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1. ChemInform Abstract: Tetrahydroquinoline Syntheses Induced with Catalytic Amounts of Viologen Additives

Author

Zheng Xue, Anindya Samanta, Michael F. Mayer, and Bruce R. Whittlesey

Subjects
Chemistry, medicine, Organic chemistry, Viologen, General Medicine, Catalysis, medicine.drug
Abstract

The viologen N,N′-dicyanomethyl-4,4′-bipyridinium·2PF6 was found to induce an aza-Diels–Alder reaction of N-arylimines with N-vinylpyrrolidinone or N-vinylcarbazole, producing tetrahydroquinoline derivatives with high cis/trans selectivities and yields.

Published
2010

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