1. Tetrasubstituted bisadamantylidenes—Highly twisted alkenes.
- Author
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Bachrach, Steven M.
- Subjects
- *
ALKENES , *DENSITY functionals , *CARBON-carbon bonds , *MAGNETIC resonance microscopy , *ISOMERIZATION - Abstract
Abstract: A number of 1,3,1′,3′‐tetrasubstituted bisadamantylidenes are examined with 4 different density functional methods (BP86‐D3, ωB97X‐D, B3LYP, and B3LYP‐D3) and the 6‐311G(d) basis set. With increasing steric bulk, these substituted bisadamantylidenes become ever more twisted about the central carbon‐carbon double bond. This manifests in significantly reduced singlet‐triplet gaps from that of typical alkenes, with the tetra‐t‐butylbisadamantylidene 17, twisted to almost 90°, having a gap of only 2.2 kcal mol−1. While its large strain energy may preclude the synthesis of 17, other less‐strained tetrasubstituted analogues are more feasible synthetic targets and still possess small singlet‐triplet gaps, which should be testable by variable temperature NMR and EPR spectroscopy. The twisted alkenes also result in a low rotational energy barrier, and 4 examples with a low barrier to cis‐trans isomerization are presented. These too should be testable by experiment. [ABSTRACT FROM AUTHOR]
- Published
- 2018
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