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The growing need for energy and the depletion of oil wells necessitate advanced Enhanced Oil Recovery (EOR) techniques, particularly water and polymer flooding, which play a crucial role in augmenting hydrocarbon recovery rates. However, water flooding in high-permeability layers often leads to water breakthroughs, reduced sweep efficiency, and the formation of preferential channels, posing significant challenges to oil recovery and reservoir management. Conformance control treatments, including the use of polymer microspheres, offer a promising solution by sealing high-permeability zones and enhancing sweep efficiency. This study focuses on the application of fluorescent polymer microspheres based on polyacrylamide, which is extensively employed in the oil sector as an oil displacement agent. Fluorescent polymers called Poly 400, Poly 200, and Poly 600, incorporating cationic methacrylamide monomers, were synthesized through copolymerization to create amphiphilic polymers with enhanced stability and functionality. These fluorescent polymers were evaluated through flooding tests using a quarter-five-spot model of transparent quartz glass under UV light, allowing for instantaneous measurement and observation of fluorescence intensity. At reservoir conditions, the oil displacement experiments confirm that the incremental oil after water flooding by Poly 400, Poly 200, and Poly 600, is 13.1%, 9.1%, and 6.1% of OOIP respectively. The findings showed that fluorescent polymer microspheres could efficiently target high-permeability layers, adapt to varying pore throat sizes, and improve the plugging rate of high-permeability channels, thereby optimizing oil recovery. A subsequent simulation study using the CMG simulator provided further insights into the efficacy of these fluorescent polymers as EOR agents, revealing their potential to enhance sweep efficiency and enhance oil recovery. Simulation results showed that oil saturation decreased from 68% (initial) to 13.5%, 16.1%, and 18.3% after Poly 400, Poly 200, and Poly 600 flooding respectively. This work highlights the potential of fluorescent polymer microspheres as a valuable tool for EOR applications, offering significant advancements in reservoir management and oil recovery optimization. [ABSTRACT FROM AUTHOR]

Despite recent advancements, artificial muscles have not yet been able to strike the right balance between exceptional mechanical properties and dexterous actuation abilities that are found in biological systems. Here, we present an artificial magnetic muscle that exhibits multiple remarkable mechanical properties and demonstrates comprehensive actuating performance, surpassing those of biological muscles. This artificial muscle utilizes a composite configuration, integrating a phase-change polymer and ferromagnetic particles, enabling active control over mechanical properties and complex actuating motions through remote laser heating and magnetic field manipulation. Consequently, the magnetic composite muscle can dynamically adjust its stiffness as needed, achieving a switching ratio exceeding 2.7 × 10³. This remarkable adaptability facilitates substantial load-bearing capacity, with specific load capacities of up to 1000 and 3690 for tensile and compressive stresses, respectively. Moreover, it demonstrates reversible extension, contraction, bending, and twisting, with stretchability exceeding 800%. We leverage these distinctive attributes to showcase the versatility of this composite muscle as a soft continuum robotic manipulator. It adeptly executes various programmable responses and performs complex tasks while minimizing mechanical vibrations. Furthermore, we demonstrate that this composite muscle excels across multiple mechanical and actuation aspects compared to existing actuators. Artificial muscles often struggle to match the performance of biological systems. Here, the authors report an artificial magnetic muscle that shows remarkable mechanical and actuating capabilities, comparable to natural muscles. [ABSTRACT FROM AUTHOR]

Heavy metals are particularly damaging contaminants in the environment, and even trace concentrations represent a risk to human health due to their toxicity. To detect the heavy metals of Mn2+ and Co2+ ions, a novel selective reusable paper-based Fluorescence naked-eye sensor based on naphthalene cationic Schiff base (NCSB) was synthesized and confirmed using FT-IR, 1 H-NMR, and MS tools. Based on a blue to colorless color change in the aqueous solution, the NCSB sensor is utilized to Mn2+ and Co2+ cations selectively among other metal ions (Fe2+, Cu2+, Mg2+, Ni2+, Zn2+, Cd2+, Hg2+, Pb2+, Sn2+ and Cr3+). In the aqueous medium, the NCSB sensor displayed high sensitivity, with limits of detection (LOD) values of 0.014 µM (14.08 nM) and 0.041 µM (41.47 nM) for Mn2+ and Co2+ cations, respectively. The paper-based sensor naked-eye detected Mn2+ and Co2+ cations in water at concentrations as low as 0.65 µM (65 nM) and 0.086 µM (86 nM), respectively. It was discovered that 5 min of incubation time and a pH range of 7 to 11 were optimal for the complexation reaction between the Mn2+ and Co2+ ions and the NCSB sensor. Through a static quenching process, the interaction of the different metal ions with the Schiff base group in the NCSB molecule results in the development of a ground-state non-fluorescent complex. NCSB sensor was also successfully applied in analysis of Mn2+ and Co2+ in environmental water with good recoveries of 94.8–105.9%. The theoretical calculations based on density functional theory (DFT) studies are in support of experimental interpretations. The links between the input factors and the anticipated response were evaluated using the quadratic model of the response surface methodology (RSM) modeling. [ABSTRACT FROM AUTHOR]

We report an innovative and facile approach to fabricating an ultrasensitive plasmonic paper substrate for surface-enhanced Raman spectroscopy (SERS). The approach exploits the self-assembling capability of poly(styrene-b-2-vinyl pyridine) block copolymers to form a thin film at the air-liquid interface within the single microdroplet scale for the first time and the subsequent in situ growth of silver nanoparticles (AgNPs). The concentration of the block copolymer was found to play an essential role in stabilizing the droplets during the mass transfer phase and formation of silver nanoparticles, thus influencing the SERS signals. SEM analysis of the morphology of the plasmonic paper substrates revealed the formation of spherical AgNPs evenly distributed across the surface of the formed copolymer film with a size distribution of 47.5 nm. The resultant enhancement factor was calculated to be 1.2 × 107, and the detection limit of rhodamine 6G was as low as 48.9 pM. The nanohybridized plasmonic paper was successfully applied to detect two emerging pollutants—sildenafil and flibanserin—with LODs as low as 1.48 nM and 3.45 nM, respectively. Thus, this study offers new prospects for designing an affordable and readily available, yet highly sensitive, paper-based SERS substrate with the potential for development as a lab-on-a-chip device. [ABSTRACT FROM AUTHOR]

In this work, dispersed nanoparticles of Fe2O3- and TiO2-reinforced linear saturated polyester resin nanocomposites were fabricated. Nanosized oxides of iron (III) and titanium (IV) and polyester resin were prepared throughout sol–gel deposition and polycondensation reactions, respectively. The incorporation of nanostructured metal oxides with polyester matrix was characterized. Molecular weight, structure, composition, morphology and electric property of composites were investigated by gel permeation chromatography, Fourier transform infrared spectroscopy, X-ray diffraction, scanning electron microscopy, transmission electron microscopy and conductivity measurements. The obtained nanocomposites exhibit low crystallinity, high agglomeration and high conductivity due to the ionic cross-linking. Moreover, the biological activity of the fabricated nanocomposites was studied against selected strains of pathogenic bacteria and fungi. The biological effect of polyester nanocomposites has higher value than the free one. These nanocomposites will find potential sites in catalysis. [ABSTRACT FROM AUTHOR]