Search

We present the results of a sedimentological and mineralogical study conducted on 305 marine sediment samples (32 seafloor grab samples and 273 subsea floor samples from 91 vibrocores) collected in the marine area of the eastern Pozzuoli Bay, offshore the area of Bagnoli, that has been the site of heavy industrial activity for more than a century. The coastal (onland-offshore) area of Bagnoli–Coroglio has been recognised as a contaminated Site of National Interest (SNI) by the Italian Ministry of the Environment (2000–2001) and since then it has been the subject of a series of environmental studies that have documented a severe contamination of soils onland and marine sediments offshore. Based on the outcomes of the sedimentological classification discussed in this study we have constructed a series of thematic maps illustrating the areal distribution of the sedimentary facies at different stratigraphic levels. Our interpretation provides a support in reconstructing the complex set of environmental changes that have affected the offshore of the eastern Pozzuoli Bay prior to and after the termination of the industrial activity of the Bagnoli brownfield. [ABSTRACT FROM AUTHOR]

We present a new seafloor sedimentological map of Bagnoli-Coroglio SIN (Sites of National Interest) in the Gulf of Pozzuoli (Napoli), Italy, based on the analysis of the acoustic backscatter, calibrated with grain size distribution of sampled surficial marine deposits. Geophysical and ground-truthing (geological) data were acquired during a series of marine surveys designed for a seafloor characterisation aimed at remediation of the marine environment offshore the dismissed industrial area of Bagnoli. This study describes the acquisition and processing of the multibeam echo-sounder (Reson SeaBat 7125 high-resolution) backscatter data recorded during geophysical survey and illustrates the approach followed in the construction of a high-resolution seafloor map of the Bagnoli-Coroglio offshore. [ABSTRACT FROM AUTHOR]

We present a high-resolution bathymetric map of the Gulf of Naples (Italy), which is surrounded by the two main volcanic complexes of Mt. Somma-Vesuvius and Phlegrean Fields. The morphology is obtained from swath bathymetric in a Digital Terrain Model with a 5 m grid cell size. Bathymetric data display the main seafloor morphologies with a resolution never obtained before. These morphologies include the Ammontatura and Dohrn Canyons, the Penta Palummo, Nisida, Miseno and Banco della Montagna banks, and the bathymetric features of the submerged sector of the Somma-Vesuvius volcano. Overall, a prevailing volcanic nature characterizes the seafloor morphologies located in the northern sector, while the southern one is dominated by sedimentary features. The Final Map could be useful for the evaluation of the volcano-related hazards in the area. [ABSTRACT FROM AUTHOR]

We present a long-range terrestrial laser scanner application for the geostructural mapping of Coroglio cliff, a tuff rock face exposed along the coastal zone of Campi Flegrei, Napoli. The procedure includes several phases (geomorphological analysis, structural field survey, laser scanner data acquisition and data processing, 3-D model development and analysis, geostructural classification of discontinuity orientation data and 2-D vertical cartographic production). Field data were processed with specific software dedicated to geostructural and geometric analysis. Spatial data were managed with a geographical information system and have been used for the construction of 2-D and 3-D geometric models of the rock cliff surface and geostructural interpretation. The main product of this study is a vertical geostructural map of the Coroglio cliff at 1:500 scale that illustrates the spatial distribution and orientation of the major families of structural discontinuities detected along the exposed surface of the cliff. The cartographic product includes base information useful to identify the main rock failure mechanisms along the cliff and represents a first step for the zonation of areas susceptible to block failures and the planning of monitoring activities. [ABSTRACT FROM PUBLISHER]

We present the results of a detailed bathymetric survey of Pozzuoli Bay (Gulf of Naples, Italy). This shallow marine area, along with the Campi Flegrei inland, is a highly active volcanic district in the coastal zone of SW Italy. The area has been active since at least 78 ka B.P., and is structurally dominated by a caldera collapse (∼8 km in diameter) associated with the eruption of the Neapolitan Yellow Tuff (NYT), a 30–50 km3dense rock equivalent (DRE) ignimbrite dated ∼15 ka B.P. The main cartographic product consists of a 1:10,000 scale morpho-bathymetric map of Pozzuoli Bay, derived from 1 m cell-size, colour hill-shaded, digital terrain model of the seafloor. Multibeam bathymetry data reveal the precise extent of Roman underwater archaeological remains located in the N–NW infralittoral zone of the Bay. Morphometric analysis allowed for the development of thematic representations, including slope and aspect maps. A complete data set of active fluid vents seafloor locations were also recorded during the survey and reported in the final map. The multibeam bathymetric survey illustrated in this study provides an unprecedentedly detailed image of the seafloor morphology of Pozzuoli Bay and represents a contribution to the understanding of the dynamic evolution of the Campi Flegrei caldera, a high-risk volcanic area densely populated by almost one million people. [ABSTRACT FROM PUBLISHER]

Here, we show the bathymetric map of Ischia Island and its offshore area (Naples Bay, Italy), an active volcanic complex in the NW sector of Naples Bay. The map presented here is based on full seafloor coverage, carried out by merging multibeam swath bathymetric data acquired from several projects using different equipment, single beam echo-sounder data and topographic data, with a final grid cell size of 20  ×  20 metres. The obtained Digital Terrain Model allows a full view of the main morphological units, and may help future geomorphologic and geologic interpretations of the study area. Several previously unknown morphologic highs of the seafloor are mapped and named, in honour of the main researchers and/or events which characterized the recent history of Ischia Island. [ABSTRACT FROM PUBLISHER]

This study presents the results of a Terrestrial Laser Scanner (TLS) application aimed at characterizing the structural pattern of Punta Epitaffio tuffaceous coastal cliff, Pozzuoli Bay, Eastern Tyrrhenian margin. The study site is located in the Campi Flegrei, an active volcanic caldera, characterized by dense urbanization, near the town of Naples, Italy. The 3D digital model of the Punta Epitaffio cliff derived from TLS data, provided a base for the classification of rock discontinuities by geostatistical analysis. In particular, the work flow of geostructural data processing included: 1) statistical analysis of spatial orientation of the facets of the 3D mesh derived by the TLS survey; 2) extraction of the best-fit attitudes (dip and dip direction) of discontinuity sets for each sub-planar patch of the rock face; 3) cluster analysis of bestfit structural discontinuities; 4) definition of all the discontinuity sets and geo-structural classification of 3D model facets; 5) kinematic analysis for the definition of possible failure mechanisms. Kinematic analysis took into account primarily structurally-controlled failure mechanisms (planar sliding, wedge sliding, flexural toppling, and direct toppling). The method illustrated in this research can be extensively applied to identify unstable areas along tuffaceous coastal cliffs and define shape and volume of rocks potentially involved by failures. [ABSTRACT FROM AUTHOR]

The monolayer crystal structure of phenazine adsorbed on graphite is determined by a combination of synchrotron X-ray diffraction and DFT calculations. The molecules adopt a rectangular unit cell with lattice parametersa= 13.55 Å andb= 10.55 Å, which contains 2 molecules. The plane group of the unit cell isp2gg, and each molecule is essentially flat to the plane of the surface, with only a small amount of out-of-plane tilt. Density functional theory (DFT) calculations find a minimum energy structure with a unit cell which agrees within 7.5% with that deduced by diffraction. DFT including dispersion force corrections (DFT+D) calculations help to identify the nature of the intermolecular bonding. The overlayer interactions are principally van der Waals, with a smaller contribution from weak C-H···N hydrogen bonds. This behaviour is compared with that of 4,4′-bipyridyl. [ABSTRACT FROM AUTHOR]