1. Comparative Oxidation Kinetics of a NiPtTi High Temperature Shape Memory Alloy.
- Author
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Smialek, James L., Humphrey, Donald L., and Noebe, Ronald D.
- Subjects
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SHAPE memory alloys , *TITANIUM , *PLATINUM , *NICKEL , *OXIDATION , *MATERIALS science - Abstract
high temperature shape memory alloy, Ni–30Pt–50Ti (at.%), with an M near 600 °C, was isothermally oxidized in air for 100 h over the temperature range of 500–900 °C. Nearly parabolic kinetics were observed in log–log and parabolic plots, with no indication of initial fast transient oxidation. On average the rates were about a factor of 4 lower than values measured here for a binary Ni–49Ti commercial SMA. The overall behavior could be best described by the Arrhenius relationships:The activation energy was consistent with literature values for TiO scale growth measured for elemental Ti and some NiTi alloys, at ~210–260 kJ/mol. However, a number of other studies produced activation energies in the range of 135–150 kJ/mol. This divergence may be related to various complex scale layers and depletion zones, however, no specific correlation can be identified at present. [ABSTRACT FROM AUTHOR]
- Published
- 2010
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