Search

A new phthalocyanine Zinc(II) bearing benzyl ether dendritic substituents with nitro-terminal group: tetra-{3,5-[di-(4-nitro benzyloxy) benzyloxy]} Phthalocyanine Zinc(II) (ZnPc(NO2)8), was synthesis and characterized by IR, 1HNMR, MALDI-TOF-MS and UV/Vis. UV/Vis spectra of ZnPc(NO2)8 exhibited characteristic absorption peaks at 290, 350 and 680 nm, and fluorescence emission peak was at 692 nm with a quantum yield at 0.20 in dimethylsulfoxide (DMSO). The polymeric nanoparticle ZnPc(NO2)8@MPEG-PLGA was formed between the amphiphilic block copolymer poly(ethylene glycol)-polylactic and polyglyctic acids (PEG-PLGA) and ZnPc(NO2)8, ZnPc(NO2)8@MPEG-PLGA formed a core-shell-type nanoparticle with diameter about 70 nm. UV/Vis spectra and fluorescence emission spectra of ZnPc(NO2)8@MPEG-PLGA were obviously lower than that of free ZnPc(NO2)8 in buffer solution, and with varying degrees of redshift. ZnPc(NO2)8@MPEG-PLGA would be a promising third-generation photosensitizer for PDT.

A mathematical model was established and validated to predict the microbubble diameter when it departing from the carbon paper and moving into the channel of μDMFC. Single bubble behaviors were studied using the model, which took the gas velocity, liquid cross-flow velocity, micro porous diameter and other parameters into account. Results indicate that the microbubble departure diameter decreases with the increasing liquid velocity, and increases with the increasing micro porous diameter and increasing gas velocity.

An aryl benzyl ester dendritic axially substituted silicon (IV) phthalocyanine, a di-{3,5-di-(4-methoxycarbonyl group benzyloxy) benzyloxy) benzyloxy} axially substituted silicon (IV) phthalocyanine (DSiPc) was synthesized. Its structure was characterized by elemental analysis, 1H NMR, IR and ESI-MS. The photophysical property of DSiPc was studied by steady and time-resolved spectroscopic methods. The steric hindrance of dendritic structure can reduced the aggregation efficiently. The photoinduced intermolecular electron transfer between this novel macromolecule and benzoquinone was studied. The results showed that the fluorescence emission of this dendritic phthalocyanine could be quenched by BQ. Therefore, this novel dendritic phthalocyanine was an effective new electron donor and transmission complex could be used as a potential artificial photosynthesis system.

This paper presents a new approach for obstacle avoidance of small mobile robots, which combine the position sensitive detector (PSD) with digital compass. It is important for an autonomous robot to explore its surroundings in performing the task of localization and navigation for searching. Because of the complexity of the environment, one simple kind of sensors is not sufficient for robot to accomplish these tasks. In this paper, the small mobile robots are enabled to identify barriers and distinguish surroundings by using the angle signal from the digital compass which is generally mounted on the robot. Experimental results indicate that this approach based on digital compass shows great potential in autonomous robot obstacle avoidance.

Aiming at some boiler tubescrack in a power plant, the element composition and the valence of elements in corrosion products on the outer surfaces of the boiler tubes were analysed by Scanning Electron Microanalyzer (SEM) and X-ray Photoelectron Spectroscopy (XPS), and the corrosion reason and mechanism of the outer surfaces of the boiler tubes were studied.The results showed as follows. (1)The content of element S in the corrosion products on the outer surfaces of the fire side boiler tubes was bigger than that in the corrosion products on the outer surfaces of the back side boiler tubes and the corrosion of the outer surfaces of the fire side boiler tubes was more serious than that of the outer surfaces of the back side boiler tubes. (2) the element S in the corrosion products existed in the form of sulfate (SO42-), because the valence of S in the corrosion products on the outer surfaces of the fire side boiler tubes and the back side boiler tubes was +6, not-2. (3) the element Fe in the corrosion products on the outer surfaces of the fire side boiler tubes and the back side boiler tubes existed in the form of Fe3O4, Fe2O3 or Fe2(SO4)3. (4) The corrosion of the boiler tubes was induced by sulphate under high temperature, and aggravated with the temperature of the outer surfaces of the boiler tubes elevated.

With the development of automobile industry, more and more people need automotive information. Meanwhile, there’s a great deal of network information which makes people gather information hard. To make people acquire the automotive information more efficiently, an Automotive News Push System is desperately needed. A distributed focused crawler is proposed for the system to assure that the information is accurate and timely. In this paper, distributed system framework and webpage classification are analyzed. Experimental results show that the frameworkare effective, the accuracy and efficiency of crawling are both improved.

With the arrival of the era of 3G mobile communications, people need not only to meet the call, SMS service, and begin to pursue more realistic visual and interactive experience. The paper developed the virtual campus roaming system of the Wuhan University of Technology for the Android platform based on the Baidu map of the mobile version of the API (Android) and OpenGL ES development tools. Users may select the Campus location of Wuhan University of Technology in the Android mobile phone and can query the campus road, the corresponding function architecture position and 3D virtual scene graph; at the same time they can accept the new information campus. The system of design cannot only provide users with a conventional mobile map services, but also show their location of the 3D scene graph. It is more intuitive to display location information, enhance the campus scenery and culture readability.

Crop monitoring play an important role in the management of agricultural production. This paper presents an integrated platform of crop condition monitoring and diagnosis based on internet of things, as well as its structure and function design. The platform adopted the technology of the internet of things; it achieved fine management of seed and cultivates process by the means of agriculture information real-time collection and monitoring. The platform has certain application value in many agriculture activities, such as livestock management, aquaculture and other and so on.

In order to process the hardened face-gear, the worm for face-gear is studied. The research includes designing and dressing method of worm. According to the meshing relationship of face-gear, worm and shaper, coordinate systems of face-gear, worm and shaper are established. By envelope theory, the face-gear tooth surface are obtained, worm tooth surface and shaper tooth surface. The solid models of face-gear, worm and shaper were built, and the approach of dressing was simulated for hardened face-gear processed.

The nonlinear torsional vibration model of a two-stage planetary gear system is established taking errors of transmission, time varying meshing stiffness and multiple gear backlashes into account. The solution of the equations is determined by using ODE45. The influences of transmission errors on the load sharing behavior are assessed and some useful theoretical guidelines for the design of planetary gear systems are provided at last.

In order to process the hardened face-gear, and improve the surface’s accuracy, the grinding process of face gear is studied. According to the equation of tooth surface, the tooth surface is drawn by a series of space curve, the contact point’s trajectory and velocity at the processing of grinding are determined in three coordinate directions. The model of grinding machine is set up, and analyses the movement of relationship between tool and face-gear. The simple grinding wheel apply complex movement to grinding process the face-gear is successful.

According to the theory of planet gear drive and the actual design requirements of ship reducer, the mathematical model of optimization for power distributional planet gear drive is set up, the optimization design variables, the optimization objective function and the restraint conditions are definited. On the base of the establishment of three hierarchical optimization method, to take advantage of its powerful optimization toolbox in Matlab, combine the basic algorithm of optimization design, optimize respectively power distributional planet gear drive from three single-objective optimization for the lightest weight, the smallest center distance, most efficient and from one multi-objective optimization of the lightest weight and smallest center distance. The optimal results showed that ship reducer weight could be further reduced.