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High bulk papers are attractive because they use less pulp but achieve properties suitable for applications in tissue, filters, and lightweight packaging. This study explores using hydroxypropyl methylcellulose (HPMC), a low-cost and renewably-sourced cellulose derivative, as a surface modifier for mechanical pulps to enhance paper properties. Two application methods were investigated: (1) pre-treatment by adding HPMC to the pulp dispersion and (2) post-treatment by spraying HPMC solution onto paper. Both pre- and post-treated handsheets exhibited improved tensile index and bulk concurrently, which is rarely observed. HPMC adsorbed to the fibre surface spontaneously improving fibre–fibre bonds through polymer entanglement, which led to higher tensile properties. Higher bulk values resulted from preventing fibre collapse during drying (i.e., maintaining open fibre lumens), attributed to the surface activity of HPMC and reinforcement of the fibre cell wall (supported by reduced kinks and curl index upon HPMC adsorption). X-ray tomography showed non-collapsed fibres and symmetric structures in handsheets from fibres pre-treated with HPMC, also suggesting improved cell wall strength and fibres that resisted pressure gradients. These findings indicate that HPMC as a paper additive is a practical and sustainable approach to reinforcing paper products, offering an alternative to high energy refining and oxidizing agents. This approach challenges the traditional trade-off between tensile index and bulk in pulp refining, emphasizing the potential of HPMC as a "green" surface modifier to enhance the strength of bulky papers. [ABSTRACT FROM AUTHOR]

This paper examines the relationship between product life cycle and book-to-market effect on cross-sectional stock returns. While previous papers suggest that the book-to-market effect is related to a firm's market value and fundamental value, this paper examines the product life cycle, which directly affects future cash flows. We find that the book-to-market effect is stronger for firms with a long product life cycle, which is consistent with the mispricing story in explaining the book-to-market effect. We further find that the role of product life cycle is more critical for firms with high investor limited attention, and that the product life cycle in part explains intangible returns. [ABSTRACT FROM AUTHOR]

Wet-strength additives are vital in maintaining the structural integrity of paper and paper-based products in wet conditions. Most wet-strength additives are synthetically produced and pose environmental and human health risks. Therefore, there is a growing interest in developing natural and environment-friendly wet-strength additives for paper. However, the unavoidable replacement of these harmful wet-strength additives with greener materials to achieve similar wet-strength without compromising product performance, with the added option of sustainability, is challenging. This review discusses up-to-date conventional synthetic, natural, and other wet-strength additives used in developing wet-strength in paper-based products. A detailed description of the additive's reaction mechanisms and working principles for achieving the required wet-strength is also analyzed. Moreover, a detailed comparative literature review of the physio-chemical properties of these wet-strength additives is also discussed. Finally, the paper also discusses the challenges associated with bio-based additives in improving the wet-strength of paper-based products, comparing the well-established synthetic wet-strength additives. [ABSTRACT FROM AUTHOR]

Cellulosic-based materials such as hemp fabric and paper have combined characteristics of renewability, biodegradability, flexibility, and recyclability. However, regular products are not suitable for use in unconventional applications due to inherent limitations, and accordingly, enabling new capabilities is a necessity. To this end, the conversion of regular hemp fabric and paper into high-strength products with hydrophobic function via surface engineering was explored. The fluorinated waterborne polyurethane (FWPU) emulsions were first synthesized as functional coatings by in-situ polymerization. The structure and properties of the FWPU emulsion and film were characterized by FTIR, XRD, SEM, TG, and XPS. The results showed that the grafting of perfluorooctanol imparts WPU film excellent hydrophobicity, and the water contact angle increases from 71.2° to 105.9°. After the FWPU coating, the water contact angles of the hemp fabric and paper increase from 0° to 117.1° and 112.8°, respectively. Quite encouragingly, the coating generation of waterborne polyurethane-derived functional additives led to the increase of mechanical strength by more than 23% and 82%, in the case of qualitative filter paper and hemp fabric. Meanwhile, the folding strength of filter paper is increased by 132 times. Overall, this functionalized waterborne polyurethane coating would direct paper and hemp fabric toward diversified applications. [ABSTRACT FROM AUTHOR]

The indicators of adhesion of adhesives based on copolymers of sodium 2-acrylamido-2-methylpropane sulfonate with acrylamide, methacrylamide, and sodium acrylate and methacrylate to silicate glass and paper products depending on the chemical nature of the comonomer and ratio of the monomer units in a macromolecule are determined. [ABSTRACT FROM AUTHOR]

Existing literature ignores to consider multiple types of pollutants when analyzing energy efficiency and its convergence. Under this background, using SuperSBM-GML model, the improved entropy method, and convergence model, this paper calculates the green total-factor energy efficiency and its evolution trend of 35 China's industrial sub-sectors considering multiple pollutants, and analyzes its convergence. The results indicate that the average score of industrial green total-factor energy efficiency is low, and there are significant differences among sub-sectors: "Utilization of waste resources" is the highest, while "Manufacture of paper and paper products" is the lowest. The green total-factor energy efficiency shows an overall upward trend from 2006 to 2021, the main driving force comes from technological progress, but numerous sub-sectors have not sufficiently caught up with existing cutting-edge technologies. Specifically, the growth rate of green total-factor energy efficiency in high-energy-consumption sub-sectors is higher than low-to-medium-energy-consumption sub-sectors. There are both σ-convergence and β-convergence in low-to-medium-energy-consumption group, indicating that development of sub-sectors is stable and outstanding. Nevertheless, the high-energy-consumption group only exhibits conditional β-convergence, revealing an imbalance in energy efficiency development. Consequently, formulating the benchmark level of energy efficiency and developing energy efficiency "leader" system are suggested for low-to-medium and high-energy-consumption sub-sectors, respectively. [ABSTRACT FROM AUTHOR]

The Gutenberg-Jahrbuch 2023, published by the Internationale Gutenberg-Gesellschaft, covers a wide range of topics related to the history of printing, book publishing, printers, and incunabula. The volume includes eleven articles and a review of recent research, with contributions in English, German, French, and Italian. Topics covered include the publications of Richard de Bury's Philobiblon, charges of blood libel and host desecration against Jews, the increase in paper products for book printers, illustrated books, German culinary recipes, and the identity of the author of a treatise on logic. The volume is well-regarded for its scholarly quality, but there are some issues with typos and mistakes in grammar and syntax. [Extracted from the article]

