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Thorough understanding of seabed fluid flow system is of great significance to geohazard identification and hydrocarbon exploration as it can reshape the seabed and act as an indicator of subsurface hydrocarbon resources. For the first time, an integrated study of side‐scan sonar, single‐ and multi‐channel seismic data and magnetic data reveals a complex fluid flow system composed of various seafloor expressions (i.e. pockmarks and mounds) and shallow fluid migration pathways in the central‐west Bohai Sea off northeast China. Gas chimneys, mud diapirs and a dense network of Quaternary faults are the main fluid migration pathways in the shallow subsurface. The gas chimneys can be classified into three categories (Type A formed by relatively rapid gas escape, Type B formed by episodic fluid expulsion and Type C formed by fluid escape from mud diapirs), based on their distribution and seismic character, implying variability in the formation processes. Sediment remobilization and basement‐involved faults contribute to deep fluid migration into shallow depths. As a seal for up‐moving fluids, the nature and thickness of Holocene marine sediments generally decide the permeability and overburden pressure that may control the distribution of pockmarks and mounds since they are almost distributed above relatively thin Holocene deposits (thickness <20 m) and localized coarse surface sediments. The results of the interpretation gain an improved understanding of the geological processes controlling the genesis and spatial distribution of gas chimney formation and show the significance of gas chimney classification. The distribution pattern of different types of gas chimneys may signify the difference of geological background and fluid flow process, like fluid migration through faults or flow of mobilized sediments, that is crucial for the evaluation of global petroleum systems and Carbon Capture and Storage studies. [ABSTRACT FROM AUTHOR]

The shift of diatom dominance to combination of diatom and dinoflagellate dominance in the Bohai Sea (BS), China might be associated with the change of dissolved nitrogen (DN). This study combines field investigation, ship‐based microcosm experiments, a nitrogen biogeochemical model, and statistical analysis to reveal the impact of DN loading on the dominance of diatoms and dinoflagellates in the BS, considering the quantitative relationship between the algal growth/death and nitrogen migration/transformation processes. The diatom to diatom‐dinoflagellate shift was significantly associated with the DN regime shift of oxidized nitrogen (NO3‐N) to reduced nitrogen (NH4‐N and dissolved organic nitrogen [DON]) since the mid‐1990s. This phenomenon was supported by microcosm and numerical experiments: (a) Gonyaulax verior as a dominant dinoflagellate in the BS efficiently absorbed/assimilated NH4‐N, and it can also utilize DON derived from centric diatoms; Chaetoceros densus as dominant centric diatoms in the BS was able to absorb/assimilate NO3‐N, and it can also utilize DON derived from the Xiaoqing River; (b) The change in dinoflagellates/diatoms ratios was reproduced with the change in DN regime from the 1980s to the 2010s by the proposed nitrogen biogeochemical model based on localized parameters in the BS. Moreover, mixotrophism and stronger survival stability, associated with the faster NH4‐N and DONalgal uptake and slower decomposition of G. verior, also supported the shift from diatoms to diatoms–dinoflagellates during high variations in nutrient supply. This study infers the phytoplankton regime shift mechanism associated with the DN structure in coastal waters, providing a credible scientific basis for the shift from water quality‐based to ecosystem‐based environmental management. Plain Language Summary: Changes in amount and proportion of dissolved nitrogen (DN) might lead to the shift of diatoms to diatoms–dinoflagellates in Bohai Sea (BS), which could result in the degradation of primary productivity, the change of zooplankton and subsequent high‐trophic organisms, and then the change of the entire ecosystem, leading to a series of marine ecosystem health problems such as increasing proportion of toxic/harmful algae blooms, jellyfish blooms and the decline of fishery resources. Our study combines field investigation, ship‐based microcosm experiments, a nitrogen biogeochemical model, and statistical analysis to reveal how changes of DN loading influence the dominant algal species structure in BS. According to microcosm and numerical experiments, we found that the DN forms shift of oxidized nitrogen to reduced nitrogen since the mid‐1990s played an important role in the shift of diatoms to diatoms–dinoflagellates. This is because diatoms can absorb/assimilate oxidized nitrogen faster, while dinoflagellates prefer to absorb/assimilate reduced nitrogen. In addition, dinoflagellates have a slower decomposition rate and stronger survival stability. We infer a mechanism that algal community structure in BS shifted from diatoms to diatoms‐dinoflagellates when the amount/proportion of DN changed, providing a credible scientific basis for the ecosystem‐based environmental management. Key Points: We reproduced the shift of diatoms dominance to diatoms‐dinoflagellates dominance in the Bohai Sea by numerical simulationMicrocosm experiments proved that ammonia and algal dissolved organic nitrogen can promote dinoflagellate (Gonyaulax verior) growthThe numerical model emphasized the driving effect of terrestrial dissolved nitrogen input on the shift of diatoms to dinoflagellates [ABSTRACT FROM AUTHOR]

