1. Dispersion of Nano TiO2 in Ethylene Glycol and Poly(ethylene terephthalate).
- Author
-
Lifei Hao, Konagaya, Shigeji, Yamada, Toshiro, Tada, Kaoru, Takemasa, Jiro, and Ito, Katsuya
- Subjects
TITANIUM dioxide ,ETHYLENE glycol ,POLYETHYLENE terephthalate ,NANOCOMPOSITE materials ,POLYMERIZATION - Abstract
Nano TiO
2 was dispersed in ethylene glycol (EG) by the replacement of dispersion medium from water sol. EG/TiO2 suspension was well stabilized by the electrostatic repulsive force when pH value of suspension was less than 4.3. In situ polymerization starting from bis(2-hydroxyethyl) terephthalate (BHET) and EG/TiO2 suspension was carried out to prepare a series of poly(ethylene terephthalate) (PET)/TiO2 nanocomposites. Under highly acidic conditions, 97% particles dispersed in PET matrix had the size less than 100 nm. With the increase of pH value, aggregation occurred and larger size particles appeared. A tensile test showed that Young's modulus of PET was increased by the addition of nano TiO2 [ABSTRACT FROM AUTHOR]- Published
- 2010
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