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Chloride attack severely impacts the performance of reinforced concrete. The total and free chloride ion concentration (CIC) of self-compacting concrete (SCC) prepared with three supplementary cementitious materials (SCM) – fly ash (FA), blast furnace slag (BS) and silica fume (SF) – were measured by accelerated salt immersion tests. The apparent chloride diffusion coefficient (CDC) at any exposure time and erosion depth were calculated using the Boltzmann–Matano method. The influence of the type and content of SCM, the water–binder ratio (W/B) and the type of salt solution on CIC and CDC were investigated. Both the introduction of SCM and the reduction of W/B effectively reduced the CIC. The SCM that most effectively reduced CIC was SF, followed by BS and then FA. Free CIC was reduced to a greater degree than total CIC in FA and BS concrete, but the opposite was true for SF concrete. The presence of calcium chloride in salt solution increased total CIC while reducing free CIC. Apparent free CDC dropped over exposure time and initially increased with erosion depth but eventually stabilised. A model of apparent free CDC considering time–depth dependency was created, which shows that time reduction factors of CDC is greater in SCC containing SCM than in control SCC. [ABSTRACT FROM AUTHOR]

Chloride attack severely impacts the performance of reinforced concrete. The total and free chloride ion concentration (CIC) of self-compacting concrete (SCC) prepared with three supplementary cementitious materials (SCM) – fly ash (FA), blast furnace slag (BS) and silica fume (SF) – were measured by accelerated salt immersion tests. The apparent chloride diffusion coefficient (CDC) at any exposure time and erosion depth were calculated using the Boltzmann–Matano method. The influence of the type and content of SCM, the water–binder ratio (W/B) and the type of salt solution on CIC and CDC were investigated. Both the introduction of SCM and the reduction of W/B effectively reduced the CIC. The SCM that most effectively reduced CIC was SF, followed by BS and then FA. Free CIC was reduced to a greater degree than total CIC in FA and BS concrete, but the opposite was true for SF concrete. The presence of calcium chloride in salt solution increased total CIC while reducing free CIC. Apparent free CDC dropped over exposure time and initially increased with erosion depth but eventually stabilised. A model of apparent free CDC considering time–depth dependency was created, which shows that time reduction factors of CDC is greater in SCC containing SCM than in control SCC. [ABSTRACT FROM AUTHOR]

The corrosion resistance of concrete strengthened with three types of fibre-reinforced polymer (FRP) sheets (unidirectional carbon-FRP (CFRP), unidirectional basalt-FRP (BFRP) and bidirectional BFRP) was evaluated under chloride attack and the combined attack of chloride and ultraviolet radiation. After different corrosion durations, powder samples were collected from various depths of the concrete specimens to measure the total chloride ion concentrations (CICs). Scanning electron microscopy (SEM) was conducted to analyse the microscale morphology changes of the concrete surface layer, FRP fibre layer and resin matrix layer before and after combined attack. The results showed that all three types of FRP sheet provided significant chloride ion resistance, with the barrier effect of CFRP being better than that of BFRP under the same conditions. The total CIC of the FRP-strengthened concretes was higher under the combined attack than under chloride attack alone. The SEM observations showed that the resin matrix and fibre filaments of the FRP layer under combined attack were damaged, resulting in an increase in the permeability of the FRP-strengthened concretes. Finally, a time-varying model of CIC inside the FRP-strengthened concrete under chloride attack was established. [ABSTRACT FROM AUTHOR]