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The expenses of maintenance and reinforcement for aged concrete structures are significantly on the increase as their durability and general performance has been naturally degraded. Due to this reason, interests on concrete crack reduction technology are growing but more researches are required to fulfill such fast growing demands. Particularly in the underground power facilities, it is difficult to maintain the quality of aging concrete spheres for underground power as their deterioration caused by long-term operation is on-going. In recent years, many studies have been made to overcome the issues and now it is determined that the shrinkage reducing technology which can dramatically reduce the crack at the design stage is one of the most effective solutions. In this study, the test investigated fundamental propertiesof concrete using various shrinkage reducing materials to develop low shrinkage mortar. According to results of experimental study, for mortar and concrete, glycol based material showed excellent shrinkage property and compressive strength. For the later study to generic application of the shrinkage reducing materials, performance reviews on the shrinkage reducing materials with variable factors and various materials such as changes in the amount and type of materials should be followed.

본 연구는 보도블록 제조시 표면 연마 과정에서 발생되는 석분슬러지의 재활용 및 광촉매제를 사용하여 콘크리트 보도블록의 백화 특성을 검토한 것으로 석분슬러지 사용량에 따른 보도블록의 품질특성과 광촉매제의 혼입률 및 도포횟수 등에 따른 보도블록의 백화, 대기정화 등의 특성을 평가하였다. 실험결과, 석분슬러지를 재활용한 콘크리트 보도블록은 납, 6가크롬, 카드뮴, 수은 등의 중금속이 불검출 되어 재활용이 가능하며, 콘크리트 보도블록에 혼입사용 할 경우 흡수율 및 휨강도 등 KS 기준 값을 충족시킬 수 있는 혼입량은 20%가 최적임을 나타내었다. 석분슬러지 및 광촉매제를 적용한 콘크리트 보도블록은 흡수율 5.4%, 휨강도 5.2MPa로 품질기준을 만족하였다. 또한 광촉매제의 사용은 $-5^{\circ}C$ 의 저온환경 조건에서도 백화가 발생되지 않았으며, 대기정화 성능 70%, 촉진내후성 시험후 대기정화 성능시험 68%의 기능성을 나타내었다. 【This study examined the efflorescence characteristics of a concrete sidewalk block manufactured using recycled stone powder sludge and photocatalytic generated by surface polishing during the sidewalk block manufacturing process. The study evaluated the characteristics of the sidewalk block in terms of its quality, based on the amount of stone powder sludge used, efflorescence, and further based on the mixing ratio and number of applications of the photocatalytic. The experimental results indicated that heavy metals such as lead, hexavalent chrome, cadmium, and mercury were not present in the concrete sidewalk block, thereby confirming the effectiveness of the recycled stone powder sludge. The optimum mixing ratio of used in the concrete sidewalk block (for satisfying KS standard values such as water absorption ratio and flexural strength) was found to be 20%. The concrete sidewalk block incorporating the stone powder sludge and photocatalytic exhibited a water absorption ratio of 5.4% and flexural strength of 5.2 MPa, thereby satisfying the quality standards. Additionally, when the photocatalytic was used, efflorescence did not occur even at the low temperature of $-5^{\circ}C$ , and the by the sidewalk block was found to be 70% under normal conditions and 68% when subjected to an accelerated weathering test.】

In this study, with the aim of improving the performance of shale to allow for its use as coarse aggregate for concrete, we coated shale aggregates with water repellents and polymers and evaluated their physical properties such as density, water absorption rate, wear rate, and stability depending on the coating method. In addition, the effects of the performance improvement were evaluated by assessing the properties of fresh concrete produced by varying the shale substitution ratio, as well as the compressive strength, flexural strength, and freeze-thaw resistance according to curing ages. The test results revealed that the absolute dry densities of all coated aggregates satisfied the standard density for coarse aggregates for concrete(>2.50g/cm 3 ),and the absorption rate of the shale aggregate coated with water repellent decreased by about 50% compared with that of uncoated shale. The wear rate of the polymer-coated shale decreased by up to 13.0% compared with that of uncoated shale. All coated aggregates satisfied the stability standard for coarse aggregates for concrete(≤12). The water repellent-induced performance improvement decreased the shale aggregates’ slump by about 20∼30mm compared with that of the uncoated shale aggregates, and the air content of the repellent-coated shale aggregate increased by up to 0.9% compared with that of the uncoated shale aggregate. The compressive strength of the polymer-coated shale aggregates at a curing age of 28 days was RS(F) 95.7% and BS(F) 90.0%, and the flexural strength was RS(F) 98.0 % and BS(F) 92.0% of the corresponding values of concretes produced using plain aggregates. Furthermore, the concrete using polymer-coated shale aggregates showed a dynamic modulus of elasticity of RS(F) 91% and BS(F) 88% after 300 freeze-thaw cycles, thus demonstrating improved freeze-thaw durability.

