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An abstract of the article "Visible-Light-Induced Trifluoromethylation of Isonitrile-Substituted Methylenecyclopropanes: Facile Access to 6-(Trifluoromethyl)-7,8-dihydrobenzo k phenanthridine Derivatives" by X.-B. Hu, Y. Wei and M. Shi is presented.

A diagram is presented regarding a three-component tandem process using photoredox catalysis, which presents complex trifluoromethylated phthalans and isoindolines.

A diagram is presented regarding the trifluoromethylation of 2-ethynylbenzenesulfonamide under light for the synthesis of benzosultams.

The scalable protocol is applicable to the diastereoselective transformation of 3,5-diethyl-4-nitroisoxazole. [ABSTRACT FROM AUTHOR]

2-Azido-N-arylacrylamides react with trifluoromethyl radicals and azidyl radicals, respectively, by using Togni′s reagent and Zhdankin′s reagent as radical sources via a tandem addition/cyclization process catalyzed by CuI. [ABSTRACT FROM AUTHOR]

Aryl and alkyl CF3 groups are converted into CH2-aryl fragments upon treatment with arenes in the presence of the reagents/catalyst combination under conditions A). [ABSTRACT FROM AUTHOR]

A mild method for the efficient trifluoromethylation of a broad range of β,γ-unsaturated carboxylic acids in order to obtain allylic CF3-substituted compounds is elaborated. [ABSTRACT FROM AUTHOR]

The presented method gives access to cyclopentanes bearing a quaternary stereocenter through a [3 + 2]-cycloaddition reaction. [ABSTRACT FROM AUTHOR]

By changing the copper catalyst and reaction conditions, E or Z isomers are formed exclusively in the reaction of α,α-dimethylpropargylamides (I), (V), and (VIII) with Togni reagent (II). [ABSTRACT FROM AUTHOR]

The article presents chemical equations related to the article "Enantioselective Synthesis of Trifluoromethyl Substituted Piperidines with Multiple Stereogenic Centers via Hydrogenation of Pyridinium Hydrochlorides" by M.-W. Chen, published in the periodical "Organic Chemistry Frontiers" in 2015.

A stereoselective synthesis of β-(trifluoromethyl)styrenes from aryl bromides is presented. [ABSTRACT FROM AUTHOR]

Aryl, hetaryl, and alkenyl boronic acids are successfully trifluoromethylated in varying yields, depending on the elctronic and steric properties of the substituents. [ABSTRACT FROM AUTHOR]

Depending on the substituents of the phenanthroline the trifluoromethylation proceeds regioselectively or provides a mixture of regioisomers [cf. [ABSTRACT FROM AUTHOR]

Under optimized conditions the reaction of arylpropiolamides and esters with sodium trifluoromethanesulfinate affords spirotrienones in moderate yields. [ABSTRACT FROM AUTHOR]

N-protected N-arylhydroxylamines are initially O-trifluoromethylated prior to a thermally induced migration of the CF3-O-group from the amino function to the ortho-position of the attached arene. [ABSTRACT FROM AUTHOR]

The intramolecular carbotrifluoromethylation of alkynes such as (I) is achieved with Togni reagent II in the presence of Cu(I)-catalyst to yield 5-membered benzoannulated hetero- and carbocycles. [ABSTRACT FROM AUTHOR]

Optically active cyclobutanols are obtained via cyclization of alkynones with arylboronic acids by using a chiral bicyclooctadiene ligand. [ABSTRACT FROM AUTHOR]

This first formal [3+2] cycloaddition of α-trifluoromethyl-3-indolylmethanol silyl ethers and acyclic ketene dithioacetals furnishes trifluoromethylated cyclopenta[b]indoles. [ABSTRACT FROM AUTHOR]

The reaction tolerates a wide range of functional groups. [ABSTRACT FROM AUTHOR]

The transformation of internal as well as terminal alkenes proceeds with high regioselectivity and low to moderate E/Z-selectivity. [ABSTRACT FROM AUTHOR]

The title reaction affords the corresponding trifluoromethyl group substituted benzene derivatives in high yield with excellent selectivity. [ABSTRACT FROM AUTHOR]

The title reaction gives the trifluoromethyl substituted terminal alkenes. [ABSTRACT FROM AUTHOR]

The unprecedented and new title reaction represents the first example of endo-type carbotrifluoromethylation of unsaturated C-C bonds. [ABSTRACT FROM AUTHOR]

This novel copper-catalyzed radical addition of CF3 to activated alkynes followed by a sequential oxidation/cyclization provides direct access to trifluoromethylated coumarins. [ABSTRACT FROM AUTHOR]

The novel method for the copper-catalyzed trifluoromethylation of aromatic and heteroaromatic iodides uses silane (II) in the presence of trimethyl borate. [ABSTRACT FROM AUTHOR]

A facile protocol for the regio- and enantioselective allylic amination of allylic esters to give the corresponding α-type allylic amines is presented. [ABSTRACT FROM AUTHOR]

A diagram is presented which explains the trifluoromethyl compounds trifluoromethylation, oxidative and oxindoles.

Aniline and diisopropylamine are found to be unreactive in the transformation with (VI). [ABSTRACT FROM AUTHOR]

Several complex alkenyl-containing steroid and cinchonine derivatives are converted with moderate yields and often good regio- and diastereoselectivities. [ABSTRACT FROM AUTHOR]

An abstract of the article "Generation of 1-(Trifluoromethyl)-1,2-dihydroisoquinolines via a Silver(I)-Catalyzed Reaction of 2-Alkynylaryl Aldimine with Trimethyl(trifluoromethyl)silane" by Xianbo Wang, Guanyinsheng Qiu, Ling Zhang, and Jie Wu is presented.

The presented method is applicable to a broad range of aryl, heteroaryl, and alkyl halides giving high yields and is compatible with a high number of functional groups. [ABSTRACT FROM AUTHOR]

The article presents chemical equations related to the article "One-Pot Synthesis of 1-(Trifluoromethyl)-4-fluoro-1,2-dihydroisoquinolines and 4,4-Difluoro-1,2,3,4-tetrahydroisoquinolines" by Q. Liu and others, published in the periodical "Organic Letters" in 2013.

Review: [43 refs. [ABSTRACT FROM AUTHOR]

Chemical reactions for the article "Directing-Group-Assisted Copper-Catalyzed Olefinic Trifluoromethylation of Electron-Deficient Alkenes" published in the periodical "Angewandte Chemie International Edition" in 2013 are presented.

The reaction affords α-aryl-βtrifluoromethylamides with a quaternary stereocenter or trifluoromethylated oxindoles from the N-aryl or N-alkyl substrates of the types (I) or (X), respectively. [ABSTRACT FROM AUTHOR]

An efficient and general method to access α-CF3-substituted ketones is developed. [ABSTRACT FROM AUTHOR]

Application of this method is demonstrated by trifluoromethylation of the agrochemicals Napropamide (XV) and Pyriftalid (XVII). [ABSTRACT FROM AUTHOR]