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Although molecular vibronic spectra generation is pivotal for chemical analysis, tackling such exponentially complex tasks on classical computers remains inefficient. Quantum simulation, though theoretically promising, faces technological challenges in experimentally extracting vibronic spectra for molecules with multiple modes. Here, we propose a nontrivial algorithm to generate the vibronic spectra using states with zero displacements (squeezed vacuum states) coupled to a linear optical network, offering ease of experimental implementation. We also fabricate an integrated quantum photonic microprocessor chip as a versatile simulation platform containing 16 modes of single-mode squeezed vacuum states and a fully programmable interferometer network. Molecular vibronic spectra of formic acid and thymine under the Condon approximation are simulated using the quantum microprocessor chip with high reconstructed fidelity (> 92%). Furthermore, vibronic spectra of naphthalene, phenanthrene, and benzene under the non-Condon approximation are also experimentally simulated. Such demonstrations could pave the way for solving complicated quantum chemistry problems involving vibronic spectra and computational tasks beyond the reach of classical computers. Proof-of-principle photonic quantum simulations of molecular vibronic spectra have been realised, but scalability to more complex systems is hindered by the difficulties in generating squeezed coherent states with multiple modes. Here, the authors demonstrate an alternative approach relying on vacuum-squeezed state. [ABSTRACT FROM AUTHOR]

Self-testing allows one to characterise quantum systems under minimal assumptions. However, existing schemes rely on quantum nonlocality and cannot be applied to systems that are not entangled. Here, we introduce a robust method that achieves self-testing of individual systems by taking advantage of contextuality. The scheme is based on the simplest contextuality witness for the simplest contextual quantum system—the Klyachko-Can-Binicioğlu-Shumovsky inequality for the qutrit. We establish a lower bound on the fidelity of the state and the measurements as a function of the value of the witness under a pragmatic assumption on the measurements. We apply the method in an experiment on a single trapped 40Ca+ using randomly chosen measurements and perfect detection efficiency. Using the observed statistics, we obtain an experimental demonstration of self-testing of a single quantum system. [ABSTRACT FROM AUTHOR]

Concept: MNDO-based semi-empirical methods in quantum chemistry have found widespread application in the modelling of large and complex systems. A method for the analytic evaluation of first and second derivatives of molecular properties against semi-empirical parameters in MNDO-based NDDO-descendant models is presented, and the resultant parameter Hessian is compared against the approximant currently used in parameterization for the PMx models. Methods: As a proof of concept, the exact parameter Hessian is employed in a limited reparameterization of MNDO for the elements C, H, N, O and F using 1206 molecules for reference data (heats of formation, ionization energies, dipole moments and reference geometries). The correctness of our MNDO implementation was verified by comparing the calculated molecular properties with the MOPAC program. [ABSTRACT FROM AUTHOR]

Quantum logic gates are backbones of quantum information processing (QIP), wherein the typical three-qubit Fredkin and Toffoli gates are essential in quantum computation and communication. So far, the quantum Fredkin gate has only been demonstrated with pre-entangled input states in free-space optics, which limits its usage for independent input photons. Here, we put forward an exquisite scheme and experimentally perform a proof-of-principle demonstration of three-qubit Fredkin and Toffoli gates on a programmable quantum photonic chip. Our scheme can also be used to realize a series of other two-qubit quantum gates. Our work sheds light on the merits of quantum photonic chip in implementing quantum logic gates, and paves the way for advanced quantum chip processors. [ABSTRACT FROM AUTHOR]

In recent experiments, the compression from qutrit to qubit is realized by the autoencoder. Inspired by the idea of dimensionality reduction, we apply the rotation transformation to compress the states. Starting from Lie algebra, we construct a 3*3 unitary matrix acting on 3*1 state and realize the rotation transformation of the states and then achieve compression of 3*1 state. Each rotation of a state is a compression, and each compression-only needs to adjust two parameters. According to the compression of 3*1 and 4*1 states by unitary matrices, we further discuss the compression law of N*1 states by unitary matrices. In the process of compression, we can adjust the form of the unitary matrix according to the system condition to change the compression position. In this paper, we focus on the compression law along the diagonal from top to bottom. We redesigned the autoencoder and added the waveplate combination to reduce the parameters without affecting the results and achieve the purpose of state compression. [ABSTRACT FROM AUTHOR]

Quantum thermodynamics has emerged as a separate sub-discipline, revising the concepts and laws of thermodynamics, at the quantum scale. In particular, there has been a disruptive shift in the way thermometry, and thermometers are perceived and designed. Currently, we face two major challenges in quantum thermometry. First, all of the existing optimally precise temperature probes are local, meaning their operation is optimal only for a narrow range of temperatures. Second, aforesaid optimal local probes mandate complex energy spectrum with immense degeneracy, rendering them impractical. Here, we address these challenges by formalizing the notion of global thermometry leading to the development of optimal temperature sensors over a wide range of temperatures. We observe the emergence of different phases for such optimal probes as the temperature interval is increased. In addition, we show how the best approximation of optimal global probes can be realized in spin chains, implementable in ion traps and quantum dots. Existing low-temperature thermometers can only perform with high precision within a narrow range. Here, the authors provide a bound for global thermometry across a wide range, including the design of optimal thermometers with the state-of-the-art quantum technologies. [ABSTRACT FROM AUTHOR]

