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Volcanic degassing of planetary interiors has important implications for their corresponding atmospheres. The oxidation state of rocky interiors affects the volatile partitioning during mantle melting and subsequent volatile speciation near the surface. Here we show that the mantle redox state is central to the chemical composition of atmospheres while factors such as planetary mass, thermal state, and age mainly affect the degassing rate. We further demonstrate that mantle oxygen fugacity has an effect on atmospheric thickness and that volcanic degassing is most efficient for planets between 2 and 4 Earth masses. We show that outgassing of reduced systems is dominated by strongly reduced gases such as H 2 , with only smaller fractions of moderately reduced/oxidised gases (CO , H 2 O ). Overall, a reducing scenario leads to a lower atmospheric pressure at the surface and to a larger atmospheric thickness compared to an oxidised system. Atmosphere predictions based on interior redox scenarios can be compared to observations of atmospheres of rocky exoplanets, potentially broadening our knowledge on the diversity of exoplanetary redox states. [ABSTRACT FROM AUTHOR]

Lacking plate tectonics and crustal recycling, the long-term evolution of the crust-mantle system of Mars is driven by mantle convection, partial melting, and silicate differentiation. Volcanic landforms such as lava flows, shield volcanoes, volcanic cones, pyroclastic deposits, and dikes are observed on the martian surface, and while activity was widespread during the late Noachian and Hesperian, volcanism became more and more restricted to the Tharsis and Elysium provinces in the Amazonian period. Martian igneous rocks are predominantly basaltic in composition, and remote sensing data, in-situ data, and analysis of the SNC meteorites indicate that magma source regions were located at depths between 80 and 150 km, with degrees of partial melting ranging from 5 to 15 %. Furthermore, magma storage at depth appears to be of limited importance, and secular cooling rates of 30 to 40 K Gyr were derived from surface chemistry for the Hesperian and Amazonian periods. These estimates are in general agreement with numerical models of the thermo-chemical evolution of Mars, which predict source region depths of 100 to 200 km, degrees of partial melting between 5 and 20 %, and secular cooling rates of 40 to 50 K Gyr. In addition, these model predictions largely agree with elastic lithosphere thickness estimates derived from gravity and topography data. Major unknowns related to the evolution of the crust-mantle system are the age of the shergottites, the planet's initial bulk mantle water content, and its average crustal thickness. Analysis of the SNC meteorites, estimates of the elastic lithosphere thickness, as well as the fact that tidal dissipation takes place in the martian mantle indicate that rheologically significant amounts of water of a few tens of ppm are still present in the interior. However, the exact amount is controversial and estimates range from only a few to more than 200 ppm. Owing to the uncertain formation age of the shergottites it is unclear whether these water contents correspond to the ancient or present mantle. It therefore remains to be investigated whether petrologically significant amounts of water of more than 100 ppm are or have been present in the deep interior. Although models suggest that about 50 % of the incompatible species (HO, K, Th, U) have been removed from the mantle, the amount of mantle differentiation remains uncertain because the average crustal thickness is merely constrained to within a factor of two. [ABSTRACT FROM AUTHOR]

Evolutionary scenarios for the major satellites of Jupiter, Saturn, Neptune, and Pluto-Charon are discussed. In the Jovian system the challenge is to understand how the present Laplace resonance of Io, Europa, and Ganymede was established and to determine whether the heat being radiated by Io is in balance with the present tidal dissipation in the moon. In the Saturnian system, Enceladus and Titan are the centers of attention. Tidal heating is the likely source of activity at the south pole of Enceladus, although the details of how the heating occurs are not understood. An evolutionary scenario based on accretion and internal differentiation is presented for Titan, whose present substantial orbital eccentricity is not associated with any dynamical resonance. The source and maintenance of methane in Titan's present atmosphere remain uncertain. Though most attention on the Saturnian moons focuses on Titan and Enceladus, the mid-size satellites Iapetus, Rhea, Tethys, and the irregular satellite Phoebe also draw our interest. An evolutionary scenario for Iapetus is presented in which spin down from an early rapidly rotating state is called upon to explain the satellite's present oblate shape. The prominent equatorial ridge on Iapetus is unexplained by the spin down scenario. A buckling instability provides another possible explanation for the oblateness and equatorial ridge of Iapetus. Rhea is the only medium-size Saturnian satellite for which there are gravity data at present. The interpretation of these data are uncertain, however, since it is not known if Rhea is in hydrostatic equilibrium. Pluto and Charon are representative of the icy dwarf planets of the Kuiper belt. Did they differentiate as they evolved, and do either of them have a subsurface liquid water ocean? New Horizons might provide some answers when it arrives at these bodies. [ABSTRACT FROM AUTHOR]