This paper concerns product constructions within the continuous-logic framework of Ben Yaacov, Berenstein, Henson, and Usvyatsov. Continuous-logic analogues are presented for the direct product, direct sum, and almost everywhere direct product analyzed in the work of Feferman and Vaught. These constructions are shown to possess a number of preservation properties analogous to those enjoyed by their classical counterparts in ordinary first-order logic: for example, each product preserves elementary equivalence in an appropriate sense; and if for i ∈ N M i is a metric structure and the sentence θ is true in ∏ i = 0 k M i for every k ∈ N , then θ is true in ∏ i ∈ N M i . [ABSTRACT FROM AUTHOR]

Paper and packaging materials a lignocellulose-based natural biodegradable polymer that spontaneously releases acetic acid, aldehydes, alcohol, and ester-based volatile organic compounds (VOCs) upon ageing and these VOCs start degrading the paper products and decline their mechanical strength properties. The reactivity of the paper of unbleached wheat straw pulp towards acetic acid and hexanal, which has been proven to have more degrading effects on paper than other VOCs, was considered in this work. The papers were exposed to these volatile compounds for 90 days in an air-tight vessel under ambient environmental conditions. The results showed that hexanal was more destructive than acetic acid with regards to cellulose degradation and depletion in the mechanical strength properties. The paper properties like, tensile, tear and burst index, viscosity, pH and carbonyl group content was measured. The growth of the carbonyl group, evidence of the ageing effects in the paper, detected more in the paper exposed to acetic acid. However, the strength of paper properties declined more with hexanal. FE-SEM analysis of the sample showed the development of pores and damage of cellulose fibre upon ageing. Similarly, the damaging effects of VOCs on cellulose, hemicelluloses and lignin were confirmed by significantly reduced peak detection through FT-IR \analysis. The high crystallinity index of the paper products due to exposure to VOCs was detected by XRD analysis, which confirmed the degradation of the low molecular weight cellulose molecule. Thus, the results are strongly recommended that VOCs that generates due to natural or artificial ageing could be the leading cause of paper degradation. [ABSTRACT FROM AUTHOR]

Bioenergy with carbon capture and storage (BECCS) is one of the key negative emission technologies (NETs). Large-scale implementation of BECCS has been criticized of the associated increase in land use. The existing large Nordic pulp and paper production units enable BECCS deployment without additional land use, as they currently release large amounts of bio-based carbon dioxide (CO2). The application of BECCS in pulp mills has been found technically feasible in earlier studies. This study explores key factors that affect the propensity to invest in BECCS in different types of existing European pulp and paper mills. The results give fresh understanding on the effects of BECCS on the market price of pulp and paper products and the required level of incentives. Based on statistical data, the marginal carbon dioxide credit (€ per ton CO2) to make BECCS profitable was derived. The results show that the required level of credit greatly depends on the mill type and details and that the feasibility of BECCS does not clearly correlate with the economic performance or the measured efficiency of the mill. The most promising mill type, a market kraft pulp mill, would find BECCS profitable with a credit in the range of 62–70 €/tCO2 and a credit of 80 €/tCO2 would decrease pulp production costs by 15 €/tproduct on average if 50% of CO2 emissions was captured. The EU Emission Trading System (ETS) is the main policy instrument to achieve the climate targets related to fossil energy use, but does not yet contemplate bio-based emissions. [ABSTRACT FROM AUTHOR]

Paper dusting, which occurs when a tissue web releases unbound and loosely bound fibers or filler particles during tissue-making or product manufacturing, has an overall negative impact, causing safety hazards, machine runnability difficulties, and product quality issues. To date, there are no well-established industry standards to quantify dusting/linting propensities in finished tissue products, thus evaluating the effectiveness of dust/lint control programs is challenging yet intriguing. This research aims to fill this gap by developing a methodology to characterize dusting in tissue papers. We have developed a device prototype (named the Tissue Dust Collector) and a methodology that together have been named the Tissue Dust Analysis System (TDAS), which aims at quantifying the propensity for tissue-grade paper products to generate dust/lint in a controlled and reproducible manner. Two samples, corresponding to commercial products with a low and high linting propensity, were tested using the proposed device and methodology, and the released particles were quantified and characterized. The device and methodology provided reproducible results for simulated consumer handling and product manufacturing scenarios. By changing the instrument's motor frequency, the force of agitation changes, mimicking/simulating consumer (60 strokes per min, spm) and producer/manufacturing (180 spm) handling scenarios (though manufacturing processes are much faster in practice). Particle counts at each level for each product showed reproducible values differentiable at different agitation levels. Adopting the proposed Tissue Dust Analysis System may help to characterize and understand the mechanisms behind dusting to create dust-control strategies that can alleviate this issue at its various sources or simply allow tissue paper manufacturers to compare and advertise their products based on dusting propensity. [ABSTRACT FROM AUTHOR]

The paper studies product bundling in a duopoly supply chain network under the influence of different power-balance structures, bundling decisions and advertising efforts on total supply chain profit. Mathematical models comprising two manufacturers and a single retailer are developed to capture the impact of bundling policy and advertisement strategy under three power-balance structures, namely Manufacturer Stackelberg, Retailer Stackelberg and Vertical Nash. Following game theory models and numerical examples, the study found that the total profit of the supply chain is undifferentiated under the manufacturer Stackelberg and Vertical Nash case in the manufacturer bundling and retailer bundling strategies. However, total supply chain profit under manufacturer bundling strongly dominates under retailer bundling in Retailer Stackelberg and Vertical Nash, and remains valid under multiple settings of market size, price elasticity and advertising elasticity. It is also found that manufacturer bundling is significantly affected by advertising effort compared to retailer bundling. The study contributes to the literature interfacing supply chain and marketing by studying bundling policy and advertising strategy simultaneously for homogenous products, under various power-balance structures and price competition. [ABSTRACT FROM AUTHOR]

