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In this work, we prepared different alkyl acrylates by esterifying acrylic acid with different alcohols (decanol, dodecanol, hexadecanol and octadecanol). Anilimide was then produced by the reaction of aniline with maleic anhydride. Different teropolymers were prepared by polymerization reaction of anilimide, different alkyl acrylate esters and olefins in different ratios. The thermal stability of the prepared terpolymers was measured by thermal gravimetric analysis which demonstrated a high thermal stability. The polymers were degraded above 500 °C. The rheology behavior shows shear-thinning, it approaches the ideal Newtonian behavior in case of polymer (C). The prepared terpolymers succeeded in raising the viscosity index of oil to 118 in case of polymer (C) and decreasing the pour point of oil to -12 in case of polymer (E). [ABSTRACT FROM AUTHOR]

Abstract: Growing environmental concerns over the use of mineral oil based lubricants in various fields have led to an increased attention towards the use of environmentally benign bio-lubricants. Working in this direction, the present report describes the synthesis of a homopolymer of almond oil and its copolymers with decyl acrylate. The structures of the prepared polymers were confirmed using FT-IR, NMR, and GPC analysis. Additive performances of each of the prepared polymers as viscosity index improvers and pour point depressants were evaluated by standard ASTM methods. The thermal stability of each of the polymers was investigated. Biodegradability of all the polymers was also tested as per ISO 846:1997 against fungal pathogens. A comparison of their multifunctional performances was also studied and is reported. The copolymers showed better performances as viscosity index improvers and pour point depressants. The thermal stability of the copolymers was also found to be higher than the homopolymer. As expected, the homopolymer showed better biodegradability among the other polymers.Graphical Abstract: [ABSTRACT FROM AUTHOR]

Nine terpolymers consisting of (jojoba: alkylacrylate: α-olefins) backbone were synthesized via free radical chain addition polymerization and determined using Fourier transform infrared spectroscopy, proton nuclear magnetic resonance and gel permeation chromatography, for determination of weight average molecular weight. The alkylacrylates used were (dodecylacrylate, tetradecylacrylate and hexadecylacrylate), while α-olefins used were (dodecene, tetradecene and hexadecane). The monomers' ratio used for polymerization was (1:1:1). It was found that the molecular weight increases with increasing the alkyl chain length of both alkylacrylate and α-olefins used. The thermal stability of the synthesized terpolymers was determined using thermal gravimetric analysis and differential scanning calorimetry. The prepared polymers were evaluated as performance modifiers (viscosity index improvers and pour point depressants) for free additives lube oil (SAE-30). It was found that the viscosity index increases with increasing the alkyl chain length, molecular weight and concentration of used terpolymer. The effect of the prepared terpolymers on the pour point of lube oil was studied and it was found that the pour point of lube decreases (more negative) with decreasing the alkyl chain length of both alkylacrylate and α-olefin used. [ABSTRACT FROM AUTHOR]