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A novel heterometallic complex [Cu2Cd2(OH)(BTC)(TMA)(H2O)2]n (1) (H3BTC = 1,3,5-benzenetricarboxylic acid, H4TMA = 2-hydroxytimesic acid) is synthesized and characterized. The crystal structure analysis reveals that two crystallographically independent Cu(II) ions are both five-coordinate in distorted square pyramidal surroundings. And for two Cd(II) ions, Cd1 is six coordinated, displaying a distorted triangular prism; Cd2 is five-coordinated, fabricating a distorted trigonal bipyramid. In 1, the H3BTC ligand is partially oxidized into H4TMA, with bridging mode of μ8- and μ7- for TMA4− and BTC3−, respectively. Thus, 1 presents a 3D structure with (5, 6, 7, 9)-connected net topology. [ABSTRACT FROM AUTHOR]

Two metal–organic frameworks, [Co2(L)(H2O)2(4,4′-bipy)]·3CH3CN (1) and [Mn2(L)(1,10-phen)(H2O)]·H2O (2) (H4L = 5-[bis(4-carboxybenzyl)-amino]isophthalic acid; 4,4′-bipy = 4,4′-bipyridine, 1,10-phen = 1,10-phenanthroline), with two different N-donor ligands have been synthesized. The structures of both MOFs were determined using single-crystal X-ray diffraction technique. MOF 1 shows 3D uncommon (4,6,6)-c net with (4.53.62)2(57.66.82)(42.54.66.72.8) topology while in the case of 2, only L4− ligands link Mn(II) ions into a 2D layer structure with chelating 1,10-phen ligand. The results demonstrate that variation in the N-donor ligands plays a pivotal role in deciding the framework of the two MOFs. Both MOFs have been exploited as photocatalyst materials for the degradation of MV. The photocatalysis results indicate that the two MOFs are stable and are prospective candidates for degradation of methyl violet under UV light irradiation. Additionally, 2 displayed superior photocatalytic activity in comparison to 1. The probable photocatalytic activity mechanism for both 1 and 2 against MV has been proposed using density of states (DOS) calculations. [ABSTRACT FROM AUTHOR]

A polyoxometalate-templated metallacycle compound, [Ag6trz6][H3PMo12O40]2·6H2O (trz = 1,2,3-triazole), has been isolated and structurally characterized. The compound represents the first example of a trigonal antiprism based metal-organic framework (MOFs) with complicated Zr6Br12 type topology, in which the trigonal antiprisms as building blocks are constructed by the Ag6trz6 space polygons and the bifunctional POMs (both as template and building block). In addition, to improve the photocatalytic activity of polyoxometalate-templated metallacycle compound, polypyrrole was loaded on its surface through a chemical oxidation polymerization process in situ. Finally, the photocatalytic activity of [Ag6trz6][H3PMo12O40]2 and PPy@[Ag6trz6][H3PMo12O40]2 under visible light was explored, and the results demonstrate that the PPy loading on the surface of POMs-based hybrid compound is feasible to improve their photocatalytic performance. [ABSTRACT FROM AUTHOR]

Two 1-D luminescent metal-organic frameworks with identical structures, {[Mn(BBPTZ)2(MeCN)2]·(ClO4)2}n (1) and {[Zn(BBPTZ)2(MeCN)2]·(MeCN)2·(ClO4)2}n (2), have been synthesized under solvent diffusion evaporation and characterized by elemental analyses, thermal analyses and single-crystal X-ray diffraction. Both complexes crystallize in the monoclinic system, space group C2/c with six-coordinate M(II). Thermal decompositions of the complexes have been studied using thermogravimetric analyses (TGA). The complexes exhibit a significant fluorescence quenching effect to Fe3+ in acetonitrile solution. The LoDs (Limit of Detection) of the complexes to Fe3+ are 2.59 × 10−8 M and 1.57 × 10−8 M for 1 and 2, respectively. The complexes could be applied to efficient chemosensor for Fe3+ detection. [ABSTRACT FROM AUTHOR]

In the present study, a hydrothermal method was developed to prepare nalidixic acid-loaded [Zn2(bdc)2(dabco)] metal–organic frameworks. The self-assembly of primary building blocks was used for synthesis of [Zn2(bdc)2(dabco)] at room temperature. The zinc metal ion was used as a connector, 1,4-benzenedicarboxylate (bdc) as a chelating ligand, and 1,4-diazabicyclo[2.2.2]octane (dabco) as a bridging ligand. The metal organic frameworks were used as the carriers for drug delivery system, where it could entrap nalidixic acid as a model drug. X-ray powder diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA), ultraviolet-visible spectroscopy (UV–vis), BET nitrogen adsorption–desorption method, and scanning electron microscopy (SEM) were used for characterization of samples. The drug release was also monitored, and 96 and 62% of the loaded drug were released over 120 h at pH values of 5.0 and 7.4, respectively. The antimicrobial activities of [Zn2(bdc)2(dabco)] and nalidixic acid-loaded [Zn2(bdc)2(dabco)] were tested against Gram-positive and Gram-negative species. The results revealed that this nanoscale metal organic framework may be regarded as a simple and stable platform for drug release in the treatment of infectious diseases. [ABSTRACT FROM AUTHOR]

A series of metal–organic frameworks built from a propionate-functionalized purine-containing ligand 3-(6-oxo-6,9-dihydro-1H-purin-1-yl)propanoic acid (H2L), {[La(HL)3(H2O)2]·2H2O}n (1), {[Ce(HL)3(H2O)2]·4H2O}n (2), [Co(HL)2(H2O)2]n (3), {[Cd(L)(H2O)]·0.5H2O}n (4) and {[Pb(HL)(C2O4)0.5(H2O)]·2H2O}n (5), was synthesized and characterized. Isostructural 1 and 2 have polymeric chain structures further linked into 3-D porous supramolecular frameworks with 1-D open channels through complicated interchain hydrogen bonding interactions. At 77 K and 1 bar, the dehydrated porous materials 1 and 2 show adsorption behaviors with maximum nitrogen uptakes of 14 and 23 mL g−1, respectively. Complexes 3–5 are 2-D coordination polymers but have different topological structures. Metallohelicate 3 has (4,4) nets composed of left- and right-handed metal–organic helices sharing the common metal centers, but metallohelicate 4 possesses (4·82) topology and 5 has 63-topological structure. In 3 and 5, the polymeric layers are further assembled through regular interlayer hydrogen bonding interactions to form 3-D supramolecular frameworks. Additionally, the thermostabilities of 1–5 as well as the magnetism of 3 were also investigated. [ABSTRACT FROM AUTHOR]