Global sustainability megatrends are promoting the utilization of sustainably perceived fibers such as recycled and agricultural residue fibers in hygiene tissue applications. Tissue paper products advertised as sustainable have higher prices and inferior performance than conventional products manufactured from virgin wood fibers. This work demonstrates the feasibility of using agricultural residues from fique plantations (Furcraea microphylla genus) as an alternative to Northern Bleached Softwood Fibers (NBSK) in high-performance hygiene tissue applications. For our study, fiber residues were mechanically cleaned and upgraded to a tissue pulp using a simple pulping and bleaching process. A complete characterization of tissue paper properties (bulk, softness, water absorbency, tensile strength) was performed and compared against the NBSK market pulp. Additionally, fique residue pulp was blended with Bleached Eucalyptus Kraft (BEK) to match the performance of a selected benchmark consisting of 70% BEK and 30% NBSK. Results indicate fique residue bleached pulp has similar fiber morphology and comparable strength properties in terms of the tensile strength (+ 6%) and tear strength (+ 10%), but superior bulk (+ 12%), water absorbency (+ 28%), and softness (−29% TS7 values) than NBSK pulp. A fiber blend of 70% BEK and 30% fique residue showed superior tensile strength (+ 21%), tear strength (+ 54%), bulk (+ 5.5%), water absorbency (+ 1.5%), and softness (−8.7% TS7 values) over a similar fiber blend of BEK and NBSK. Our findings demonstrate that fibers from fique residue can substitute NBSK in hygiene tissue applications. Upgrading residues from fique fibers as raw materials for the tissue industry can bridge the gap between sustainability and product performance, simultaneously opening the possibility of new revenue streams for millions of small farmers in the producing countries. [ABSTRACT FROM AUTHOR]

The chloropropanols 3-monochloropropane-1,2-diol (3-MCPD) and 1,3-dichloro-2-propanol (1,3-DCP) are potentially carcinogenic contaminants that may occur in paper or cardboard e.g., as a result of the use of certain wet-strength agents. This study describes the contamination of cardboard toy products (books and puzzles) with 3-MCPD and 1,3-DCP, as well as the migration potential and oral exposure to young children (< 3 years). For 54 cardboard toy products, the cold water extract according to EN 645 was prepared and analyzed for the leaching of 3-MCPD and 1,3-DCP. The limits for food contact papers, as recommended by the German Federal Institute for Risk Assessment (BfR), were exceeded in 31% and 23% of the samples, respectively. Some cases showed significant transfers of up to 4102 µg/L (3-MCPD) or 1295 µg/L (1,3-DCP). We estimated the oral exposure resulting for children playing with these toys by dynamic migration according to EN 71-10:2005, and applied it to children weighing 7.5 kg, taking into consideration the TDI for 3-MCPD or the BMDL10 for 1,3-DCP. Four samples exceeded the TDI for 3-MCPD and five samples had an MOE < 10,000 for 1,3-DCP, a clear indication that measures must be undertaken to minimize this exposure. These toy articles represent a serious risk regarding the exposure of children to the toxic substances 3-MCPD and 1,3-DCP, for which regulatory measures should be undertaken. The BfR limits for food contact papers were met by a majority of the samples examined and can serve as suitable reference values for kid's toy products. [ABSTRACT FROM AUTHOR]

We theoretically analyze the phase sensitivity of an SU (1 , 1) interferometer with various input states by product detection in this paper. This interferometer consists of two parametric amplifiers that play the role of beam splitters in a traditional Mach–Zehnder interferometer. The product of the amplitude quadrature of one output mode and the momentum quadrature of the other output mode is measured via balanced homodyne detection. We show that product detection has the same phase sensitivity as parity detection for most cases, and it is even better in the case with two coherent states at the input ports. The phase sensitivity is also compared with the Heisenberg limit and the quantum Cramér–Rao bound of the SU (1 , 1) interferometer. This detection scheme can be easily implemented with current homodyne technology, which makes it highly feasible. It can be widely applied in the field of quantum metrology. [ABSTRACT FROM AUTHOR]

This is an expository paper on tensor products where the standard approaches for constructing concrete instances of algebraic tensor products of linear spaces, via quotient spaces or via linear maps of bilinear maps, are reviewed by reducing them to different but isomorphic interpretations of an abstract notion, viz. the universal property, which is based on a pair of axioms. [ABSTRACT FROM AUTHOR]

For the perturbed Hamiltonian of a multifrequency resonance harmonic oscillator, a new approach to calculating the coefficients in the procedure of quantum averaging is proposed. The procedure of quantum averaging is transferred to the space of the graded algebra of symbols by using twisted product introduced in the paper. As a result, the averaged Hamiltonian is represented as a function of generators of the quantum symmetry algebra of the harmonic part of the Hamiltonian. The proposed method is applied to the spectral problem for the Hamiltonian of the cylindrical Penning trap. [ABSTRACT FROM AUTHOR]

It is generally acknowledged that in order to have access to locally accumulated industrial knowledge, firms have to collaborate and take part in cluster knowledge networks. This study argues that the inherited capabilities of spinoff enable them to cooperate and exchange knowledge more easily and to gain more from positive knowledge externalities in clusters. The basis of the analysis is a relational dataset on a printing and paper product cluster in Hungary, and I use exponential random graph models to explain the formation of knowledge ties. I demonstrate that besides geographical proximity, ownership similarity and network structural effects, being a spinoff company enhances tie formation in the local network. Results suggest that spinoffs are indeed more likely to collaborate and take advantage of knowledge concentration. [ABSTRACT FROM AUTHOR]

The traditional measurement of quality indices cannot meet the requirements of new products, precise and intelligent control. Prediction models of pulp components are established based on analyzing the correlation between cellulose, hemicellulose, lignin content and whiteness, Kappa number, intrinsic viscosity, respectively, in the chlorine dioxide bleaching process. The results show that the models can simulate the varieties of components in bleaching process and judge the quality of bleached pulp more directly than traditional quality indices. The models have a practical significance for paper products requiring the concerned component and match to the tendency of precise and intelligent control of the bleaching process. [ABSTRACT FROM AUTHOR]

