1. Reaction Products and Process of 2-Chloroethyl Ethyl Sulfide in Microemulsion Media.
- Author
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Mei-Ling, Lei, Hai-Ling, Xi, Ming, Shen, Ling, Yuan, and Shi-Tong, Han
- Subjects
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ETHYL group , *SULFIDES , *MICROEMULSIONS , *CHEMICAL reactions , *SULFONIUM compounds , *NUCLEAR magnetic resonance spectroscopy - Abstract
The reaction of 2-chloroethyl ethyl sulfide was investigated in several oil-in-water microemulsions. The reaction products were identified by GC/MS, NMR, and LC/MS, and the reaction process was monitored by measuring peak height of reaction products and 2-chloroethyl ethyl sulfide with time by1H NMR spectroscopy. The result showed that 2-chloroethyl ethyl sulfide degraded to 2-hydroxyethyl ethyl sulfide, cyclic sulfonium ion, open chain sulfonium chloro ion and sulfonium hydroxyl ion, and the reaction proceeded via a cyclic sulfonium ion intermediate. Based on the NMR results, a pseudoternary model was established for the reaction process of 2-chloroethyl ethyl sulfide in microemulsion. [ABSTRACT FROM AUTHOR]
- Published
- 2014
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