7 results on '"Ali Fakhri"'
Search Results
2. Synthesis and characterization of Fe3O4 and CdTe quantum dots anchored SnO2 nanofibers and SnO2 nanospheres for degradation and removal of two carcinogen substance
- Author
-
Pedram Afshar Nejad, Leila Fatolahi, Ali Fakhri, and Mahsa Naji
- Subjects
Photoluminescence ,Materials science ,Scanning electron microscope ,Analytical chemistry ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,01 natural sciences ,Atomic and Molecular Physics, and Optics ,Cadmium telluride photovoltaics ,0104 chemical sciences ,Electronic, Optical and Magnetic Materials ,Adsorption ,Quantum dot ,Nanofiber ,Electrical and Electronic Engineering ,0210 nano-technology ,Photodegradation ,Nuclear chemistry ,BET theory - Abstract
The Fe3O4 quantum dots anchored SnO2 nanofibers (Fe3O4 QDs/SnO2 NFs) and CdTe quantum dots anchored SnO2 nanospheres have been prepared via hydrothermal method. The characteristic structure of Fe3O4 QDs/SnO2 NFs and CdTe QDs/SnO2 NSs was analyzed using several techniques such as X-ray diffraction, transmission and scanning electron microscopy, UV–Vis and photoluminescence spectroscopy, and N2 adsorption–desorption instruments. The average diameters of Fe3O4QDs/SnO2 NFs and CdTe QDs/SnO2 NSs were 7.25 and 3.75 nm, respectively. BET surface area of Fe3O4QDs/SnO2 NFs and CdTe QDs/SnO2 NSs has been found 53.064 and 148.59 m2/g, respectively. The Fe3O4 QDs/SnO2 NFs and CdTe QDs/SnO2 NSs sample were used for removal and photo-catalytic of carcinogenic compounds such as ethyl methanesulfonate (EMS) and N-nitrosonornicotine (NNN). The Fe3O4 QDs/SnO2 NFs and CdTe QDs/SnO2 NSs demonstrates up to 90 and 56% photo degradation and adsorption activity against EMS and NNN solution, respectively. Additionally, cytotoxicity test indicated that the prepared catalyst has low cytotoxic influences. The antibacterial activity of prepared catalyst has excellent effect against Staphylococcus aureus, and Pseudomonas aeruginosa.
- Published
- 2017
- Full Text
- View/download PDF
3. Degradation of toxin via ultraviolet and sunlight photocatalysis using ZnO quantum dots/CuO nanosheets composites: preparation and characterization studies
- Author
-
Mona Azad, Shiva Tahami, and Ali Fakhri
- Subjects
Materials science ,Band gap ,Composite number ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,medicine.disease_cause ,01 natural sciences ,Atomic and Molecular Physics, and Optics ,Hydrothermal circulation ,0104 chemical sciences ,Electronic, Optical and Magnetic Materials ,Quantum dot ,medicine ,Photocatalysis ,Degradation (geology) ,Crystallite ,Electrical and Electronic Engineering ,Composite material ,0210 nano-technology ,Ultraviolet - Abstract
Finding the materials, which help to control the water pollution caused by organic and bacterial pollutants is one of the challenging tasks for the scientific community. We have developed and characterized a material, which can be used to remove of pollutant compound. ZnO quantum dots decorated CuO nanosheets composites have been synthesized using a hydrothermal method. The as synthesized ZnO QDs/CuO NSs composites were characterized by various techniques. The Crystallite sizes were to be obtained 12.5 and 3.2 nm for CuO NSs and ZnO QDs/CuO NSs composite. The energy band gap of the CuO NSs and ZnO QDs/CuO NSs composite are calculated to be 2.01 and 1.86 eV, respectively. The CuO NSs and ZnO QDs/CuO NSs composites are efficiently utilized for the photocatalytic degradation of Tetanus toxin (TeNT) as a target pollutant under UV and sunlight irradiation. The ZnO QDs/CuO NSs composites reveal excellent photocatalytic degradation of TeNT by degrading it up to 75% under UV and sunlight irradiation. The photocatalysis efficiency of ZnO QDs/CuO NSs composite is clearly higher than CuO NSs. The antibacterial activity of the CuO NSs and ZnO QDs/CuO NSs composites was also investigated on gram positive (Enterococcus faecalis) and gram negative (Micrococcus luteus) microbes.