Research on the distribution of mantle CO2 should involve comprehensive analysis from CO2 source to accumulation. The crust‐mantle pathway system is the key controlling factor of the distribution of mantle CO2, but has received little attention. The pathway system and controlling factors of CO2 distribution in the Bohai Sea are analyzed using data on fault styles and information on the mantle and lithosphere. The relation between volcanic rocks and the distribution of mantle CO2 is reassessed using age data for CO2 accumulations. The distribution of mantle CO2 is controlled by uplift of the asthenosphere and upper mantle, magma conduits in the mantle and fault systems in the crust. Uplifted regions of the asthenosphere are accumulation areas for CO2. The area with uplift of the Moho exhibits accumulation of mantle CO2 at depth. CO2 was mainly derived from vertical migration through the upper mantle and lower crust. The fault style in the upper crust controls the distance of horizontal migration and the locations of CO2 concentrations. The distribution of mantle CO2 and volcanic rocks are not the same, but both probably followed the same pathways sometimes. Mantle CO2 in the Bohai Sea is concentrated in the Bozhong sag and the surrounding area, particularly in a trap that formed before 5.1 Ma and is connected to crustal faults (the Bozhang faults) and lithospheric faults (the Tanlu faults). [ABSTRACT FROM AUTHOR]

Abstract: Organic carbon (OC) cycling in coastal seas that connect terrestrial and open oceanic ecosystems is a dynamic and disproportionately important component of oceanic and global carbon cycles. However, OC cycling in coastal seas needs to be better constrained, particularly for geochemically important black carbon (BC). In this study, we conducted multimedium sampling campaigns, including atmospheric deposition, river water, seawater, and sediments in coastal Bohai Sea (BS) in China. We simultaneously quantified particulate OC (POC), particulate BC (PBC), dissolved OC (DOC), and dissolved BC (DBC) and investigated the cycling and budgets of OC and BC. The cycling and budgets of each individual particulate phase (i.e., POC versus PBC) and dissolved phase (i.e., DOC versus DBC) displayed similar patterns, but there were some distinct differences between the particulate and dissolved phases. In the particulate phases, atmospheric and riverine delivery dominated exogenous inputs (>80%), sequestration to sediments dominated removal (~70%), and exchanges in the Bohai Strait resulted in net export. In the dissolved phases, exchanges in the Bohai Strait dominated both import and export and were in a relatively dynamic equilibrium. We found that both natural perturbations, such as spring dust storms, and anthropogenic activity, exerted significant impacts on BS carbon cycling. The integration of regional and global source‐to‐sink process databases made it clear that future BC studies should calculate PBC and DBC fluxes independently. Continuous field observational studies, more details of the biogeochemical processes involved, and consistent BC quantification methods are urgently needed to elucidate coastal OC and BC cycling. [ABSTRACT FROM AUTHOR]