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4. Berichtigung: Unusual Length Dependence of the Conductance in Cumulene Molecular Wires

Author

Xu, Wenjun, primary, Leary, Edmund, additional, Hou, Songjun, additional, Sangtarash, Sara, additional, González, M. Teresa, additional, Rubio‐Bollinger, Gabino, additional, Wu, Qingqing, additional, Sadeghi, Hatef, additional, Tejerina, Lara, additional, Christensen, Kirsten E., additional, Agraït, Nicolás, additional, Higgins, Simon J., additional, Lambert, Colin J., additional, Nichols, Richard J., additional, and Anderson, Harry L., additional

Published
2021
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5. Corrigendum: Unusual Length Dependence of the Conductance in Cumulene Molecular Wires

Author

Xu, Wenjun, primary, Leary, Edmund, additional, Hou, Songjun, additional, Sangtarash, Sara, additional, González, M. Teresa, additional, Rubio‐Bollinger, Gabino, additional, Wu, Qingqing, additional, Sadeghi, Hatef, additional, Tejerina, Lara, additional, Christensen, Kirsten E., additional, Agraït, Nicolás, additional, Higgins, Simon J., additional, Lambert, Colin J., additional, Nichols, Richard J., additional, and Anderson, Harry L., additional

Published
2021
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6. Constructive Quantum Interference in Single‐Molecule Benzodichalcogenophene Junctions

Author

Baghernejad, Masoud, primary, Yang, Yang, additional, Al‐Owaedi, Oday A., additional, Aeschi, Yves, additional, Zeng, Biao‐Feng, additional, Abd Dawood, Zahra Murtada, additional, Li, Xiaohui, additional, Liu, Junyang, additional, Shi, Jia, additional, Decurtins, Silvio, additional, Liu, Shi‐Xia, additional, Hong, Wenjing, additional, and Lambert, Colin J., additional

Published
2020
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7. Structure‐Independent Conductance of Thiophene‐Based Single‐Stacking Junctions

Author

Li, Xiaohui, primary, Wu, Qingqing, additional, Bai, Jie, additional, Hou, Songjun, additional, Jiang, Wenlin, additional, Tang, Chun, additional, Song, Hang, additional, Huang, Xiaojuan, additional, Zheng, Jueting, additional, Yang, Yang, additional, Liu, Junyang, additional, Hu, Yong, additional, Shi, Jia, additional, Liu, Zitong, additional, Lambert, Colin J., additional, Zhang, Deqing, additional, and Hong, Wenjing, additional

Published
2020
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10. Turning the Tap: Conformational Control of Quantum Interference to Modulate Single‐Molecule Conductance

Author

Jiang, Feng, primary, Trupp, Douglas I., additional, Algethami, Norah, additional, Zheng, Haining, additional, He, Wenxiang, additional, Alqorashi, Afaf, additional, Zhu, Chenxu, additional, Tang, Chun, additional, Li, Ruihao, additional, Liu, Junyang, additional, Sadeghi, Hatef, additional, Shi, Jia, additional, Davidson, Ross, additional, Korb, Marcus, additional, Sobolev, Alexandre N., additional, Naher, Masnun, additional, Sangtarash, Sara, additional, Low, Paul J., additional, Hong, Wenjing, additional, and Lambert, Colin J., additional

Published
2019
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13. Unusual Length Dependence of the Conductance in Cumulene Molecular Wires

Author

Xu, Wenjun, primary, Leary, Edmund, additional, Hou, Songjun, additional, Sangtarash, Sara, additional, González, M. Teresa, additional, Rubio‐Bollinger, Gabino, additional, Wu, Qingqing, additional, Sadeghi, Hatef, additional, Tejerina, Lara, additional, Christensen, Kirsten E., additional, Agraït, Nicolás, additional, Higgins, Simon J., additional, Lambert, Colin J., additional, Nichols, Richard J., additional, and Anderson, Harry L., additional

Published
2019
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15. Single-molecule conductance studies of organometallic complexes bearing 3-thienyl contacting groups

Author

Bock, Soren, Al-Owaedi, Oday A, Eaves, Samantha G, Milan, David C, Lemmer, Mario, Skelton, Brian W, Osorio, Henrry M, Nichols, Richard J, Higgins, Simon J, Cea, Pilar, Long, Nicholas J, Albrecht, Tim, Martin, Santiago, Lambert, Colin J, Low, Paul J, Leverhulme Trust, Ministerio de Educación (Ecuador), Secretaría de Educación Superior, Ciencia, Tecnología e Innovación (Ecuador), University of Western Australia, Australian Research Council, Engineering and Physical Sciences Research Council (UK), Ministry of Higher Education and Scientific Research (Iraq), Ministerio de Economía y Competitividad (España), European Commission, and Diputación General de Aragón

Subjects
organometallic chemistry, single-molecule conductors, Science & Technology, RUTHENIUM(II) COMPLEXES, Chemistry, Multidisciplinary, QUANTUM INTERFERENCE, LENGTH DEPENDENCE, JUNCTIONS, General Chemistry, density functional calculation, contacting group, EFFECTIVE CORE POTENTIALS, Chemistry, LEVEL ALIGNMENT, Physical Sciences, CHARGE-TRANSPORT, scanning tunneling microscopy, METAL-COMPLEXES, ANCHORING GROUPS, 03 Chemical Sciences, ELECTRON-TRANSPORT
Abstract