- Published
- 2017
- Full Text
- View/download PDF
4. Lessons learnt from developing a Health Impact Assessment guide in Iran
- Author
-
Patrick Harris, Ali Fakhri, and Mohammadreza Maleki
- Subjects
Medical sociology ,medicine.medical_specialty ,Health Policy ,Public health ,Public Health, Environmental and Occupational Health ,Human factors and ergonomics ,Poison control ,Guidelines as Topic ,Iran ,010501 environmental sciences ,01 natural sciences ,Suicide prevention ,Occupational safety and health ,03 medical and health sciences ,0302 clinical medicine ,Models, Organizational ,Political science ,Environmental health ,medicine ,Humans ,Health Impact Assessment ,030212 general & internal medicine ,Health impact assessment ,0105 earth and related environmental sciences ,Social policy - Abstract
For others wishing to develop Health Impact Assessment (HIA) guides (manuals) and to adjust them to conditions in their countries, we draw lessons from developing an HIA guide in Iran. We derive the lessons from our research comparing HIA guides found in the international literature and our experiences in adapting international experience to an HIA model for Iran that incorporates Iranian experts' opinions.
- Published
- 2016
- Full Text
- View/download PDF
5. Interaction of removal Ethidium Bromide with Carbon Nanotube: Equilibrium and Isotherm studies
- Author
-
Ali Fakhri, Mehdi Norouzi, Kazem Naddafi, and Omid Moradi
- Subjects
Environmental Engineering ,Contact time ,Health, Toxicology and Mutagenesis ,Inorganic chemistry ,Single-walled carbon nanotube ,Nanotechnology ,Carbon nanotube ,Applied Microbiology and Biotechnology ,Endothermic process ,law.invention ,chemistry.chemical_compound ,symbols.namesake ,Adsorption ,law ,Carboxylate ,Waste Management and Disposal ,Water Science and Technology ,Isotherm ,Ethidium bromide ,Chemistry ,Public Health, Environmental and Occupational Health ,Langmuir adsorption model ,Pollution ,Electrophoresis ,symbols ,Research Article - Abstract
Drinking water resources may be contaminated with Ethidium Bromide (EtBr) which is commonly used in molecular biology laboratories for DNA identification in electrophoresis. Carbon nanotubes are expected to play an important role in sensing, pollution treatment and separation techniques. In this study adsorption of Ethidium Bromide on single-walled carbon nanotubes (SWCNTs) and carboxylate group functionalized single-walled carbon nanotube (SWCNT-COOH) surfaces have been investigated by UV–vis spectrophotometer. The effect of contact time, initial concentration and temperature were investigated. The adsorbents exhibits high efficiency for EtBr adsorption and equilibrium can be achieved in 6 and 3 min for SWCNTs and SWCNT-COOH, respectively. The effect of temperature on adsorption of EtBr by toward adsorbents shows the process in this research has been endothermic. The results showed that the equilibrium data were well described by the Langmuir isotherm model, with a maximum adsorption capacity of 0.770 and 0.830 mg/g for SWCNTs and SWCNT-COOH, respectively. The adsorption of EtBr on SWCNT-COOH is more than SWCNTs surfaces. A comparison of kinetic models was evaluated for the pseudo first-order, pseudo second-order models. Pseudo second-order was found to agree well with the experimental data.