We study an experimentally feasible qubit system employing neutral atomic currents. Our system is based on bosonic cold atoms trapped in ring-shaped optical lattice potentials. The lattice makes the system strictly one dimensional and it provides the infrastructure to realize a tunable ring-ring interaction. Our implementation combines the low decoherence rates of neutral cold atoms systems, overcoming single site addressing, with the robustness of topologically protected solid state Josephson flux qubits. Characteristic fluctuations in the magnetic fields affecting Josephson junction based flux qubits are expected to be minimized employing neutral atoms as flux carriers. By breaking the Galilean invariance we demonstrate how atomic currents through the lattice provide an implementation of a qubit. This is realized either by artificially creating a phase slip in a single ring, or by tunnel coupling of two homogeneous ring lattices. The single qubit infrastructure is experimentally investigated with tailored optical potentials. Indeed, we have experimentally realized scaled ring-lattice potentials that could host, in principle, n ∼ 10 of such ring-qubits, arranged in a stack configuration, along the laser beam propagation axis. An experimentally viable scheme of the two-ring-qubit is discussed, as well. Based on our analysis, we provide protocols to initialize, address, and read-out the qubit. [ABSTRACT FROM AUTHOR]

Optical orbital angular-momentum (OAM) has more complex mechanics than the spin degree of photons, and may have a broad range of application. Manipulating atomic states via OAM has become an interesting topic. In this paper, we first review the general theory of generating adiabatic gauge field in ultracold atomic systems by coupling atoms to external optical fields with OAM, and point out the applications of the generated adiabatic gauge field. Then, we review our work in this field, including the generation of macroscopic superposition of vortex-antivortex states and spin Hall effect (SHE) in cold atoms. [ABSTRACT FROM AUTHOR]

Topological Thouless pumping and Aharonov–Bohm effect are both fundamental effects enabled by the topological properties of the system. Here, we study both effects together: topological pumping of interacting particles through Aharonov–Bohm rings. This system can prepare highly entangled many-particle states, transport them via topological pumping and interfere with them, revealing a fractional flux quantum. The type of the generated state is revealed by non-trivial Aharonov–Bohm interference patterns that could be used for quantum sensing. The reflections induced by the interference result from transitions between topological bands. Specific bands allow transport with a band gap scaling as the square-root of the particle number. Our system paves a new way for a combined system of state preparation and topological protected transport. Topological pumping and Aharonov–Bohm effect are fundamental effects enabled by the topological properties of a system. The authors combine these two concepts to study an interacting ring-lead system pierced by a synthetic magnetic field, finding that particle transport is substantially affected by entanglement and interaction. [ABSTRACT FROM AUTHOR]

Quantum entanglement is usually considered a fragile quantity and decoherence through coupling to an external environment, such as a thermal reservoir, can quickly destroy the entanglement resource. This doesn't have to be the case and the environment can be engineered to assist in the formation of entanglement. We investigate a system of qubits and higher dimensional spins interacting only through their mutual coupling to a reservoir. We explore the entanglement of multipartite and multidimensional system as mediated by the bath and show that at low temperatures and intermediate coupling strengths multipartite entanglement may form between qubits and between higher spins, i.e., qudits. We characterise the multipartite entanglement using an entanglement witness based upon the structure factor and demonstrate its validity versus the directly calculated entanglement of formation, suggesting possible experiments for its measure. [ABSTRACT FROM AUTHOR]

In this Article, the equation following the sentence "The extra damping introduced can be written as:" was incorrect and should have appeared as shown in the correction notice. [ABSTRACT FROM AUTHOR]

According to the principle of weak measurement, when coupling the orbital angular momentum (OAM) state with a well-defined pre-selected and post-selected system of a weak measurement process, there will be an indirect coupling between position and topological charge (TC) of OAM state. Based on this we propose an experiment scheme and experimentally measure the TC of OAM beams from −14 to 14 according to the weak measurement principle. After the experiment the intrinsic OAM of the beams changed very little. Weak measurement, Topological Charge, OAM beams. [ABSTRACT FROM AUTHOR]

Quantum sealed-bid auction (QSA) has been widely studied in quantum cryptography. For a successful auction, post-confirmation is regarded as an important mechanism to make every bidder verify the identity of the winner after the auctioneer has announced the result. However, since the auctioneer may be dishonest and collude with malicious bidders in practice, some potential loopholes could exist. In this paper, we point out two types of collusion attacks for a particular post-confirmation technique with EPR pairs. And it is not difficult to see that there exists no unconditionally secure post-confirmation mechanism in the existing QSA model, if the dishonest participants have the ability to control multiparticle entanglement. In the view of this, we note that some secure implementation could exist if the participants are supposed to be semi-quantum, i.e., they can only control single photons. Finally, two potential methods to design post-confirmation mechanism are presented in this restricted scenario. [ABSTRACT FROM AUTHOR]

This corrects the article DOI: 10.1038/srep38356 [ABSTRACT FROM AUTHOR]

Hybrids consisting of macroscopic superconducting circuits and microscopic components, such as atoms and spins, have the potential of transmitting an arbitrary state between different quantum species, leading to the prospective of high-speed operation and long-time storage of quantum information. Here we propose a novel hybrid structure, where a neutral-atom qubit directly interfaces with a superconducting charge qubit, to implement the qubit-state transmission. The highly-excited Rydberg atom located inside the gate capacitor strongly affects the behavior of Cooper pairs in the box while the atom in the ground state hardly interferes with the superconducting device. In addition, the DC Stark shift of the atomic states significantly depends on the charge-qubit states. By means of the standard spectroscopic techniques and sweeping the gate voltage bias, we show how to transfer an arbitrary quantum state from the superconducting device to the atom and vice versa. [ABSTRACT FROM AUTHOR]