increasing membrane cleaning frequency, which increases downtime and reduces membrane useful life. For waters with known high biofouling potential, plant designs also may require more extensive pretreatment, which increases capital and operating costs as well as the footprint of a desalination plant. It is known from the literature that the three keys to fending off biofouling in RO systems and/or recovering from biofouling once it takes root include (1) understanding site-specific processes governing biofilm formation, (2) implementing effective biofouling pretreatment ahead of RO membranes, and (3) monitoring biofouling to enable more proactive and effective RO membrane cleaning. Herein, we present four case studies of RO membrane biofouling in seawater, municipal wastewater, brackish groundwater and industrial wastewater. Next, we describe what is known about the causes and consequences of bacterial biofilm formation and growth through a process level RO membrane biofouling model. Finally, we review common biofouling control methods including pre-treatment, chemical cleaning and the most common strategies for monitoring biofouling in RO membrane systems. [ABSTRACT FROM AUTHOR]

Ensuring safe water supply for communities across the United States is a growing challenge due to aging infrastructure, impaired source water, strained community finances, etc. In 2019, about 6% of public water utilities in the U.S. had a health-based violation. Due to the high risk of exposure to various contaminants in drinking water, point-of-use (POU) drinking water treatment is rapidly growing in popularity in the U.S. and beyond. POU treatment technologies include various combinations of string-wound sediment filters, activated carbon, modified carbon, ion exchange and redox media filters, reverse osmosis membranes, and ultraviolet lamps depending on the contaminants of concern. While the technologies are well-proven, highly commoditized, and cost-effective, most systems offer little in the way of real-time performance monitoring or interactive technology like other smart home appliances (e.g., thermostats, smoke detectors, doorbells, etc.). Herein, we review water quality regulations and violations in the U.S. as well as state-of-the-art POU technologies and systems with an emphasis on their effectiveness at removing the contaminants most frequently reported in notices of violations. We conclude by briefly reviewing emerging smart water technologies and the needs for advances in the state-of-the-art technologies. The smartness of commercially available POU water filters is critiqued and a definition of smart water filter is proposed. [ABSTRACT FROM AUTHOR]

Here, we present a review of the antibacterial effects of silver nanomaterials, including proposed antibacterial mechanisms and possible toxicity to higher organisms. For purpose of this review, silver nanomaterials include silver nanoparticles, stabilized silver salts, silver–dendrimer, polymer and metal oxide composites, and silver-impregnated zeolite and activated carbon materials. While there is some evidence that silver nanoparticles can directly damage bacteria cell membranes, silver nanomaterials appear to exert bacteriocidal activity predominantly through release of silver ions followed (individually or in combination) by increased membrane permeability, loss of the proton motive force, inducing de-energization of the cells and efflux of phosphate, leakage of cellular content, and disruption DNA replication. Eukaryotic cells could be similarly impacted by most of these mechanisms and, indeed, a small but growing body of literature supports this concern. Most antimicrobial studies are performed in simple aquatic media or cell culture media without proper characterization of silver nanomaterial stability (aggregation, dissolution, and re-precipitation). Silver nanoparticle stability is governed by particle size, shape, and capping agents as well as solution pH, ionic strength, specific ions and ligands, and organic macromolecules—all of which influence silver nanoparticle stability and bioavailability. Although none of the studies reviewed definitively proved any immediate impacts to human health or the environment by a silver nanomaterial containing product, the entirety of the science reviewed suggests some caution and further research are warranted given the already widespread and rapidly growing use of silver nanomaterials. [ABSTRACT FROM AUTHOR]

Rapid growth in nanotechnology is increasing the likelihood of engineered nanomaterials coming into contact with humans and the environment. Nanoparticles interacting with proteins, membranes, cells, DNA and organelles establish a series of nanoparticle/biological interfaces that depend on colloidal forces as well as dynamic biophysicochemical interactions. These interactions lead to the formation of protein coronas, particle wrapping, intracellular uptake and biocatalytic processes that could have biocompatible or bioadverse outcomes. For their part, the biomolecules may induce phase transformations, free energy releases, restructuring and dissolution at the nanomaterial surface. Probing these various interfaces allows the development of predictive relationships between structure and activity that are determined by nanomaterial properties such as size, shape, surface chemistry, roughness and surface coatings. This knowledge is important from the perspective of safe use of nanomaterials. [ABSTRACT FROM AUTHOR]

Hybrid zeolite-polyamide thin film nanocomposite (TFN) reverse osmosis membranes were synthesized by incorporating Linde type A (LTA)-type zeolite molecular sieve nanocrystals in the interfacial polymerization reaction used to form polyamide thin films. Nanocrystals were prepared with two different mobile cations (Na+ and Ag+) exchanged within the LTA crystal matrix. Incorporation of molecular sieve nanocrystals into polyamide thin films during interfacial polymerization was verified by infrared spectroscopy. Both TFN membranes exhibited higher water permeability, while maintaining similar salt rejection to pure polyamide thin film composite membranes. Nanocomposite thin films containing LTA nanocrystals in the silver form (AgA) produced a greater increase in water permeability than those in the sodium form (NaA). Furthermore, AgA-TFN membranes exhibited more hydrophilic and smooth interfaces, which appeared to inhibit adhesion of bacteria cells onto the membranes. The AgA nanocrystals exhibited significant bactericidal activity; however, when encapsulated within polyamide thin films the antimicrobial activity was significantly reduced. [ABSTRACT FROM AUTHOR]