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Amine absorption processes are widely used to purify both refinery and process gases and natural gas. Recently, amine absorption has also been considered for application to CO removal from flue gases. It has a number of advantages, but there is one major disadvantage-high energy consumption. This can be solved by using an appropriate solvent. From a group of several dozen solutions, seven amine solvents based on primary amine, tertiary amine and sterically hindered amine were selected. For the selected solutions research was conducted on CO absorption capacity, an absorption rate and finally a solvent vapor pressure. Furthermore, tests on an absorber-desorber system were also performed. In this study the most appropriate solvent for capturing CO from flue gases with higher carbon dioxide concentrations was selected. [ABSTRACT FROM AUTHOR]

With regard to the climate policy that has been adopted, the implementation of the carbon capture and storage and carbon capture and utilization technologies seems to be the unavoidable solution to reduce emissions from the energy sector. As most Polish energy is derived from coal, the government has taken steps to reduce CO emissions by initiating a strategic research program-'Advanced technologies for energy generation: Development of a technology for highly efficient zero-emission coal-fired power units integrated with CO capture.' This paper presents the results of an investigation of a process for continuous removal of CO from the gas stream on a laboratory unit. This study was conducted at the Institute for Chemical Processing of Coal in Zabrze, Poland. The purpose of the tests that were conducted was to establish the effect of the sorption column load on CO recovery and on the process regeneration heat duty. In the second part of the paper, a simple comparison of three amine solvents is presented as a part of the solvent selection process for further pilot plant tests. [ABSTRACT FROM AUTHOR]

As a part of the strategic research program 'Advanced technologies for energy generation: Development of a technology for highly efficient zero-emission coal-fired power units integrated with CO capture', a mobile CO absorption pilot plant was erected. The main purpose of the pilot plant was to demonstrate the post-combustion technology in conjunction with a coal-fired power plant. The pilot plant captured CO by chemical absorption in amine-based solvents, which was considered to be the best adapted technology to the requirements of coal-fired power plants and suitable for retrofitting to existing units. The pilot plant captured up to 1000 kg/day of CO from the power plant's flue gases with CO recovery exceeding 90 %. The flexible process flowsheet of the pilot plant offered high potential for the validation of various improvements, which were designed to reduce the process energy demand and to increase the CO recovery. This paper summarizes the initial operation experience at the TAURON Łaziska Power Plant in Poland. Selected first results obtained are presented and discussed. The initial campaigns utilized 20 and 30 wt% monoethanolamine (MEA) solutions recognized as baseline solvents that were suitable for comparative purposes. The initial campaigns at the pilot plant successfully demonstrated reliable operation and promising results. [ABSTRACT FROM AUTHOR]

The densities of aqueous mixtures of aminoethylethanolamine (CAS #000111-41-1) were measured over the entire compositional range at temperatures of 283.15-343.15 K. The results of these measurements were used to calculate excess molar volumes and isobaric thermal expansion coefficients, and partial molar and apparent molar volumes and excess isobaric thermal expansion coefficients were subsequently derived. The excess molar volumes were correlated as a function of the mole fraction using the Redlich-Kister equation. Temperature dependences of the Redlich-Kister coefficients are also presented. The partial molar volumes at infinite dilution of AEEA in water were determined using two different methods. In addition, the solution density was correlated using a Joubian-Acree model. Aqueous solutions of AEEA exhibit similar properties to the aqueous solutions of other alkanolamines (like monoethanolamine) used in acid gas sweetening. [ABSTRACT FROM AUTHOR]