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High‐performance nanoparticle platforms can drive catalysis progress to new horizons, delivering environmental and energy targets. Nanoparticle exsolution offers unprecedented opportunities that are limited by current demanding process conditions. Unraveling new exsolution pathways, particularly at low‐temperatures, represents an important milestone that will enable improved sustainable synthetic route, more control of catalysis microstructure as well as new application opportunities. Herein it is demonstrated that plasma direct exsolution at room temperature represents just such a step change in the synthesis. Moreover, the factors that most affect the exsolution process are identified. It is shown that the surface defects produced initiate exsolution under a brief ion bombardment of an argon low‐pressure and low‐temperature plasma. This results in controlled nanoparticles with diameters ≈19–22 nm with very high number densities thus creating a highly active catalytic material for CO oxidation which rivals traditionally created exsolved samples. [ABSTRACT FROM AUTHOR]

Supported bimetallic nanoparticles used for various chemical transformations appear to be more appealing than their monometallic counterparts, because of their unique properties mainly originating from the synergistic effects between the two different metals. Exsolution, a relatively new preparation method for supported nanoparticles, has earned increasing attention for bimetallic systems in the past decade, not only due to the high stability of the resulting nanoparticles but also for the potential to control key particle properties (size, composition, structure, morphology, etc.). In this review, we summarize the trends and advances on exsolution of bimetallic systems and provide prospects for future studies in this field. [ABSTRACT FROM AUTHOR]

Bimetallic exsolution, catalysis, electrochemistry, energy conversion, nanomaterials In the Minireview on page 6666, C. Tang, K. Kousi, D. Neagu, and I. S. Metcalfe review the, approximately, 70 studies published so far, on bimetallic exsolution and identified research trends in this area. Keywords: bimetallic exsolution; catalysis; electrochemistry; energy conversion; nanomaterials EN bimetallic exsolution catalysis electrochemistry energy conversion nanomaterials 1 1 1 04/19/21 20210416 NES 210416 B Exsolution is a relatively new research hotspot b which can be traced back to 2002. [Extracted from the article]