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Atmospheric N2O concentration was observed in the Pacific for the period 1991–2006, using commercial container ships sailing between Japan and North America and between Japan and Australia or New Zealand. The N2O concentration showed a secular increase and interannual variations at all sampling locations, but a seasonal cycle was detectable only at northern high latitudes. The annual mean N2O concentration showed little longitudinal variations (within ± 0.3 ppb) in the northern Pacific, but showed a clear north-south gradient of about 0.8 ppb, with higher values in the Northern Hemisphere. The annual mean N2O was also characterized by especially high values at 30°N due to strong local N2O emissions and by a steep latitudinal decrease from the equator to 20°S due to the suppression of interhemispheric exchange of air by the South Pacific Convergence Zone. The N2O growth rate showed an interannual variation with a period of about 3 yr (high-values in 1999 and 2000), with a delayed eastward and poleward phase propagation in the northern and western Pacific, respectively. The interannual variations of the N2O growth rate and soil water showed a good correlation, suggesting that the N2O emission from soils have an important causative role in the atmospheric N2O variation. [ABSTRACT FROM AUTHOR]

A high-resolution (1.67 km) ensemble transform (ET)-based meso-scale modelling system utilizing urbanization and sea surface temperature (SST) perturbations is used to examine characteristics of sea breeze/heat island interactions and atmospheric transport and dispersion for Tokyo. The ensemble displays a positive spread–skill relationship, with the addition of urban perturbations enabling the ensemble variance to distinguish a larger range of forecast error variances. Two synoptic regimes are simulated. For a pre-frontal period (stronger synoptic flow), there is less variability among ensemble members in the strength of the urban heat island and its interaction with the sea breeze front. During the post-frontal time period, the sea breeze frontal position is very sensitive to the details of the urban representation, with horizontal frontal variation covering the width of the urban centre (∼30 km) and displaying significant impacts on the development and strength of the heat island. Moreover, the dosage values of a tracer released at offshore and urban sites have considerable variability among ensemble members in response to small-scale features such as coastally upwelled water, enhanced anthropogenic heating and variations in building heights. Realistic variations in SST (i.e. warm Tokyo Bay or local upwelling) produce subtle sea breeze variations that dramatically impact tracer distributions. [ABSTRACT FROM AUTHOR]