Unlike in developed countries, most public toilets in China do not provide toilet paper onsite and users must bring their toilet paper. Moreover, an open waste bin is placed in each user's cubicle to collect used toilet paper and tissues. Such practices, which are common in East Asia and central America, have induced a dilemma of toilet paper disposal because some municipalities have removed waste bins from public toilets to prevent virus transmission by fecal matter. As a consequence, users were forced to flush down their used toilet paper and tissues. Yet, it is unknown whether standard toilet paper can be flushed easily without causing issues in sewer operations. Here, we surveyed the conditions of toilets in university campus and other public facilities in different regions across China. We also evaluated the disintegration characteristics of toilet paper products both by conducting online surveys and by physical disintegration experiments. We found that only 15% of toilets provided toilet paper, while open waste bins occurred at nearly all sites. Further, our survey indicated that 82% of toilet paper products sold in China did not give any indication on their flushability, whereas 77% of US products did. Disintegration results showed that none of the five popular, best-selling toilet paper products passed the flushability standard. We propose strategies to solve the current toilet paper dilemma in developing communities. [ABSTRACT FROM AUTHOR]

Tellurium is a rare metalloid that is vastly produced from copper anode slime, which is a by-product of the copper electrorefining process. Choosing the proper recovery method strongly depends on the slimes composition, mineralogy, and tellurium concentration. In addition, correctly selecting the right method of leaching, purification, and precipitation in economic and environmental processing of the variety of copper anode slimes very much depends on having a thorough understanding of the chemistry, thermodynamics, and kinetics of the recovery process. Despite a wide variety of developments in the recovery of slime, a lack of comprehensive study to help identify the effective factors in the selection of the right process is evident. This article provides a comprehensive literature review on the available tellurium recovering processes from copper anode slime to the final high purity product. This overview is written, hoping to help researchers select and apply the appropriate method in the recovery of tellurium from copper anode slimes of different characteristics. [ABSTRACT FROM AUTHOR]

Logistics sustainability is increasingly becoming a central focus of businesses, when most societies are aware of the influence of industry on both the environment and human health. To address the drawbacks of the way logistics systems have been designed, a new logistics system called Physical Internet has been proposed. This system relies on the creation of hyperconnected logistics systems. It aims to improve in an order of magnitude the way physical objects are transported, handled, stored, supplied, realized, and used to be more sustainable and efficient economically, environmentally, and socially. This paper focuses on the product realization using a hyperconnected mobile production mode in the context of Physical Internet, an open global logistics system. It addresses its dynamic deployment of production modules and resource allocation and sharing. It then proposes a make-to-order bi-objective optimization model which minimizes costs and greenhouse gases (GHGs) related to the product realization of a manufacturer to serve its customers given the availability of the open fabs. Experimental results are presented to identify the computational performance of the established model, as well as the economic and environmental benefits of using the facilities enabled by the PI. Finally, it concludes and provides directions for future research. [ABSTRACT FROM AUTHOR]

Due to the recent pandemic of coronavirus, known as the COVID-19 outbreak, the supply chains have been impacted most significantly. Manufacturers of certain items have experienced a substantial increase in demand, and on the other hand, raw materials supply, to produce those items, has reduced because of supply failure. To overcome these challenges, this paper proposes some strategies to improve service level during an extraordinary pandemic outbreak, such as COVID-19, for the most wanted products such as toilet paper. This study considers meeting the increased demand of the customers for an essential product of daily life like toilet paper during a pandemic is beyond the traditional economic objective, i.e., increase profit, of the manufacturers. Instead, this should be more about the social responsibility of all the manufactures to ensure that they can serve more customers. Motivated by this and taking toilet paper as an example of the product, we first analyzed the current scenario of the manufacturing and the demand for the product and then proposed some strategies to deal with this unprecedented risk and analyzed the results. We have compared the results, using hypothetical data, between the current scenario and proposed strategies. The result shows that sharing information and resources from all manufacturers to produce under a single brand, emergency sourcing, producing basic quality items, and packing in the smallest sizes have a significant positive impact on the service level. This paper first investigates the strategies for a high-demand and essential item during a pandemic situation and proposes strategies to deal with this unique, extraordinary disruption. [ABSTRACT FROM AUTHOR]

Droplet impact and penetration into the paper-like medium are essential physical phenomena in variety of natural and industrial processes. The lattice Boltzmann model coupled with random-walk-based stochastic scheme is presented to calculate the interactions between inertial dominated droplet and fibrous medium. Results show that the droplet spreading regime is independent of surface wettability, volume fraction, and Ohnesorge number at very early impact stage. For fibrous medium with volume fraction ~ 50% and wettability 85°, three stages of penetration process are observed. Whereas for low-volume-fraction fibrous medium, the phases of droplet spreading and penetration are coupled which results in a small spreading width for hydrophilic wettability. It is found that the spaces of spreading width and penetration rate are divided by the curve of O h = 0.038 and R e = 144 . The effects of Ohnesorge and Reynolds numbers largely influence the behaviors of droplet spreading and penetration process. The in-depth insight of inkjet droplet impact onto the paper-like fibrous medium is beneficial for improving printed products in Paper Electronics. [ABSTRACT FROM AUTHOR]

In offset printing process, poor mechanical properties and printability of paper substrate usually result in printing problems, low quality of print and waste of paper materials. Therefore, many researches focus on the quality improvement of paper substrates using suitable additives. In this work, N-methylated chitosan, including N, N-dimethyl chitosan (DMC) and N, N, N-trimethyl chitosan (TMC), were prepared and employed as coating agents to ameliorate the mechanical properties and printability of paper sheets. Analysis results showed that the mechanical strength of coated papers with DMC and TMC were largely improved, because the fibers with negative charges were prone to form electrostatic bonding with the positively charged N-methylated chitosan, thus enhancing paper strength. Particularly, compared with chitosan and DMC, the TMC-coated paper exhibited better mechanical properties, printability and surface properties due to the high cationic charge density of TMC. Therefore, surface coating with TMC is of great benefit to decrease the printing problem of paper sheets and enhance the operation speed in offset printing. This work provides a valuable reference for the amelioration of the printability and physical properties of high-quality paper products for many promising applications. [ABSTRACT FROM AUTHOR]

