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7. Tandem <scp>Functionalization‐Carboxylation</scp> Reactions of <scp>π‐Systems</scp> with <scp> CO 2 </scp>

Author

Lorenzo Lombardi, Giulio Bertuzzi, Alessandro Cerveri, Marco Bandini, Bertuzzi, Giulio, Cerveri, Alessandro, Lombardi, Lorenzo, and Bandini, Marco

Subjects
Carboxylation, Tandem, Cascade reaction, Chemistry, Tandem reaction, Surface modification, Double bond, General Chemistry, Carbon Dioxide, Photocatalyisis, Metal catalysis, Combinatorial chemistry, Catalysis
Abstract

The tandem catalytic functionalization/carboxylation of double as well as triple carbon-carbon bonds with CO2 represent an emerging research area in synthetic organic methodology. In particular, the combination of mild reaction conditions, stoichiometric acceptor/donorless conditions (visible light photoredox catalysis) and chiral catalysts contributed to a rapid development of this intriguing research area capable of creating chemical diversity/ complexity from readily available unsaturated hydrocarbons and CO2 as a C1-buinding block. The most recent developments in the field have been collected in the present review article and organized, based on the different sets of π-systems/intermediates/reactive partners employed (i.e., nickelalactones, organo-halides) as well as synthetic strategies (i.e., visible-light photo redox catalysis).

Published
2021

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