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Your search keyword '"Stilinović, Vladimir"' showing total 1 results
Start Over Author "Stilinović, Vladimir" Topic crystal structure Publisher taylor & francis ltd
1 results on '"Stilinović, Vladimir"'

1. Two tetrakis(benzoylacetonato)lanthanide species: synthesis, characterization and structures of tetrakis(benzoylacetonato)cerium(IV) and triethylammonium tetrakis(benzoylacetonato)lanthanate(III) tetrahydrate.

Author

Stilinović, Vladimir and Kaitner, Branko

Subjects
*COORDINATION compounds, *RARE earth metals, *METALS, *METAL organic chemical vapor deposition, *BIOLOGICAL assay
Abstract

Tetrakis(benzoylacetonato)cerium(IV), [Ce(bzac)4] and triethylammonium tetrakis(benzoylacetonato)lanthanate(III) tetrahydrate, [Et3NH][La(bzac)4] · 4H2O were prepared and characterized by TG and DCS measurements, IR spectroscopy, and X-ray structure analysis. The coordination polyhedron of cerium is a trigonal dodecahedron, while that of lanthanum is a distorted square antiprism. Thermal and spectroscopic measurements indicate that bonding of the ligand to metal is stronger in [Ce(bzac)4] than in [La(bzac)4]-. [ABSTRACT FROM AUTHOR]

Published
2009
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