Traditional bending products are usually divided into two steps: extrusion and bending. Staggered extrusion (SE) as a new process was proposed to prepare Mg alloy bending products in this paper. By designing the structure at one end of the stem, the dual functions of extrusion process and bending process can be realized in a single extrusion pass. The results of the present study show that by adjusting the degree of deformation of the AZ31 Mg alloy, a bending product with a specific curvature could be obtained by the SE process, and the microstructure of the bending product was refined. When the extrusion ratio was increased from 11.11 to 44.44, the grain size was refined from 23.89 to 9.69 μm, and the percentage of recrystallized structures increased from 61.1 to 78.8%. [ABSTRACT FROM AUTHOR]

Purpose: ISO 14020 series of standards provide guidance for establishing ecolabels and a classification based on three label types, I, II, and III. They also determine the consideration of product's life cycle and application of the life cycle assessment (LCA) in ecolabeling. Still, the large number and variety of existing ecolabels has led to consumer confusion in the recent years. The objective of this paper is to propose a characterization scheme for ecolabels and to provide recommendations for the enhancement of existing ecolabel classification, questioning the current sufficiency of ISO. Methods: To reach the objective, we first create a sample of ecolabels covering forest and paper products as an example, to narrow down the enormous number of existing ecolabels (over 460 as of August 2018). Second, we analyze their content, purpose, and awarding criteria through a desk research. In parallel, scientific publication, reports, and standards are also analyzed. Third, based on the obtained information, we define a list of ecolabel characterization attributes and their options and observe tendencies in ecolabel development. Ultimately, based on the outcomes of the proposed characterization scheme, we give recommendations for enhancement. Results and discussion: Ultimately, we compare a sample of 45 ecolabels against 18 attributes of the proposed characterization scheme, including, among others, their ISO typology, life cycle perspective, awarding format, covered environmental aspects, and scope. Regarding type I or type III label, ISO seems to be explicit and their requirements are well respected, including how LCA is to be applied. However, approximately 60% of the explored ecolabels in our sample did not declare any ISO typology, whereas none assigned a type II classification. These "undefined" ecolabels, as we call them, apply different awarding formats and criteria in combination and hybrid forms that are not recognized and described by ISO or any other observed classification approach. Misuse of the term "LCA" is also perceived in such "undefined" initiatives. Conclusions: We conclude that the current ISO standards on ecolabels belittle the consequences that the increased number of undefined ecolabels brings. We provide a list of recommendations for the enhancement of the current ISO classification in seven topics, namely, awarding format, aspects diversity, operation scope, verification, reconsideration of the usability of ISO 14021, new ISO classification, and transparency. Limitations of the study and outlook conclude the work. [ABSTRACT FROM AUTHOR]

Purpose: The European Ecolabel (EU Flower) has the mission to encourage cleaner production and influence consumers to promote Europe's transition to a circular economy. Nonetheless, little is known about EU Ecolabel evolution; it is not clear what the drivers that encourage its implementation are. Thus, this study aims to assess the growing acceptance of the EU Ecolabel in the European Union, and Spain more specifically, by examining product and service categories and geographical regions. Methods: The methodological approach taken in this study is a mixed methodology based on the triangulation method by consulting the EU Ecolabel scheme database, EU Ecolabel delegates from some autonomous regions, and the academic literature. Also, a geographic analysis was run in the ArcGIS Software with data about the accumulation of licenses assigned in 2016. Results and discussion: The analysis shows that most products in Spain that have been awarded the EU Ecolabel belong to the following categories: Do-It-Yourself Products (paint and varnish), Paper Products, Cleaning Up Products, and Electronic Equipment. At the same time, the study showed that this ecolabel faces significant obstacles in its diffusion, such as the competition with environmental labels launched previously in Europe and other regional labels. Conclusions: The results of this study indicate the existence of five drivers that may encourage the implementation of EU Flower in a region: (1) public management, (2) communication strategy, (3) sustainable public procurement criteria, (4) local income per capita, and (5) international trade incentives. Finally, this study provides essential recommendations for policymakers to trigger ecolabeling practices such as the need to improve the understanding of the EU ecolabel impact in different levels of activity, which means countries, regions, industrial clusters, firms, and consumers. Also, this investigation identifies areas for further research, and it expresses the need to develop business case studies about ecolabeling with the objective to visualize this phenomenon as an eco-innovation process. [ABSTRACT FROM AUTHOR]

The coating technique, supposedly invented by Chinese papermakers no later than the 3rd century AD, greatly improved paper sheets' qualities of color, texture, writability, and printability. Alongside the dispersal of papermaking and surface-treatment techniques beyond China, coated papers were manufactured and used in many other regions of the world. Understanding the manufacture of coated papers, therefore, is crucial for perceiving how surface treatments were developed to meet the need for paper with enhanced properties. However, the characterization of coating and coating pigments on ancient Chinese papers has long remained an unsolved issue, and previous studies on this topic have often produced inconclusive results. To explore a non-invasive methodology that can more reliably characterize coated papers and the coating pigment on them, this article presents the results of a pilot study that applied micro-computed tomography (micro-CT) and Raman spectroscopy to samples of three Qing Dynasty (1644–1911 AD) papers and two handmade papers manufactured in China in the 1990s. Micro-CT revealed the coating layer(s) on Lajian (waxed coated paper) and Lengjinjian (gold-dusted paper) of the Qing Dynasty and characterized the modern raw xuan and bamboo papers as uncoated. Raman spectroscopy, together with handheld X-ray fluorescence analysis, identified the mineral-based pigment in the coating layer, suggesting the use of lead white or kaolin as the coating pigment. Additionally, Raman analysis confirmed the use of other mineral pigments (red lead and cinnabar), beeswax, and organic dyes (gamboge, kermesic acid, and possibly purpurin) in the manufacture of Lajian and Lengjinjian papers. The combination of micro-CT and Raman spectroscopy, it is therefore suggested, is a practical, more reliable approach for non-invasive investigation of coating and coating pigments on ancient Chinese paper specimens. [ABSTRACT FROM AUTHOR]

