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1. One-pot synthesis of functionalized thioureas by reaction of benzoyl isothiocyanates, secondary amines, and alkyl propiolates.

2. Efficient synthesis of ethyl 3-alkyl-4-oxo-2-thioxo-1,3-thiazolane-5-carboxylates from the reaction of carbon disulfide and primary amines in the presence of diethyl 2-chloromalonate.

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