In summer and winter, the difference between the temperature during the day and that during the night is high, which leads to various problems during concrete placement, such as cracks and defects in the concrete as well as low durability and strength. Although nuclear power plant concrete is widely used for placement in all seasons, particular attention must be paid to its quality during the summer. Therefore, we evaluated the effects of a cooling method for mixing water, which is a commonly used hot weather precooling method, and the use of a retarder, on the characteristics of Nuclear Power Plant concrete. In the cooling method for mixing water, cold water at 5 was used, with 50% of the water content consisting of ice flakes. The effects of using a retarder were evaluated by reviewing the characteristics of the cement at the unset stage and after hardening. To evaluate the characteristics of the unset cement, we measured the slump, air volumes, setting times, and pressure strengths after hardening. Furthermore, we measured the heat of hydration at different temperatures; the loss of heat was minimized using insulation. Both the slump time and the complete ageing time of the air volume were found to be 120 min at and 40 min at . In the case when the cooling method for mixing water was used and in the case when a retarder was used, the initial and final sets by penetration resistance were delayed, and the delay decreased with increasing air temperature. For the heat of hydration, the cooling method for mixing water not only lowered the maximum temperature but also delayed its attainment. However, the use of a retarder had no effect on the maximum temperature. Moreover, in the early ages (e.g., 3 and 7 days), the pressure strength of the concrete was lower than that of plain cement. However, the strength of 28-day concrete met the standard construction specifications.

Sedimentary rocks from construction waste are discarded through open storage and landfilling, which causes an increase in construction cost and inefficient of execution of works. Some sandstone are selected and utilized as aggregates, but shale is buried as industrial waste. Therefore, in this research, we evaluated weathering properties of shale aggregate that is widely distributed throughout Daegu-Kyeongbuk region and freeze-thaw characteristics of concrete according to the replacement ratio of shale aggregate, in an effort to stabilize aggregate supply-demand in Daegu-Kyeongbuk region and develop alternative aggregates. We used red shale and black shale in the experiment, which were exported from a construction site in Deagu. We verified the usage of shale as a concrete aggregate by comparing andesite, which is broadly used as a thick aggregate for concrete, to hornfels, which is a metamorphic sedimentary rock. As a result of the experiment, we observed no degradation phenomenon for andesite and hornfels. However, a part of country rock containing black shale was found to be exfoliated. Red shale started having cracks in the direction of stratification after 1.5 months of direct exposure, and it broke into smaller pieces after approximately 4 months. After 300 cycles of freeze-thaw process on the concrete manufactured according to the replacement ratio of shale aggregate, the modulus of elasticity was 97% for plain and 95% for hornfels. In the case of RS_100, it was 57% after 210 cycles, and for BS_100, it was 54% after 240 cycles. Therefore, we established that, as the number of repetition increases, the freeze-thaw resistance decreases dramatically.

Sedimentary rocks dug up in construction fields are mostly stockpiled for landfill disposal, leading to an increase in construction costs and construction inefficiency. After screening, some of the sandstone can be used as aggregate; however, most of the shale ends up as industrial waste in practice. In this study, to stabilize the demand and develop resources for alternative aggregates of concrete, the potential use of shale, which is widely distributed in the Daegu-Kyeongbuk region, as a concrete aggregate was evaluated. Red and black shale exported from a Daegu excavation site was selected for use in the experiments and evaluated by comparing with hornfels, which is widely used as a coarse aggregate and is a type of andesite and metamorphosed sedimentary rock. The physical properties of the aggregate were evaluated in accordance with the test methods of KS F 2527 "crushed concrete aggregate," and the compressive strength against the shale aggregate replacement ratio was measured. The compressive strength of the concrete after 28 days was 30.8 MPa when the black shale replaced 100% of the aggregate in the concrete and 31.1 MPa when the red shale replaced 100% of the aggregate in the concrete. Compared with the compressive strength of 37.5 MPa for concrete prepared by using plain aggregate, using shale as a substitute for the aggregate produced an average compressive strength that was 82% of normal concrete.