- Published
- 2014
- Full Text
- View/download PDF
6. Removal of ethidium bromide by carbon nanotube in aqueous solution: isotherms, equilibrium mechanism studies, and its comparison with nanoscale of zero valent iron as adsorbent
- Author
-
Karim Zare, F. Najafi, Mehdi Norouzi, and Ali Fakhri
- Subjects
Langmuir ,Zerovalent iron ,Aqueous solution ,Materials science ,Kinetics ,Inorganic chemistry ,Langmuir adsorption model ,Nanochemistry ,Carbon nanotube ,law.invention ,symbols.namesake ,Adsorption ,law ,symbols - Abstract
The adsorption of ethidium bromide (EtBr) by single-walled carbon nanotubes (SWCNTs) and nanoscale of zero valent iron (NZVI) were investigated to assess its possible use as adsorbents. The effect of various factors, namely initial adsorbate concentration, adsorbent dosage, and contact time, were studied to identify adsorption capacity of SWCNTs and NZVI surfaces. The experiment demonstrated the maximum EtBr which was obtained at 5 min to attain equilibrium for SWCNTs and NZVI surfaces. Adsorption data were modeled with the Langmuir, Freundlichand, Temkin isotherms. Langmuir adsorption model was used for the mathematical description of the adsorption equilibrium, and the equilibrium data fitted very well with this model for both surfaces as adsorbents. The study showed that SWCNTs and NZVI surfaces could be used as new and efficient adsorbent materials for the removal of EtBr from aqueous solution. Also, the result showed that the SWCNTs were more effective than NZVI in the removal of EtBr from aqueous solution.
- Published
- 2013
- Full Text
- View/download PDF
7. Removal of Co(II), Cu(II) and Pb(II) ions by polymer based 2-hydroxyethyl methacrylate: thermodynamics and desorption studies
- Author
-
Mehdi Norouzi, Ali Fakhri, Behrooz Mirza, and Omid Moradi
- Subjects
Langmuir ,Environmental Engineering ,Aqueous solution ,Health, Toxicology and Mutagenesis ,Metal ions in aqueous solution ,Public Health, Environmental and Occupational Health ,Thermodynamics ,Langmuir adsorption model ,Langmuir isotherm ,Polymeric surfaces ,chemistry.chemical_compound ,symbols.namesake ,Adsorption ,chemistry ,Heavy metal ions ,Desorption ,symbols ,Freundlich equation ,Methyl methacrylate ,Removal ,Thermodynamics parameters ,Waste Management and Disposal ,Research Article ,Water Science and Technology - Abstract
Removal thermodynamics and desorption studies of some heavy metal ions such as Co(II), Cu(II) and Pb(II) by polymeric surfaces such as poly 2-hydroxyethyl methacrylate (PHEMA) and copolymer 2-hydroxyethyl methacrylate with monomer methyl methacrylate P(MMA-HEMA) as adsorbent surfaces from aqueous single solution were investigated with respect to the changes in pH of solution, adsorbent composition, contact time and temperature in the individual aqueous solution. The linear correlation coefficients of Langmuir and Freundlich isotherms were obtained and the results revealed that the Langmuir isotherm fitted the experiment results better than Freundlich isotherm. Using the Langmuir model equation, the monolayer removal capacity of PHEMA surface was found to be 0.7388, 0.8396 and 3.0367 mg/g for Co(II), Cu(ΙΙ) and Pb(II) ions and removal capacity of P(MMA-HEMA) was found to be 28.8442, 31.1526 and 31.4465 mg/g for Co(II), Cu(ΙΙ) and Pb(II) ions, respectively. Changes in the standard Gibbs free energy (ΔG0), standard enthalpy (ΔH0) and standard entropy (ΔS0) showed that the removals of mentioned ions onto PHEMA and P(MMA-HEMA) are spontaneous and exothermic at 293-323 K. The maximum desorption efficiency was 75.26% for Pb(II) using 0.100 M HNO3, 70.10% for Cu(II) using 0.100 M HCl, 59.20% for 0.100 M HCl 63.67% Co(II).
- Published
- 2012
- Full Text
- View/download PDF
Catalog
Discovery Service for Jio Institute Digital Library
For full access to our library's resources, please sign in.