1. Flotation assessment and adsorption mechanism of wulfenite with three anionic collectors.
- Author
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Song, Baoxu, Zhu, Ya, Ran, Jincheng, Han, Baisui, Sun, Xiaoyan, and Zhou, Yongxing
- Subjects
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SODIUM dodecyl sulfate , *FRONTIER orbitals , *MOLECULAR dynamics , *LEAD , *ADSORPTION (Chemistry) , *ADSORPTION capacity , *MOLYBDENUM ions - Abstract
Wulfenite is a useful mineral containing both lead and molybdenum. Although the Mo theoretical content of wulfenite is too low to meet the sales requirement, how to pre-concentrate the wulfenite more efficiently and economically becomes increasingly important for subsequent leaching process. Using sodium oleate (NaOL), benzohydroxamic acid (BHA) and sodium dodecyl sulfonate (SDS) as collector, the flotation behavior of wulfenite has been investigated by micro-flotation tests, and the adsorption capacity of the three collectors on wulfenite has been measured and listed as below: NaOL (pH = 9.5) > SDS (pH = 6.5) > BHA (pH = 7.5). According to the frontier orbital theory analysis, when the collector ions act on the {112} surface of wulfenite, the effective mass of NaOL is the lowest, followed by SDS and BHA. Moreover, the molecular dynamics simulation of the three collector ions on wulfenite {112} surface reveals that the two adjacent outermost molybdenum atoms of wulfenite have strong adsorption due to the fracture of the original Mo-O bonds and could easily react with the single-bond oxygen atom outside the polar groups of the three collectors. Comparing the adsorption energy, NaOL has the best adsorption performance to wulfenite {112} surface, during which the O-Mo1 distance and O-Mo2 distance are both below 2.5 Å. By associations of the simulation results with flotation tests, when the feed contains 0.14% Mo, using NaOL as collector, a rough molybdenum concentrate with molybdenum grade of 17.25% and molybdenum recovery of 86.32% has been obtained by conventional flotation tests, which provide theoretical guidance and practical evidence to promote the wulfenite flotation performance. [ABSTRACT FROM AUTHOR]
- Published
- 2023
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