1. Crystal structures of the solvate and two tetralkylammonium inclusion compounds of [1, 2, 4, 5-tetra(4'-carboxyphenyl) - benzene].
- Author
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Yun-Xia, Yang, Ma, Xiao-Na, Guo, Ying-Wa, and Wu, Xiang-Xiang
- Subjects
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INCLUSION compounds , *CRYSTAL structure , *AMMONIUM ions , *HYDROGEN bonding , *COLUMNS - Abstract
This article reports [1, 2, 4, 5-tetra(4'-carboxyphenyl)-benzene] (1) and its tetraethyl ammonium and tetrabutylammonium inclusion compounds (C34H21O8−·N+(C2H5)4·H2O (2) C34H21O8−·N+(n-C3H7)4·H2O (3). Compound one eventually forms a "molecular column" along the direction of [110], and the solvent molecules are filled by two adjacent columns to form a stable crystal structure. In compound 2, the tetravalent host anion forms rectangular three-dimensional pores with water molecules by O-H... O hydrogen bonds, two tetraethyl ammonium ions are neatly arranged in the pores to form a tighter structure, In structure 3, the formation of the main skeleton mainly relies on O...H...O hydrogen bond formed by the contact between the proton H shared between the two host anions and the O-H...O generated by the water molecule and one of the two anions. In the three crystal structures, [1, 2, 4, 5-tetra(4'-carboxyphenyl)-benzene], as an "X" polycyclic polycarboxylate aromatic molecule, constructs a large 3 D hole by using its configuration feature. Corresponding solvent molecules and different guest molecules are contained in the 3 D pores, forming various stable crystal structures. [ABSTRACT FROM AUTHOR]
- Published
- 2022
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