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This article addresses the spatial analysis of landslide susceptibility in the Ardabil province of Iran. To this end, two well-known optimization algorithms, namely genetic algorithm (GA) and particle swarm optimization (PSO) are synthesized with an adaptive neuro-fuzzy inference system (ANFIS) to create the ensembles of GA-ANFIS and PSO-ANFIS. Besides, the statistical index (SI) model is also performed to be compared with the mentioned intelligent techniques. Fourteen landslide conditioning factors including elevation, slope aspect, land use, plan curvature, profile curvature, soil type, distance to river, distance to road, distance to fault, rainfall, slope degree, stream power index (SPI), topographic wetness index (TWI), and lithology were considered within the geographic information system (GIS). Out of 253 identified landslides, 177 points (70% of them) were randomly selected and used for the training phase, and the remaining 76 points (30% of them) were used to evaluate the accuracy of the SI, GA-ANFIS, and PSO-ANFIS models. Referring to the calculated area under the receiver operating characteristic curve (AUROC) index, the GA-ANFIS (AUROC = 0.914) and SI (AUROC = 0.821) showed the best performance, respectively in the training and testing phases. Notably, ANFIS-PSO emerged as the faster prediction method compared to the GA-ANFIS. Also, from spatial analysis, it was revealed that around 95%, 87%, and 97% of the training landslides, and 96%, 84%, and 76% of the testing landslides are located in hazardous areas. [ABSTRACT FROM AUTHOR]

Alcohols have always been an important component of drugs, and their design, discovery, synthesis and preparation play an important role in the diagnosis, prevention and treatment of diseases. To synthesize most of organic compounds, we need to perform a variety of selective hydroxyl protections of reagents to synthesize target molecules. Among these protection reactions, formylation is the most commonly used method to protect the hydroxyl groups in organic synthesis. Methods to convert alcohols to formamides are of interest due to the many uses of formamides as synthetic intermediates. These methods include stoichiometric reactions of formylating reagents and catalytic reactions with ethyl formate as the carbonyl source. This review discusses the reported catalytic approaches for the formylation of alcohols to preparation of formate esters. [ABSTRACT FROM AUTHOR]

Strong ground motions usually trigger lots of slope failures in the affected area. In this work, we analyse the occurrence likelihood of earthquake-triggered landslide by employing the ensembles of adaptive neuro-fuzzy inference systems (ANFIS) with four well-known metaheuristics techniques, namely particle swarm optimization (PSO), genetic algorithm (GA), ant colony optimization (ACO), and differential evolution (DE) algorithms. Twelve landslide conditioning factors namely, elevation, slope degree, lithology, peak ground acceleration (PGA), stream power index (SPI), topographic wetness index (TWI), distance to road, distance to river, distance to fault, normalized difference vegetation index (NDVI), slope aspect, and plan curvature are considered within the geographic information system (GIS) to produce the required spatial database. In this paper, frequency ratio (FR) model is used to evaluate the spatial interaction between the landslides and conditioning factors. Meantime, among a total of 458 marked earthquake-induced landslides, 366 (80%) are specified to the learning process, and the remaining 92 (20%) landslides are used to evaluate the accuracy of applied models. The landslide susceptibility maps are generated in the GIS environment. Three accuracy criteria of mean square error (MSE), root mean square error (RMSE), and area under the receiving operating characteristic curve (AUROC) are used to develop a ranking system for comparing the integrity of the designed models. The total ranking scores (TRSs) of 15, 8, 10, and 18, respectively, obtained for PSO-ANFIS, GA-ANFIS, ACO-ANFIS, and DE-ANFIS revealed the superiority of the DE algorithm compared to other metaheuristics techniques. Also, the DE-ANFIS emerged as the fastest ensemble, due to the highest convergence speed obtained for this model. [ABSTRACT FROM AUTHOR]