The compounds and complexes 1,4-CH(C≡C-cyclo-3-CHS) (2), trans-[Pt(C≡C-cyclo-3-CHS)(PEt)] (3), trans-[Ru(C≡C-cyclo-3-CHS)(dppe)] (4; dppe=1,2-bis(diphenylphosphino)ethane) and trans-[Ru(C≡C-cyclo-3-CHS){P(OEt)}] (5) featuring the 3-thienyl moiety as a surface contacting group for gold electrodes have been prepared, crystallographically characterised in the case of 3–5 and studied in metal|molecule|metal junctions by using both scanning tunnelling microscope break-junction (STM-BJ) and STM-I(s) methods (measuring the tunnelling current (I) as a function of distance (s)). The compounds exhibit similar conductance profiles, with a low conductance feature being more readily identified by STM-I(s) methods, and a higher feature by the STM-BJ method. The lower conductance feature was further characterised by analysis using an unsupervised, automated multi-parameter vector classification (MPVC) of the conductance traces. The combination of similarly structured HOMOs and non-resonant tunnelling mechanism accounts for the remarkably similar conductance values across the chemically distinct members of the family 2–5., C.J.L. and O.A.A. acknowledge financial support from the Ministry of Higher Education and Scientific Research of Iraq. C.J.L. acknowledges funding from the EU through the FP7 ITN MOLESCO (project number 212942) and EPSRC (EP/N017188/1, EP/M014452/1 and EP/N03337X/1). P. J.L. holds an ARC Future Fellowship (FT120100073) and gratefully acknowledge sfunding for this work from the ARC (DP140100855,LE15100148). S.B.holds an International Postgraduate Research Scholarship and gratefully acknowledges support from the University of Western Australia. S.G.E. held a Durham Doctoral Scholarship, further supported by the University of Western Australia. T.A.(EP/N032977/1) and R.J.N. and S.J.H. (EP/H035184/1 and EP/K007785/1) thank the EPSRC for funding. M.L.,N.J.L. and T.A. acknowledge the Leverhulme Trust (RPG 2012-754and RPG2014-225) for funding. H.M.O. is grateful for financial assistance from the Secretaría Nacional de Educación Superior, Ciencia,Tecnología e Innovación from Ministerio de Educación (Ecuador). P. C. and S.M. are grateful for financial assistance from Ministerio de Economia y Competitividad from Spain and fondos FEDER in the framework of projects CTQ2012-33198 and CTQ2013-50187-EXP. S.M.and P. C. also acknowledge DGA and fondos FEDER for funding the research group Platón(E-54).

Published
2016

16. Anchor Groups for Graphene-Porphyrin Single-Molecule Transistors

Author

Limburg, Bart, primary, Thomas, James O., additional, Holloway, Gregory, additional, Sadeghi, Hatef, additional, Sangtarash, Sara, additional, Hou, Ian Cheng-Yi, additional, Cremers, Jonathan, additional, Narita, Akimitsu, additional, Müllen, Klaus, additional, Lambert, Colin J., additional, Briggs, G. Andrew D., additional, Mol, Jan A., additional, and Anderson, Harry L., additional

Published
2018
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21. Radical‐Enhanced Charge Transport in Single‐Molecule Phenothiazine Electrical Junctions

Author

Liu, Junyang, primary, Zhao, Xiaotao, additional, Al‐Galiby, Qusiy, additional, Huang, Xiaoyan, additional, Zheng, Jueting, additional, Li, Ruihao, additional, Huang, Cancan, additional, Yang, Yang, additional, Shi, Jia, additional, Manrique, David Zsolt, additional, Lambert, Colin J., additional, Bryce, Martin R., additional, and Hong, Wenjing, additional

Published
2017
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23. Single-Molecule Conductance Studies of Organometallic Complexes Bearing 3-Thienyl Contacting Groups

Author

Bock, Sören, primary, Al-Owaedi, Oday A., additional, Eaves, Samantha G., additional, Milan, David C., additional, Lemmer, Mario, additional, Skelton, Brian W., additional, Osorio, Henrry M., additional, Nichols, Richard J., additional, Higgins, Simon J., additional, Cea, Pilar, additional, Long, Nicholas J., additional, Albrecht, Tim, additional, Martín, Santiago, additional, Lambert, Colin J., additional, and Low, Paul J., additional

Published
2017
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25. Synthesis and Single‐Molecule Conductance Study of Redox‐Active Ruthenium Complexes with Pyridyl and Dihydrobenzo[b]thiophene Anchoring Groups

Author

Ozawa, Hiroaki, primary, Baghernejad, Masoud, additional, Al‐Owaedi, Oday A., additional, Kaliginedi, Veerabhadrarao, additional, Nagashima, Takumi, additional, Ferrer, Jaime, additional, Wandlowski, Thomas, additional, García‐Suárez, Víctor M., additional, Broekmann, Peter, additional, Lambert, Colin J., additional, and Haga, Masa‐aki, additional

Published
2016
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27. A Detailed Experimental and Theoretical Study into the Properties of C60Dumbbell Junctions

Author

Gillemot, Katalin, primary, Evangeli, Charalambos, additional, Leary, Edmund, additional, La Rosa, Andrea, additional, González, M. Teresa, additional, Filippone, Salvatore, additional, Grace, Iain, additional, Rubio-Bollinger, Gabino, additional, Ferrer, Jaime, additional, Martín, Nazario, additional, Lambert, Colin J., additional, and Agraït, Nicolás, additional

Published
2013
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