1. Catalytic inhibition of olefin oxidation with Mn and Cu compounds
- Author
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E. M. Pliss, A. M. Grobov, Andrey Sirik, I. V. Tikhonov, O. A. Yasinsky, and V. A. Machtin
- Subjects
Olefin fiber ,Reaction rate constant ,Transition metal ,Chemistry ,Radical ,General Chemistry ,Photochemistry ,Chain termination ,Kinetic energy ,Catalysis ,Highly sensitive - Abstract
The rate constants and kinetic coefficients of inhibition (fkin) for olefins oxidized with the transition metal compounds (Mn) were measured by highly sensitive microvolumometry at 323 K in combination with kinetic modeling. The cyclic mechanism of the reactions of hydroxyl radicals with Mn leading to the multiple chain termination was confirmed as indicated by the observed effect of long-term inhibition of the oxidation of the substrates with Mn and obtained values of fkin > 102.
- Published
- 2021
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