A procedure for the rapid simultaneous determination of anthraquinone and bisphenol A in paper and cardboard is proposed based on a combination of extraction with subcritical methanol and subsequent analysis of the extracts by HPLC‒tandem mass spectrometry. The achieved limits of detection are 25 and 250 µg/kg for anthraquinone and bisphenol A, respectively, and fully meet present-day safety requirements for pulp and paper products. The total duration of the analysis, including sample preparation, is not more than 45 min. The sensitivity of anthraquinone determination is 1‒2 orders of magnitude higher than that of the known procedures, including those with the preconcentration of analytes. The results obtained were successfully used to study paper and cardboard samples, in most of which unacceptably high levels of the anthraquinone concentration were found. [ABSTRACT FROM AUTHOR]

Cellulosic fibers are widely used in biocomposites, paper and paperboard products, and other fiber-based materials. The properties of fiber-based materials are significantly affected by lignin characteristics, especially the lignin distribution in cellulosic fiber cell walls. In this study, chemical (sodium chlorite) and biological (laccase/mediator system) techniques were used to control three fiber models with different lignin contents at about 20%, 10%, 5%, respectively. The lignin distribution in cell walls was determined based on the "enzymatic peeling" method and SEM–EDS analysis. Results showed that the lignin concentrations in fiber cell walls prepared from the combined chemical and biological techniques were lower in the outer region and higher in the inner region than those from the chemical treatment only, which is due to the fact that laccase-induced lignin degradation is only limited to the outer region and not able to get into the inner region. The fiber model with less lignin in the inner region of the cell wall had a better deformation performance (the flexibility of 1.559 × 109 N−1 m−2) than that with more lignin in the same region. The relationships of fiber models of different specific lignin distribution with their deformability were established, which could be valuable to extend the wide value-added applications of fiber-based materials. [ABSTRACT FROM AUTHOR]

Foam forming is a promising papermaking technology, which can reduce water and energy consumption while saving raw material. It can be used to produce low quantity thick special products such as non-woven fabrics and filter papers with high porosity and smooth surfaces. This study mainly introduced the effect of polyvinyl alcohol (PVA) foaming properties on foam forming, including foam generation rate, liquid drainage rate, properties of the suspension and foam stability. Moreover, the effect of surfactant, air content and stirring speed on the behavior and characteristics of the foams were also investigated. The results indicate that foams prepared at 1200 rpm rotational speed under room temperature (25 °C) with a particular surfactant loading range from 0.75 to 1.25% have a life time of 7.5 min and its bubble size is uniform. It is also found that the degree of hydrolysis of PVA, would affect the bubble size and foam stability. Eventually, fiber-based materials with low density and highly porous structure were fabricated via a foam forming technology. [ABSTRACT FROM AUTHOR]

Wood density affects the strength of lumber and paper products. Despite considerable research, however, the key factors influencing wood density are still not fully understood. The aim of this study was to analyze the effects of variables within and among trees on the density of current wood growth along the stem in order to further understanding and prediction of wood quality. Correlation analyses together with linear mixed effects and randomForest modelling were carried out using stem analysis and tree-level data from long-term balsam fir and white spruce stand density experiments in Eastern Canada. Wood density showed highly structured patterns of variation among trees. Mixed effects and randomForest models, which incorporated tree-level effects accounted for much of the wood density variation. The three most influential variables identified by randomForest analysis for both species were tree slenderness, relative height and ring width. Wood density increased with slenderness and relative height, and these variables affected relationships of wood density to ring width. Wood density is associated with interacting variables within and among trees including tree slenderness and relative height. Wood density is related to ring width, but this relationship is modulated by tree-level influences which likely reflect mechanical stability requirements. [ABSTRACT FROM AUTHOR]

In this paper, a spectral collection of over 150 ATR-FT-IR spectra of materials related to cultural heritage and conservation science has been presented that have been measured in the extended region of 4000-80 cm (mid-IR and far-IR region). The applicability of the spectra and, in particular, the extended spectral range, for investigation of art-related materials is demonstrated on a case study. This collection of ATRFT-IR reference spectra is freely available online () and is meant to be a useful tool for researchers in the field of conservation and materials science. [ABSTRACT FROM AUTHOR]

Phthalate acid esters are widely used as plasticizers to impart plastic flexibility in various industrial applications. In this study, the content of seven phthalates, dibutyl phthalate (DBP), benzyl butyl phthalate (BBP), di-(2-ethylhexyl) adipate (DEHA), di-2-ethylhexyl phthalate (DEHP), di-n-octyl phthalate (DNOP), di-isononyl phthalate (DINP), and di-isodecyl phthalate (DIDP) were determined in paper cups using gas chromatography-mass spectrometry (GC-MS). In addition, the potential migration of these seven phthalates from paper cups into various food stimulants under different conditions was evaluated. The levels of DBP, DEHA, DEHP, and DNOP were in the ranges of 0.07-3.14, 0.16-42.69, 0.45-58.56, and 0.3-2.4 mg/kg, respectively. Meanwhile, BBP, DINP, and DIDP were not detected in most of the tested samples. In the migration test, DEHA was released to 50 % ethanol and n-heptane in a time-dependent manner and the maximum migration levels were 65.62 ± 3.61 and 95.56 ± 19.76 μg/L, respectively. The release of other phthalates was very low or negligible. These results demonstrated that paper cups are not a significant source of phthalate exposure; however, DEHA could be released from paper cups into alcoholic beverages or oily liquid beverages in the human diet. [ABSTRACT FROM AUTHOR]

In this work, metal-matrix composites were prepared via paper-manufacturing technology using metastable austenitic steel powder of type 16-7-3 (Cr-Mn-Ni in wt pct) and magnesia partially stabilized zirconia reinforcing particles. The influence of the process parameters on the paper web formation and the resulting properties of the MMCs were studied and solids retention of >90 wt pct was achieved. During filtration of the aqueous fiber-filler suspension, the steel particles were incorporated in the fiber network, and steel clusters were formed. Calendering had a positive influence on the porosity, bulk density, and tensile strength of the green paper sheets. Within this contribution, the debinding process for the metal-matrix paper sheets was in focus. A debinding rate of 0.5 K/min to 733 K (460 °C) with a dwell time of 90 minutes was sufficient to completely remove cellulose fibers. The sintered composites attained a tensile strength of up to 177 N/mm at a total porosity of 66 pct. [ABSTRACT FROM AUTHOR]

