1. Colorimetric and fluorescence dual-mode pH sensor based on nitrogen-doped carbon dots and its diverse applications.
- Author
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Zhou, Xueying, Pang, Yuanhao, Wang, Yu, Yan, Wenju, Zhang, Yun, Zou, Jianmei, and Yuan, Yali
- Subjects
DOPING agents (Chemistry) ,FLUORESCENCE ,COLORIMETRY ,DETECTORS ,HELA cells ,CARBON ,PHENYLENEDIAMINES - Abstract
A dual-mode pH sensor based on nitrogen-doped carbon dots (N-CDs) with the source of o-phenylenediamine and tryptophan has been constructed. Under the stimulation of pH, the N-CDs exhibited prominent both color and fluorescence changes, leading to the rarely discovered colorimetric and fluorescent dual-readouts for the evaluation of pH. The mathematic relationship was established between pH and fluorescence intensity of N-CDs, and between pH and the UV–Vis absorbance ratio at 630 nm and 488 nm of N-CDs, respectively, over a quite broad pH range of 2.2 to 12.0. Multiple techniques are used to explore the dual-mode pH-responsive mechanism, and the preliminary explanation is put forward. The experimental results show that the N-CDs have visualized pH sensing applicability for actual samples, including various water samples and HeLa cell. Furthermore, the N-CD ink is developed for successful information encryption and anti-counterfeiting. This work might provide valuable insights into the sensing mechanism of CDs, and the application potential of CDs in broader fields. [ABSTRACT FROM AUTHOR]
- Published
- 2023
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