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Sodium molybdate (Na−Mo−O) wrapped by graphene oxide (GO) composites have been prepared via a simple in‐situ precipitation method at room temperature. The composites are mainly constructed with one dimension (1D) ultra‐long sodium molybdate nanorods, which are wrapped by the flexible GO. The introduction of GO is expected to not merely provide more active sites for lithium‐ions storage, but also improve the charge transfer rate of the electrode. The testing electrochemical performances corroborated the standpoint: The Na−Mo−O/GO composites delivers specific capacities of 718 mAh g−1 after 100 cycles at 100 mA g−1, and 570 mAh g−1 after 500 cycles at a high rate of 500 mA g−1; for comparison, the bare Na−Mo−O nanorod shows a severe capacity decay, which deliver only 332 mAh g−1 after 100 cycles at 100 mA g−1. In view of the cost‐efficient and less time‐consuming in synthesis, and one‐step preparation without further treatment, these Na−Mo−O nanorods/GO composites present potential and prospective anodes for LIBs. [ABSTRACT FROM AUTHOR]