Biodegradability and compostability of nanofibrillar cellulose-based (NFC) products including films, concentrated NFC and paper products containing NFC were evaluated under controlled composting conditions. All the NFC products tested were biodegradable according to the requirements set in European standard EN 13432. NFC even enhanced the rate of biodegradability of paper containing 1.5 % NFC as an additive. Disintegration during composting was evaluated using the modified pilot-scale composting test EN 14045. NFC films disintegrated completely in 3 weeks of composting, and NFC did not influence the degradability of paper products containing NFC. Ecotoxicity during biodegradation of NFC products in a compost environment was evaluated using a bioluminescence test with Vibrio fischeri. No acute toxicity was detected for any of the samples. [ABSTRACT FROM AUTHOR]

The combination of biopolymer science and technology with surface engineering of paper-based cellulosic materials has a lot of potential in stepping forward to a sustainable future. Various biopolymers such as oxidized starch, carboxymethyl cellulose, and polylatic acid have been commercially used to engineer paper surface. The paper-based cellulosic products are widely used for printing/writing and packaging applications. However, the production of these products are currently dependent mainly upon the use of petroleum-based materials including synthetic pigment coating latexes and barrier coating materials. The major challenges associated with some biopolymers are their relatively high costs and unsatisfactory performances. Continuing efforts are being made to enable the increased and value-added use of various biopolymers in paper surface engineering. These polymers can be based on cellulose, hemicelluloses, chitosan, alginate, protein, polylactic acid, and polyhydroxyalkanoate. The biopolymer-engineered paper products can be tailored for use as substitutes for various non-renewable materials including plastics and metals as well. Future development in the area of biopolymers for paper surface engineering is likely to lead to new possibilities and breakthroughs, paving the way for a substantially sustainable and green future. [ABSTRACT FROM AUTHOR]

A paper cup forming machine can produce a maximum of about 140 paper cups a minute. If the rate of production is increased to improve productivity, the contact force in the barrel cam increases, producing more vibration. Therefore, a method for reduction of cam vibration is needed. The profile of the barrel cam is optimized by using a multibody dynamics model. The objective of the optimization is to minimize the contact force that occurs between the rollers and the barrel cam. An experiment is carried out using the optimized barrel cam. The reduction of vibration at higher rates of production than the current rates validated the optimization. [ABSTRACT FROM AUTHOR]

Nanofibrillated cellulose offers new technological solutions for the development of paper products. Here, composites of nanofibrillated cellulose (NFC) and Ag nanoparticles (NP) were prepared for the first time via the electrostatic assembly of Ag NP (aqueous colloids) onto NFC. Distinct polyelectrolytes have been investigated as macromolecular linkers in order to evaluate their effects on the building-up of Ag modified NFC and also on the final properties of the NFC/Ag composite materials. The NFC/Ag nanocomposites were first investigated for their antibacterial properties towards S. aureus and K. pneumoniae microorganisms as compared to NFC modified by polyelectrolytes linkers without Ag. Subsequently, the antibacterial NFC/Ag nanocomposites were used as fillers in starch based coating formulations for Eucalyptus globulus-based paper sheets. The potential of this approach to produce antimicrobial paper products will be discussed on the basis of complementary optical, air barrier and mechanical data. [ABSTRACT FROM AUTHOR]

In this paper two procedures are developed for the identification of the parameters contained in an orthotropic elastic-plastic-hardening model for free standing foils, particularly of paper and paperboard. The experimental data considered are provided by cruciform tests and digital image correlation. A simplified version of the constitutive model proposed by Xia et al. (Int J Solids Struct 39:4053-4071, ) is adopted. The inverse analysis is comparatively performed by the following alternative computational methodologies: (a) mathematical programming by a trust-region algorithm; (b) proper orthogonal decomposition and artificial neural network. The second procedure rests on preparatory once-for-all computations and turns out to be applicable economically and routinely in industrial environments. [ABSTRACT FROM AUTHOR]

Purpose: Pulp and paper manufacturing constitutes one of the largest industry segments in term of water and energy usage and total discharges to the environment. More than many other industries, however, this industry plays a key role in sustainable development because its most important raw material, wood fiber, is renewable Dias and Houtman (Environ Prog 23(4):347-357, ). Actually, even if the communication is dominated by electronic media, paper-based communication has a role to play due to its unique practical and aesthetic qualities. This research aims to assess the environmental impact of advertising folders produced with different papers and distributed by a system of Italian consumers' cooperatives in order to indicate the possible options of improvement and to assess the CO emitted during the entire life cycle. Methods: Life cycle assessment (LCA) was performed from cradle-to-grave considering paper production, transport from paper mill to printing site, printing, distribution, and disposal. Data for the study were directly collected from specific companies and completed on the basis of literature information. The analysis was conducted using the SimaPro 7.1.5 software and IMPACT 2002+ method to assess all its environmental impact and damage categories. Results and discussion: LCA analysis indicates that the higher environmental impact is mainly due to paper production and printing processes. The main operations which generate the major impact in the paper production stage are related to the direct or indirect fossil energy use, the production of additives for bleaching operations, and the collection and selection of waste paper. Printing causes relevant impacts for the electricity and ink production and for the aluminum plates used in the offset printing. Moreover, the use of paper with low quantity of additives and small amount of primary fibers causes a reduction of the environmental load of 13.94 %. The major global warming potential value was found for advertising folders made with little amount of mechanical pulp which slightly contributes to the absorption of CO. Conclusions: The analysis pointed out the relevance of the paper production phase and of the printing step within the advertising folders life cycle and allowed to detect the other critical stages of the life cycle. Paper composition greatly affects the environmental impact of the advertising folders' life cycle. [ABSTRACT FROM AUTHOR]

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Paper sheets impregnated with flame retardants made from agricultural residues and other additives were studied with the cone calorimeter. The use of sugar beet ethanol eluent (SBE), CaCl, and ZnCl lowered the peak rate of heat release (PRHR) the most in comparison to water treated material. The average effective heat of combustion (AEHC) was lowered by most of our treatments with the exception of BMIC (butylmethylimidazolium chloride)/starch (BMS). The average mass loss rate was lowered by all the treatments, but the most by the use of ZnCl and CaCl treatments. Mass losses were the least with SBE, CaCl/NaOH/starch, and CaCl/NaOH treatments. The BMS sample exhibited the greatest total heat release while SBE samples gave the smallest value of the parameter. The flame retarding effect of SBE was ascribed to the presence of ferulates which prevented the formation of volatile products by condensing into polycyclic aromatic residue. [ABSTRACT FROM AUTHOR]

The article presents information on a study related to the optical coherence tomography and its possible applications in the paper industry to evaluate the properties of paper surface and coating layers. A three dimensional reconstruction of a commercial premium quality photopaper structure is presented. It can be used as a multifunctional tool for inspection of different paper products and also shows that amplitude map can provide more information than the corresponding topography.

Background, aim, and scope Pulp and paper production is one of the most important Portuguese economic activities. Mostly based on eucalyptus (Eucalyptus globulus), nearly 70% of the pulp produced is exported, mainly to the European Union. The aim of this paper is to compare the environmental impacts of the production of Portuguese printing and writing paper based on eucalyptus with those from the production of paper from industrial hemp (Cannabis sativa). Materials and methods We have used a life cycle assessment approach to compare both types of paper. The functional unit used was a ton of white printing and writing paper. Data was mostly derived from the Portuguese literature for eucalyptus and from scientific literature for hemp. The impact categories/indicators taken into account were global warming, photochemical oxidant formation (summer smog), acidification, eutrophication, and direct land use. Results and discussion Industrial hemp presents higher environmental impacts than eucalyptus paper in all environmental categories analyzed. The main differences are in the crop and the pulp production stages. This is because hemp makes use of higher number of mechanical operations and larger amounts of fertilizer in the former and larger amounts of chemical additives in the latter. Conclusions There is scope for improving industrial hemp paper production. We present some suggestions on how to reduce some of the environmental impacts identified for hemp, so that the pulp and paper industry can continue its progress towards a more environmentally friendly paper production. Recommendations and perspectives New studies could be based on the alternatives presented throughout the paper for improving hemp paper. Further studies should incorporate analyses on water consumption, soil erosion, soil nutrient depletion, and impacts on biodiversity. [ABSTRACT FROM AUTHOR]

Films made of nanofibrillated cellulose (NFC) are most interesting for use in packaging applications. However, in order to understand the film-forming capabilities of NFC and their properties, new advanced methods for characterizing the different scales of the structures are necessary. In this study, we perform a comprehensive characterisation of NFC-films, based on desktop scanner analysis, scanning electron microscopy in backscatter electron imaging mode (SEM-BEI), laser profilometry (LP) and field-emission scanning electron microscopy in secondary electron imaging mode (FE-SEM-SEI). Objective quantification is performed for assessing the (i) film thicknesses, (ii) fibril diameters and (iii) fibril orientations, based on computer-assisted electron microscopy. The most frequent fibril diameter is 20–30 nm in diameter. A method for acquiring FE-SEM images of NFC surfaces without a conductive metallic layer is introduced. Having appropriate characterisation tools, the structural and mechanical properties of the films upon moisture were quantified. [ABSTRACT FROM AUTHOR]

Objectives: Natural organic fibers are used in large quantities in the production of paper products and textiles. They are also constituents of food and added to food to promote health. The objective of this review is to evaluate the health effects of natural organic fibers. The health effects of dietary fibers are excluded from the review. Methods: This is a literature review. Results: Exposure to these fibers in industry is usually not characterized as fibers but as dust. Rather dusty conditions have been reported in both paper and textile industries with concentrations up to and above 30 mg/m3. Both in the paper and textile industry inorganic fibers may occur making it hard to evaluate health effects of natural organic fibers from studies of workers in the paper and textile industry. There seems to be no increased risk of mesothelioma, lung cancer or lung fibrosis in workers exposed to natural organic fibers in contrast to workers exposed to inorganic crystalline fibers as asbestos. However, workers with a heavy exposure to paper dust or textile dust seem to have an increased risk of obstructive lung disease and bronchitis. These effects have not been causally linked to the fibrous shape of the particles but rather to the dust, chemicals absorbed on the dust or microorganisms occurring together with the dust. There is some indication that work in the textile industry may increase the risk of sinonasal cancer, but the etiological agents are unknown. Conclusion: Natural organic fibers are not causally linked with the well-known effects of some inorganic fibers, i.e. mesothelioma, lung cancer, lung fibrosis or some pleural diseases. The health effects of natural organic fibers, e.g. irritative effects, seem not to be linked to their fibrous shape. [ABSTRACT FROM AUTHOR]

The present state of worldwide discussions of how to apply LCA in environmental labelling, taking into account the current ISO 14 020 and ISO 14 024 works, is described. There is a consensus to use LCA as a tool for more scientific environmental labelling. The examples presented verify some practical possibilities to realise this approach. As a background to different stages of practical labelling, results from LCA studies are already used in the German “Blue Angel” scheme, e.g. for the definition of the scope in one product category, for the priorisation of specific life cycle phases and criteria, as a basis to establish a scoring system or to emphasise the importance of information on how to use environmentally sound products. Practical examples are presented in detail for hand-drying systems, paper products, milk packages, household equipment, televisions and detergents. Some future perspectives are mentioned. [ABSTRACT FROM AUTHOR]

The article presents a study of the detection and toxicity of titanium (Ti) as it seemed to accumulate in algal cells from pulp and paper effluents. It examines whether Ti was bioavailable and in habited the growth of algal cells below pH 7.0. Results show that Ti toxicity was shown by the damage to the chloroplasts of the Chlorella cells, while the absorption was suggested by the identification of Ti in polyphosphate bodies.